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Methods and systems for measuring and controlling the percent stoichiometric oxidant in the pyrolyzing section of incinerators are provided. The methods and systems rely on measurements of the oxygen concentration and temperature of the gases within the pyrolysis section and mathematical relationsh

Methods and systems for measuring and controlling the percent stoichiometric oxidant in the pyrolyzing section of incinerators are provided. The methods and systems rely on measurements of the oxygen concentration and temperature of the gases within the pyrolysis section and mathematical relationships between these values and the percent stoichiometric oxidant.

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What is claimed is: 1. A system for determining the PSO in the pyrolyzing section of an incinerator comprising: a means for generating an electrical signal corresponding to oxygen concentration in the gases within the pyrolyzing section; a means for generating an electrical signal corresponding to

What is claimed is: 1. A system for determining the PSO in the pyrolyzing section of an incinerator comprising: a means for generating an electrical signal corresponding to oxygen concentration in the gases within the pyrolyzing section; a means for generating an electrical signal corresponding to the temperature of the gases within the pyrolyzing section; and a device for converting said electrical signals corresponding to oxygen partial pressure and temperature to an estimate of the PSO using a mathematical relationship between the electrical signals and the PSO, wherein the mathematical relationship includes adjustment of the PSO estimate due to temperature and temperature variations wherein the temperature is above 1100�� F. 2. The system of claim 1 wherein the electrical signal corresponding to the oxygen concentration is generated by an oxygen sensor selected from the group consisting of zirconia-based oxygen sensors, electrochemical sensors, microfuel sensors and paramagnetic sensors and positioned in the gases within the pyrolyzing section. 3. The system of claim 1 wherein said oxygen sensor is a zirconia-based oxygen sensor. 4. The system of claim 1 wherein the electrical signal corresponding to the temperature is generated by a temperature sensor selected from the group consisting of thermocouples, resistance temperature detectors, pyrometers and remote temperature devices and positioned to sense the temperature of the gases within the pyrolyzing section. 5. The system of claim 1 wherein the temperature sensor is a thermocouple. 6. The system of claim 1 wherein said mathematical relationship is: description="In-line Formulae" end="lead"PSO=a+b/[1+((x+eT)/c)d] description="In-line Formulae" end="tail" where x is the oxygen sensor output in millivolts, T is the temperature in �� F., and a through e are empirical constants. 7. The system of claim 6 wherein the oxygen sensor is a zirconia-based oxygen sensor and the empirical constants are as follows: description="In-line Formulae" end="lead"a=-733.109; b=873.246; c=1610.403; d=15.176; e=0.2439.description="In-line Formulae" end="tail" 8. The system of claim 1 wherein said mathematical relationship is: description="In-line Formulae" end="lead"PSO=[a+b(x+eT)+c(x+eT)2 +d(x+eT)3]x100description="In-line Formulae" end="tail" where x is the oxygen sensor output in millivolts, T is equal to (Tf-2100) and Tf is the temperature in �� F., and a through e are empirical constants. 9. The system of claim 8 wherein the oxygen sensor is a zirconia-based oxygen sensor and the empirical constants are as follows: description="In-line Formulae" end="lead"a=3.424; b=-1.3433E-02; c=2.4979E-05; d=-1.5670E-08; e=0.2439.description="In-line Formulae" end="tail" 10. A system for controlling the operation of an incinerator, said system comprising: a means for generating an electrical signal corresponding to the oxygen concentration in the gases within the pyrolyzing section of the incinerator; a means for generating an electrical signal corresponding to the temperature of the gases within the pyrolyzing section; a device to convert the electrical signals corresponding to oxygen concentration and temperature to an estimate of the PSO using a mathematical relationship between the electrical signals and the PSO, wherein the mathematical relationship includes adjustment of the PSO estimate due to temperature and temperature variations wherein the temperature is above 1100�� F.; a means for generating a flow control signal to adjust a process flow rate based on the PSO estimate, a pre-selected PSO value, and the process flow, wherein said process flow rate is selected from the group consisting of combustion air, oxidant and fuel flow rates; and a device to adjust the process flow rate corresponding to said control signal. 11. The system of claim 10 wherein the electrical signal corresponding to the oxygen concentration is generated by an oxygen sensor selected from the group consisting of zirconia-based oxygen sensors, electrochemical sensors, microfuel sensors and paramagnetic sensors and positioned in the gases within the pyrolyzing section. 12. The system of claim 10 wherein said oxygen sensor is a zirconia-based oxygen sensor. 13. The system of claim 10 wherein the electrical signal corresponding to the temperature is generated by a temperature sensor selected from the group consisting of thermocouples, resistance temperature detectors, pyrometers and remote temperature devices and positioned to sense the temperature of the gases within the pyrolyzing section. 14. The system of claim 10 wherein the temperature sensor is a thermocouple. 15. The system of claim 10 wherein said mathematical relationship is: description="In-line Formulae" end="lead"PSO=a+b/[1+((x+eT)/c)d] description="In-line Formulae" end="tail" where x is the oxygen sensor output in millivolts, T is the temperature in �� F., and a through e are empirical constants. 16. The system of claim 15 wherein the oxygen sensor is a zirconia-based oxygen sensor and the empirical constants are as follows: description="In-line Formulae" end="lead"a=-733.109; b=873.246; c=1610.403; d=15.176; e=0.2439.description="In-line Formulae" end="tail" 17. The system of claim 10 wherein said mathematical relationship is: description="In-line Formulae" end="lead"PSO=[a+b(x+eT)+c(x+eT)2 +d(x+eT)3]x100description="In-line Formulae" end="tail" where x is the oxygen sensor output in millivolts, T is equal to (Tf-2100) and Tf is the temperature in �� F., and a through e are empirical constants. 18. The system of claim 17 wherein the oxygen sensor is a zirconia-based oxygen sensor and the empirical constants are as follows: description="In-line Formulae" end="lead"a=3.424; b=-1.3433E-02; c=2.4979E-05; d-1.5670E-08; e=0.2439.description="In-line Formulae" end="tail"