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Disclosed are weatherable multilayer articles comprising (i) a coating layer comprising a block copolyestercarbonate comprising structural units derived from at least one 1,3-dihydroxybenzene and at least one aromatic dicarboxylic acid, (ii) a second layer comprising a polymer comprising carbonate s

Disclosed are weatherable multilayer articles comprising (i) a coating layer comprising a block copolyestercarbonate comprising structural units derived from at least one 1,3-dihydroxybenzene and at least one aromatic dicarboxylic acid, (ii) a second layer comprising a polymer comprising carbonate structural units, (iii) an adhesive layer comprising a polyurethane, and (iv) a substrate layer comprising at least one material selected from the group consisting of a thermoplastic resin, a cured thermoset resin, a metal, a ceramic, a glass, and a cellulosic material, wherein the coating layer is in contiguous superposed contact with the second layer, and the adhesive layer is in contiguous contact with the second layer and the substrate layer. Also disclosed is a method for making the multilayer article.

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The invention claimed is: 1. A multilayer article comprising: a coating layer comprising a block copolyestercarbonate comprising structural units derived from a 1,3-dihydroxybenzene and an aromatic dicarboxylic acid; a second layer comprising a polymer comprising carbonate structural units; an adhe

The invention claimed is: 1. A multilayer article comprising: a coating layer comprising a block copolyestercarbonate comprising structural units derived from a 1,3-dihydroxybenzene and an aromatic dicarboxylic acid; a second layer comprising a polymer comprising carbonate structural units; an adhesive layer comprising an adhesive material and a resinous copolymer, wherein the adhesive material comprises a polyurethane, wherein the resinous copolymer comprises structural units derived from an alkenyl aromatic compound and a conjugated diene, and wherein the resinous copolymer is compatible with the adhesive material; and a substrate layer comprising a material selected from the group consisting of a thermoplastic resin, a cured thermoset resin, a metal, a ceramic, a glass, a cellulosic material, and mixtures thereof, wherein the coating layer is in contiguous contact with the second layer, and the adhesive layer is in contiguous contact with the second layer and the substrate layer. 2. The article of claim 1 wherein the 1,3-dihydroxybenzene is selected from the group consisting of unsubstituted resorcinol, 2-methyl resorcinol, and mixtures thereof. 3. The article of claim 2 wherein the 1,3-dihydroxybenzene is unsubstituted resorcinol. 4. The article of claim 1 wherein the aromatic dicarboxylic acid is selected from the group consisting of isophthalic acid, terephthalic acid, naphthalene-2,6-dicarboxylic acid, and mixtures thereof. 5. The article of claim 4 wherein the aromatic dicarboxylic acid is a mixture of isophthalic acid and terephthalic acid. 6. The article of claim 5 wherein the ratio of isophthalic-derived structural units to terephthalic-derived structural units is about 0.25-4.0:1. 7. The article of claim 5 wherein the ratio of isophthalic-derived structural units to terephthalic-derived structural units is about 0.40-2.5:1. 8. The article of claim 1 wherein the copolyestercarbonate comprises about 10% to about 99% by weight arylate blocks. 9. The article of claim 1 wherein the copolyestercarbonate comprises about 60% to about 98% by weight arylate blocks. 10. The article of claim 1 wherein the carbonate portion of the copolyestercarbonate comprises structural units derived from bisphenol A. 11. The article of claim 1 wherein the second layer comprises a bisphenol A polycarbonate. 12. The article of claim 1 wherein the second layer further comprises a colorant selected from the group consisting of dyes, pigments, metal flakes, and glass flakes, and mixtures thereof. 13. The article of claim 1 wherein the adhesive layer comprises a polyurethane comprising structural units derived from a polyol selected from the group consisting of polyether polyols, polyester polyols, polytetramethylene ether glycol, hexamethylene glycol, polyols based on polybutadiene, and mixtures thereof. 14. The article of claim 13 wherein the polyurethane comprises structural units derived from methylene diphenyl diisocyanate or methylene biscyclohexyl diisocyanate. 15. The article of claim 1 wherein the polyurethane comprises an aliphatic polyurethane film. 16. The article of claim 1 wherein the polyurethane comprises a block copolymer comprising a thermoplastic polyurethane block and a block comprising structural units derived from styrene. 17. The article of claim 16 wherein the block comprising structural units derived from styrene comprises a hydrogenated styrene-diene block. 18. The article of claim 1 wherein the alkenyl aromatic compound comprises styrene. 19. The article of claim 1 wherein the multilayer article exhibits a ninety-degree peel force of at least 1750 Newtons per meter. 20. The article of claim 1 wherein the substrate layer comprises a thermoplastic resin selected from the group consisting of polyarylene ethers, polyphenylene ethers, homo-and copolymeric aliphatic olefin and functionalized olefin polymers, polystyrenes; and blends thereof. 21. The article of claim 1 wherein the coating layer has a thickness of about 2-2,500 microns; the second layer has a thickness of about 2-2,500 microns; and the adhesive layer has a thickness of about 8-2,500 microns. 22. A multilayer article comprising: a coating layer comprising a block copolyestercarbonate comprising structural units derived from unsubstituted resorcinol, a mixture of isophthalic acid and terephthalic acid, and bisphenol A; a second layer comprising a bisphenol A polycarbonate optionally containing at least one colorant; an adhesive layer comprising a resinous copolymer and comprising an adhesive material selected from the group consisting of a polyurethane; an aliphatic polyurethane film; thermoplastic polyurethane; and a block copolymer comprising a thermoplastic polyurethane block and a block comprising structural units derived from styrene; wherein the resinous copolymer comprises structural units derived from an alkenyl aromatic compound and a conjugated diene, wherein the resinous copolymer is compatible with the adhesive material; and a substrate layer selected from the group consisting of a thermoplastic resin, a cured thermoset resin, a metal, a ceramic, a glass, and a cellulosic material; wherein the coating layer is in contiguous contact with the second layer, and the adhesive layer is in contiguous contact with the second layer and the substrate layer; and wherein the multilayer article exhibits a ninety-degree peel force of at least 700 Newtons per meter. 23. A film assembly comprising: a coating layer comprising a block copolyestercarbonate comprising structural units derived from a 1,3-dihydroxybenzene and an aromatic dicarboxylic acid; a second layer comprising a polymer comprising carbonate structural units; and an adhesive layer comprising an adhesive material and a resinous copolymer, wherein the adhesive material comprises a polyurethane, wherein the resinous copolymer comprises structural units derived from an alkenyl aromatic compound and a conjugated diene, and wherein the resinous copolymer is compatible with the adhesive material; wherein the second layer is disposed between and in contiguous contact with the coating layer and the adhesive layer. 24. A film assembly comprising: a coating layer comprising a block copolyestercarbonate comprising structural units derived from unsubstituted resorcinol, a mixture of isophthalic acid and terephthalic acid, and bisphenol A; a second layer comprising a bisphenol A polycarbonate optionally containing at least one colorant; and an adhesive layer comprising a resinous copolymer and comprising an adhesive material selected from the group consisting of a polyurethane; an aliphatic polyurethane film; thermoplastic polyurethane; and a block copolymer comprising a thermoplastic polyurethane block and at least one block comprising structural units derived from styrene; wherein the resinous copolymer comprises structural units derived from an alkenyl aromatic compound and a conjugated diene, wherein the resinous copolymer is compatible with the adhesive material; and wherein the second layer is disposed between and in contiguous contact with the coating layer and the adhesive layer. 25. A method for making a multilayer article comprising a coating layer comprising a block copolyestercarbonate comprising structural units derived from a 1,3-dihydroxybenzene and a aromatic dicarboxylic acid; a second layer comprising a polymer comprising carbonate structural units; an adhesive layer comprising an adhesive material and a resinous copolymer, wherein the adhesive material comprises a polyurethane, wherein the resinous copolymer comprises structural units derived from an alkenyl aromatic compound and a conjugated diene, and wherein the resinous copolymer is compatible with the adhesive material; and a substrate layer comprising a material selected from the group consisting of a thermoplastic resin, a cured thermoset resin, a metal, a ceramic, a glass, and a cellulosic material, wherein the coating layer is in contiguous contact with the second layer, and the adhesive layer is in contiguous contact with the second layer and the substrate layer; which method is selected from the group consisting of the method (i) comprising preparing an assembly of the coating layer and the second layer, and combining the assembly with the separate adhesive layer and the substrate layer; the method (ii) comprising preparing an assembly of the coating layer and the second layer, forming the adhesive layer adjacent to the substrate layer, and combining the assembly with the adhesive layer/substrate layer combination; and the method (iii) comprising preparing an assembly of the coating layer, the second layer, and the adhesive layer, and forming the assembly adjacent to the substrate layer. 26. The method of claim 25 wherein the assembly of the coating layer and the second layer is formed by coextrusion. 27. The method of claim 25 wherein forming the assembly adjacent to the adhesive layer is performed by extrusion coating, lamination, or compression molding. 28. The method of claim 25 wherein the coating layer comprises a 1,3-dihydroxybenzene selected from the group consisting of unsubstituted resorcinol, 2-methyl resorcinol, and mixtures thereof. 29. The method of claim 28 wherein the 1,3-dihydroxybenzene is unsubstituted resorcinol. 30. The method of claim 25 wherein the aromatic dicarboxylic acid is selected from the group consisting of isophthalic acid, terephthalic acid, naphthalene-2,6-dicarboxylic acid, and mixtures thereof. 31. The method of claim 30 wherein the aromatic dicarboxylic acid is a mixture of isophthalic acid and terephthalic acid. 32. The method of claim 31 wherein the ratio of isophthalic-derived structural units to terephthalic-derived structural units is about 0.25-4.0:1. 33. The method of claim 32 wherein the ratio of isophthalic-derived structural units to terephthalic-derived structural units is about 0.40-2.5:1. 34. The method of claim 25 wherein the copolyestercarbonate comprises about 10% to about 99% by weight arylate blocks. 35. The method of claim 25 wherein the copolyestercarbonate comprises about 60% to about 98% by weight arylate blocks. 36. The method of claim 25 wherein the carbonate portion of the copolyestercarbonate comprises structural units derived from bisphenol A. 37. The method of claim 25 wherein the second layer comprises a bisphenol A polycarbonate. 38. The method of claim 25 wherein the second layer further comprises a colorant selected from the group consisting of dyes, pigments, metal flakes, and glass flakes. 39. The method of claim 25 wherein the polyurethane comprises structural units derived from a polyol selected from the group consisting of polyether polyols, polyester polyols, polytetramethylene ether glycol, hexamethylene glycol, and polyols based on polybutadiene. 40. The method of claim 39 wherein the polyurethane comprises structural units derived from methylene diphenyl diisocyanate or methylene biscyclohexyl diisocyanate. 41. The method of claim 25 wherein the polyurethane comprises an aliphatic polyurethane film. 42. The method of claim 25 wherein the adhesive layer further comprises a block copolymer comprising a block comprising structural units derived from styrene, and a block comprising a thermoplastic polyurethane. 43. The method of claim 42 wherein the block comprising structural units derived from styrene comprises a hydrogenated styrene-diene block. 44. The method of claim 42 wherein the alkenyl aromatic compound comprises structural units derived from styrene. 45. The method of claim 25 wherein the multilayer article exhibits a ninety-degree peel force of at least 1750 Newtons per meter. 46. The method of claim 25 wherein the substrate layer comprises a thermoplastic resin selected from the group consisting of polyarylene ethers, polyphenylene ethers, homo-and copolymeric aliphatic olefin and functionalized olefin polymers, polystyrenes, and blends thereof. 47. The method of claim 25 wherein the coating layer has a thickness of about 2-2,500 microns; the second layer has a thickness of about 2-2,500 microns; and the adhesive layer has a thickness of about 8-2,500 microns. 48. The article of claim 20 wherein the thermoplastic resin is selected from the group consisting of polyethylene, polypropylene, thermoplastic polyolefin, ethylene-propylene copolymer, and blends thereof. 49. The article of claim 20 wherein the thermoplastic resin comprises thermoplastic polyolefin. 50. The method of claim 25, wherein the block copolyestercarbonate further comprises structural units derived from bisphenol A, wherein the 1,3-dihydroxybenzene comprises unsubstituted resorcinol, wherein the aromatic dicarboxylic acid comprises a mixture of isophthalic acid and terephthalic acid, wherein the polymer is a bisphenol A polycarbonate, and wherein the adhesive material is selected from the group consisting of an aliphatic polyurethane film; a thermoplastic polyurethane; and a block copolymer comprising a thermoplastic polyurethane block and at least one block comprising structural units derived from styrene. 51. The method of claim 46 wherein the thermoplastic resin is selected from the group consisting of polyethylene, polypropylene, thermoplastic polyolefin, ethylene-propylene copolymer, and blends thereof.