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The invention encompasses a method of forming a metallic coating. A metallic glass coating is formed over a metallic substrate. After formation of the coating, at least a portion of the metallic glass can be converted into a crystalline material having a nanocrystalline grain size. The invention a

The invention encompasses a method of forming a metallic coating. A metallic glass coating is formed over a metallic substrate. After formation of the coating, at least a portion of the metallic glass can be converted into a crystalline material having a nanocrystalline grain size. The invention also encompasses metallic coatings comprising metallic glass. Additionally, the invention encompasses metallic coatings comprising crystalline metallic material, with at least some of the crystalline metallic material having a nanocrystalline grain size.

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The invention claimed is: 1. A method of forming a hardened surface on a substrate, comprising: providing a substrate; and forming a molten alloy and cooling said alloy to form a metallic glass coating on the substrate, the forming comprising forming a successive buildup of metallic glass layers, t

The invention claimed is: 1. A method of forming a hardened surface on a substrate, comprising: providing a substrate; and forming a molten alloy and cooling said alloy to form a metallic glass coating on the substrate, the forming comprising forming a successive buildup of metallic glass layers, the metallic glass coating having a hardness of at least about 9.2 GPa, and comprising an alloy consisting of at least 50% iron, optionally chromium, one or more elements selected from the group consisting of boron and phosphorous, one or both of molybdenum and tungsten; and at least one member of the group consisting of Ga, Ge, Au, Zr, Hf, Nb, Ta, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, N, S, and O. 2. The method of claim 1 wherein the substrate is a metallic material. 3. The method of claim 1 wherein the substrate is a ceramic material. 4. The method of claim 1 wherein the metallic glass coating is applied to the substrate as a plasma spray. 5. The method of claim 1 wherein the forming the metallic glass coating comprises an application of an atomized powder of a metallic glass material over the substrate. 6. A method of forming a hardened surface on a substrate, comprising: providing a substrate; and forming a molten alloy and cooling said alloy to form a metallic glass coating on the substrate and having a first hardness of at least about 9.2 GPa, the metallic glass consisting of at least 50% iron, optionally chromium, one or more elements selected from the group consisting of boron and phosphorous, and at least one member of the group consisting of Ga, Ge, Au, Zr, Hf, Nb, Al, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, N, S, and O; and converting at least a portion of the metallic glass coating to a crystalline material having a nanocrystalline grain size and a second hardness of at least about 9.2 GPa. 7. The method of claim 6 wherein the first hardness is at least about 10.0 GPa. 8. The method of claim 6 wherein the forming a metallic glass coating comprises forming a successive buildup of continuous layers. 9. The method of claim 6 wherein the converting comprises heating the metallic glass to above a crystallization temperature of the metallic glass. 10. The method of claim 9 wherein the heating comprises heating to a temperature of at least about 600�� C. and below a melting temperature of the metallic glass. 11. The method of claim 6 wherein the second hardness is at least about 10.0 GPa. 12. The method of claim 6 wherein the forming the hardened surface comprises an application of an atomized powder of a metallic glass material over the substrate.