초록 ▼

A metal compound obtained by a process comprising the step of contacting, in a specific ratio, a compound represented by the formula BiL1r, a compound represented by the formula R1s-1TH, and a compound represented by the formula R23-nJ(OH)n; a catalyst component for addition polymerization comprisin

A metal compound obtained by a process comprising the step of contacting, in a specific ratio, a compound represented by the formula BiL1r, a compound represented by the formula R1s-1TH, and a compound represented by the formula R23-nJ(OH)n; a catalyst component for addition polymerization comprising the metal compound; a catalyst for addition polymerization using the catalyst component; and a process for producing an addition polymer using the catalyst.

대표청구항 ▼

The invention claimed is: 1. A process for producing a catalyst component for addition polymerization, which comprises the step of contacting with one another the following component (a), 0.1 to 8 mol of the following component (b) per 1 mol of the component (a), and 0.6 to 8 mol of the following c

The invention claimed is: 1. A process for producing a catalyst component for addition polymerization, which comprises the step of contacting with one another the following component (a), 0.1 to 8 mol of the following component (b) per 1 mol of the component (a), and 0.6 to 8 mol of the following component (c) per 1 mol of the component (a): (a) a compound represented by the following formula [1], description="In-line Formulae" end="lead"BiL1r [1],description="In-line Formulae" end="tail" (b) a compound represented by the following formula [2], description="In-line Formulae" end="lead"R1s-1TH [2],description="In-line Formulae" end="tail" description="In-line Formulae" end="lead"anddescription="In-line Formulae" end="tail" (c) a compound represented by the following formula [3], description="In-line Formulae" end="lead"R23-nJ(OH)n [3],description="In-line Formulae" end="tail" wherein r is the valence of Bi; L1 is a hydrogen atom, a halogen atom, a hydrocarbon group or a hydrocarbonoxy group, and when two or more L1's exist, they are the same as or different from one another; T is a non-metal atom of the Group 15 or 16 in the periodic table; s is the valence of T; R1 is an electron-withdrawing group or an electron-withdrawing group-containing group, and when two or more R1's exist, they are the same as or different from one another; n is 2 or 3; J is an atom of the Group 13 in the periodic table; and R2 is a hydrocarbon group, and when two or more R2's exist, they are the same as or different from one another. 2. The process for producing a catalyst component for addition polymerization according to claim 1, wherein T is a nitrogen atom or an oxygen atom. 3. The process for producing a catalyst component for addition polymerization according to claim 1, wherein R1 is a halogenated hydrocarbon group. 4. The process for producing a catalyst component for addition polymerization according to claim 1, wherein the compound (b) is a fluorinated phenol. 5. The process for producing a catalyst component for addition polymerization according to claim 1, wherein the compound (b) is pentafluorophenol. 6. The process for producing a catalyst component for addition polymerization according to claim 1, wherein Bi has the valence of 3. 7. The process for producing a catalyst component for addition polymerization according to claim 1, wherein J is a boron atom. 8. A process for producing a catalyst for addition polymerization, which comprises the steps of: (i) contacting with one another the following component (a), 0.1 to 8 mol of the following component (b) per 1 mol of the component (a), and 0.6 to 8 mol of the following component (c) per 1 mol of the component (a): (a) a compound represented by the following formula [1], description="In-line Formulae" end="lead"BiL1r [1],description="In-line Formulae" end="tail" (b) a compound represented by the following formula [2], description="In-line Formulae" end="lead"R1s-1TH [2],description="In-line Formulae" end="tail" description="In-line Formulae" end="lead"anddescription="In-line Formulae" end="tail" (c) a compound represented by the following formula [3], description="In-line Formulae" end="lead"R23-nJ(OH)n [3],description="In-line Formulae" end="tail" wherein r is the valence of Bi; L1 is a hydrogen atom, a halogen atom, a hydrocarbon group or a hydrocarbonoxy group, and when two or more L1s exist, they are the same as or different from one another; T is a non-metal atom of the Group 15 or 16 in the periodic table; s is the valence of T; R1 is an electron-withdrawing group or an electron-withdrawing group-containing group, and when two or more R1s exist, they are the same as or different from one another; n is 2 or 3; J is an atom of the Group 13 in the periodic table; and R2 is a hydrocarbon group, and when two or more R2s exist, they are the same as or different from one another, thereby producing a catalyst component for addition polymerization; and (ii) contacting with one another: the catalyst component for addition polymerization; a compound represented by the following formula [4], description="In-line Formulae" end="lead"L2aMX1b [4],description="In-line Formulae" end="tail" wherein a is a number satisfying 02 is a group having a cyclopentadienyl type anion skeleton, or a group containing a hetero-atom, and when two or more L2s exist, they are the same as or different from one another, and they may be linked with one another directly or through a group containing a carbon atom, a silicon atom, a nitrogen atom, an oxygen atom, a sulfur atom or a phosphorus atom; X1 is a halogen atom, a hydrocarbon group excluding the group having a cyclopentadienyl type anion skeleton, or a hydrocarbonoxy group, and when two or more X1s exist, they are the same as or different from one another, and an organoaluminum compound. 9. The process for producing a catalyst component for addition polymerization according to claim 8, wherein T is a nitrogen atom or an oxygen atom. 10. The process for producing a catalyst component for addition polymerization according to claim 8, wherein R1 is a halogenated hydrocarbon group. 11. The process for producing a catalyst component for addition polymerization according to claim 8, wherein the compound (b) is a fluorinated phenol. 12. The process for producing a catalyst component for addition polymerization according to claim 8, wherein the compound (b) is pentafluorophenol. 13. The process for producing a catalyst component for addition polymerization according to claim 8, wherein Bi has the valence of 3. 14. The process for producing a catalyst component for addition polymerization according to claim 8, wherein J is a boron atom. 15. The process for producing a catalyst component for addition polymerization according to claim 8, wherein the compound represented by the following formula [4] is a metallocene compound. 16. The process for producing a catalyst component for addition polymerization according to claim 8, wherein the organoaluminum compound is a compound represented by the following formula [8], description="In-line Formulae" end="lead"R6dAlY3-d [8],description="In-line Formulae" end="tail" wherein d is a number satisfying 06 is a hydrocarbon group, and when two or more R6s exist, these are the same as or different from one another; Y is a hydrogen atom, a halogen atom or an hydrocarbonoxy group, and when two or more Ys exist, they are the same as or different from one another. 17. A process for producing an addition polymer, which comprises the steps of: (i) contacting an addition polymerizable monomer with a catalyst for addition polymerization produced according to the process of claim 8; and (ii) polymerizing the addition polymerizable monomer in the presence of the catalyst for addition polymerization. 18. The process for producing an addition polymer according to claim 17, wherein the addition polymerizable monomer is an olefin. 19. The process for producing an addition polymer according to claim 17, wherein the addition polymerizable monomer is a combination of ethylene and an α-olefin.