IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0288995
(2005-11-29)
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등록번호 |
US-7425603
(2008-09-16)
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발명자
/ 주소 |
- Raj,T. Tilak
- Srinivasarao,Radhakrishna Arakali
- Lens,Jan Pleun
- K.,Subrahmanya Bhat
- Hasyagar,Umesh
- Scindia,Subash
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출원인 / 주소 |
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인용정보 |
피인용 횟수 :
1 인용 특허 :
1 |
초록
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A polymer comprising structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic
A polymer comprising structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; wherein each occurrence of "n", "m", and "p" independently has a value of 0, 1, 2, 3, or 4; and wherein the polymer is substantially linear.
대표청구항
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What is claimed is: 1. A polymer comprising structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 ca
What is claimed is: 1. A polymer comprising structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; wherein each occurrence of "n", "m", and "p" independently has a value of 0, 1, 2, 3, or 4; and wherein the polymer is substantially linear. 2. The polymer of claim 1, wherein the polymer is a polycarbonate, a polyester, a copolyestercarbonate, a polyurethane, or an epoxide-containing polymer. 3. The polycarbonate of claim 2, comprising structural carbonate units of Formula (XI) wherein at least about 60 percent of the total number of R5 groups are aromatic functionalities and the balance thereof are aliphatic or alicyclic functionalities; and wherein at least two R5 groups are structural units derived from a polycyclic dihydroxy compound of Formula (I). 4. The polycarbonate of claim 2, comprising about 5 to about 100 mole percent of R5 units derived from a polycyclic dihydroxy compound of Formula (I). 5. The polycarbonate of claim 2, further comprising structural units derived from bisphenol A. 6. The polycarbonate of claim 2, further comprising at least one structural unit having Formula (XVI), Formula (XVII), or Formula (XVIII) 7. The polyester of claim 2, comprising structural units of the Formula (XII) wherein "D" is a divalent functionality derived from a dihydroxy compound, wherein at least two of "D" are each independently derived from a polycyclic dihydroxy compound of Formula (I); and wherein "T" is a divalent functionality derived from a dicarboxylic acid. 8. The polyester of claim 7, further comprising at least one structural unit having Formula (XVI), Formula (XVII), or Formula (XVIII) 9. The copolyestercarbonate of claim 2, comprising recurring carbonate units of Formula (XI) wherein at least about 60 percent of the total number of R5 groups are aromatic functionalities and the balance thereof are aliphatic, alicyclic, or aromatic functionalities and; and structural units of Formula (XII) wherein "D" is a divalent functionality derived from a dihydroxy compound; and wherein "T" is a divalent functionality derived from a dicarboxylic acid; and wherein at least two R5 groups or at least two of "D" are each independently structural units derived from a polycyclic dihydroxy compound of Formula (I). 10. The copolyestercarbonate of claim 9, further comprising at least one structural unit having Formula (XVI), Formula (XVII), or Formula (XVIII) 11. The polyurethane of claim 2, comprising recurring units having Formula (XIII) wherein R6 is a divalent functionality derived from a dihydroxy compound; wherein at least two of R6 are each independently structural units derived from a polycyclic dihydroxy compound of Formula (I); and wherein "Q" is a divalent functionality derived from a diisocyanate compound, having Formula (XIV) description="In-line Formulae" end="lead"Q(NCO)2 (XIV)description="In-line Formulae" end="tail" wherein Q comprises a divalent aliphatic radical having 2 to 28 carbons, a divalent cycloaliphatic radical having 4 to 15 carbons, or a divalent aromatic radical having 6 to 15 carbons. 12. The epoxide-containing polymer of claim 2, having the structure of Formula (XV) wherein R7 is a divalent functionality derived from a dihydroxy compound; wherein at least two of R7 are each structural units derived from a polycyclic dihydroxy compound of Formula (I); and wherein "q" is 2 to about 20. 13. A polycarbonate comprising at least two structural units derived from a polycyclic dihydroxy compound of Formula (XIX) or Formula (X) wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; wherein each occurrence of "n", "m", and "p" independently has a value of 0 or 1; wherein the polycarbonate further comprises structural units derived from bisphenol A; and wherein the polycarbonate is substantially linear. 14. A polycarbonate comprising structural units derived from a polycyclic dihydroxy compound of Formula (XX) or Formula (XXI) wherein the polycarbonate comprises about 5 to about 50 mole percent of repeating units derived from the polycyclic dihydroxy compound of Formula (XX) or Formula (XXI) or a mixture of the two, and about 50 to about 95 mole percent of repeating units derived from bisphenol A; and wherein the polycarbonate is substantially linear. 15. A polymer comprising structural units derived from a polycyclic dihydroxy compound of Formula (X) wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; and wherein each occurrence of "n", "m", and "p" independently has a value of 0, 1, 2, 3, or 4. 16. A process for preparing a polymer, comprising polymerizing a polycyclic dihydroxy compound of Formula (I) wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; wherein each occurrence of "n", "m", and "p" independently has a value of 0, 1, 2, 3, or 4; and wherein the polycarbonate is substantially linear. 17. The process of claim 16, wherein polymerizing comprises dissolving or dispersing the polycyclic dihydroxy compound of Formula (I) in an aqueous base; adding the resulting mixture to a water-immiscible solvent to form an interfacial mixture; and contacting the interfacial mixture with a carbonate precursor in the presence of a catalyst under controlled pH conditions to form a polycarbonate. 18. The process of claim 17, wherein the aqueous base comprises sodium hydroxide, potassium hydroxide, or a combination thereof. 19. The process of claim 17, wherein the carbonate precursor comprises a carbonyl halide, a haloformate, a bishaloformate of a glycol, an ester, or a mixture of two or more of the foregoing carbonate precursors. 20. The process of claim 17, wherein the catalyst comprises triethylamine, a phase transfer catalyst, or a combination thereof. 21. The process of claim 17, wherein the water-immiscible solvent comprises methylene chloride, 1,2-dichloroethane, chlorobenzene, toluene, or a combination of two or more of the foregoing solvents. 22. The process of claim 17, wherein pH is maintained at about 8 to about 10. 23. The process of claim 16, wherein polymerizing comprises reacting, in a molten state, the polycyclic dihydroxy compound of Formula (I) and a diaryl carbonate ester, in the presence of a transesterification catalyst to form a polycarbonate. 24. The process of claim 23, wherein the diaryl carbonate ester comprises diphenyl carbonate, bis(methyl salicyl) carbonate, or a combination thereof. 25. The process of claim 16, wherein polymerizing comprises reacting the polycyclic dihydroxy compound of Formula (I) with a dicarboxylic acid compound of Formula (XXII) wherein R8 is independently at each occurrence hydroxy, chloro, or OR9; wherein R9 is independently at each occurrence selected from the group consisting of an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; and wherein "T" is a divalent functionality derived from a dicarboxylic acid, wherein the divalent functionality comprises a cycloaliphatic functionality having 6 to 10 carbon atoms, an aromatic functionality having 6 to 20 carbon atoms, or an aliphatic functionality having 2 to 10 carbon atoms. 26. The process of claim 16, wherein said polymerizing comprises reacting a polycyclic dihydroxy compound of Formula (I) with a carbonate precursor and a dicarboxylic acid compound of Formula (XXII) wherein R8 is independently at each occurrence hydroxy, chioro, or OR9; wherein R9 is independently at each occurrence selected from the group consisting of an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; and wherein "T" is a divalent functionality derived from a dicarboxylic acid, wherein the divalent functionality comprises a cycloaliphatic functionality having 6 to 10 carbon atoms, an aromatic functionality having 6 to 20 carbon atoms, or an aliphatic functionality having 2 to 10 carbon atoms. 27. The process of claim 16, wherein polymerizing comprises reacting the polycyclic dihydroxy compound of Formula (I) with a diisocyanate compound having Formula (XIV) description="In-line Formulae" end="lead"Q(NCO)2 (XIV)description="In-line Formulae" end="tail" wherein Q comprises a divalent aliphatic radical having 2 to 28 carbons, a divalent cycloaliphatic radical having 4 to 15 carbons, or a divalent aromatic radical having 6 to 15 carbons. 28. The process of claim 27, wherein the diisocyanate compound is selected from the group consisting of toluene-2,6-diisocyanate, 1,6-hexamethylene diisocyanate, 4,4'-diphenyl methane diisocyanate, 2,4'-diphenyl methane diisocyanate, 1,3-phenylene diisocyanate, 1,4-phenylene diisocyanate, toluene-2,4-diisocyanate, and combinations of two or more of the foregoing diisocyanate compounds. 29. The process of claim 16, wherein polymerizing comprises reacting the polycyclic dihydroxy compound of Formula (I) with epichlorohydrin to form a diglycidyl ether compound of Formula (XV) polymerizing the diglycidyl ether compound having Formula (XV), wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; and wherein each occurrence of "n", "m", and "p" independently has a value of 0, 1, 2, 3, or 4. 30. A substantially linear polymer prepared according to the method of claim 16. 31. The substantially linear polymer of claim 30, wherein the substantially linear polymer is a polycarbonate prepared by a process comprising dissolving or dispersing the polycyclic dihydroxy compound of Formula (I) in an aqueous base; adding the resulting mixture to a water-immiscible solvent to form an interfacial mixture; and contacting the interfacial mixture with a carbonate precursor in the presence of a catalyst under controlled pH conditions to form a polycarbonate. 32. The substantially linear polymer of claim 30, wherein the substantially linear polymer is a polycarbonate prepared according to a process comprising reacting, in a molten state, the polycyclic dihydroxy compound of Formula (I) and a diaryl carbonate ester, in the presence of a transesterification catalyst to form a polycarbonate. 33. The substantially linear polymer of claim 30, wherein the substantially linear polymer is a polyester prepared according to a process comprising reacting the polycyclic dihydroxy compound of Formula (I) with a dicarboxylic acid compound of Formula (XXII) wherein R8 is independently at each occurrence hydroxy, chloro, or OR9; wherein R9 is independently at each occurrence selected from the group consisting of an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; and wherein "T" is a divalent functionality derived from a dicarboxylic acid, wherein the divalent functionality comprises a cycloaliphatic functionality having 6 to 10 carbon atoms, an aromatic functionality having 6 to 20 carbon atoms, or an aliphatic functionality having 2 to 10 carbon atoms. 34. The substantially linear polymer of claim 30, wherein the substantially linear polymer is a copolyestercarbonate prepared according to a process comprising reacting a polycyclic dihydroxy compound of Formula (I) with a carbonate precursor and a dicarboxylic acid compound of Formula (XXII) wherein R8 is independently at each occurrence hydroxy, chloro, or OR9; wherein R9 is independently at each occurrence selected from the group consisting of an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; and wherein "T" is a divalent functionality derived from a dicarboxylic acid, wherein the divalent functionality comprises a cycloaliphatic functionality having 6 to 10 carbon atoms, an aromatic functionality having 6 to 20 carbon atoms, or an aliphatic functionality having 2 to 10 carbon atoms. 35. The substantially linear polymer of claim 30, wherein the substantially linear polymer is a polyurethane prepared according to a process comprising reacting the polycyclic dihydroxy compound of Formula (I) with a diisocyanate compound having Formula (XIV) description="In-line Formulae" end="lead"Q(NCO)2 (XIV)description="In-line Formulae" end="tail" wherein Q comprises a divalent aliphatic radical having 2 to 28 carbons, a divalent cycloaliphatic radical having 4 to 15 carbons, or a divalent aromatic radical having 6 to 15 carbons. 36. The substantially linear polymer of claim 30, wherein the substantially linear polymer is an epoxide-containing polymer prepared according to a process comprising reacting the polycyclic dihydroxy compound of Formula (I) with epichlorohydrin to form a diglycidyl ether compound of Formula (XV) polymerizing the diglycidyl ether compound having Formula (XV), wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; and wherein each occurrence of "n", "m", and "p" independently has a value of 0, 1, 2, 3, or 4. 37. A thermoplastic composition comprising a polymer comprising structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1, R2 and R3 at each occurrence, can be the same or different and are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; wherein each occurrence of "n", "m", and "p" independently has a value of 0, 1, 2, 3, or 4; and wherein the polymer is substantially linear. 38. The thermoplastic composition of claim 37, further comprising an additive selected from the group consisting of fillers, reinforcing agents, thermal stabilizers, radiation stabilizers, antioxidants, light stabilizers, UV stabilizers, plasticizers, visual effect enhancers, extenders, antistatic agents, catalyst quenchers, mold release agents, flame retardants, infrared shielding agents, whitening agents, blowing agents, anti-drip agents, impact modifiers, processing aids, and combinations of two or more of the foregoing additives. 39. An article comprising the composition of claim 37. 40. A method of manufacture of an article comprising molding, extruding, or shaping the composition of claim 37 into an article.
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