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A method and apparatus for producing high purity argon by combined cryogenic distillation and adsorption technologies is disclosed. Crude argon from a distillation column or a so-called argon column is passed to a system of adsorption vessels for further purification. Depressurization gas from ads

A method and apparatus for producing high purity argon by combined cryogenic distillation and adsorption technologies is disclosed. Crude argon from a distillation column or a so-called argon column is passed to a system of adsorption vessels for further purification. Depressurization gas from adsorption is introduced back, in a controlled manner, to the distillation column and/or a compressor or other means for increasing pressure. Particulate filtration and getter purification may optionally be used.

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We claim: 1. A method for producing argon product comprising: withdrawing an argon-containing fluid from a first cryogenic distillation column; increasing the pressure of at least a portion of the argon-containing fluid in a means for increasing pressure thereby forming a compressed argon-containin

We claim: 1. A method for producing argon product comprising: withdrawing an argon-containing fluid from a first cryogenic distillation column; increasing the pressure of at least a portion of the argon-containing fluid in a means for increasing pressure thereby forming a compressed argon-containing fluid; introducing at least a portion of the compressed argon-containing fluid into a first end portion of a first pressure swing adsorption vessel; withdrawing a first argon-rich gas from a second end portion of the first pressure swing adsorption vessel; terminating the introduction of the compressed argon-containing fluid into the first pressure swing adsorption vessel; withdrawing a depressurization gas from at least one of the first end portion and a middle portion of the first pressure swing adsorption vessel thereby reducing the pressure in the first pressure swing adsorption vessel to a final depressurization pressure; regulating the flow of at least a portion of the depressurization gas by passing the at least a portion of the depressurization gas to a means for moderating flow thereby forming a regulated depressurization gas; and introducing at least a portion of the regulated depressurization gas into at least one of the first cryogenic distillation column and the means for increasing pressure. 2. The method of claim 1 wherein, for at least 90% of a cycle time of the first pressure swing adsorption vessel, the at least a portion of the regulated depressurization gas has a molar flow rate within 50% and 400% of the time-averaged molar flow rate of the at least a portion of the regulated depressurization gas. 3. The method of claim 1 wherein the means for moderating flow comprises a gas capacitance means and a downstream flow restriction. 4. The method of claim 3 wherein the gas capacitance means has a volume 0.5 to 20 times greater than the volume of the first pressure swing adsorption vessel. 5. The method of claim 1 wherein the compressed argon-containing fluid comprises oxygen, the method further comprising kinetically adsorbing the oxygen in the first pressure swing adsorption vessel using carbon molecular sieve. 6. The method of claim 1 further comprising: withdrawing a first equalization gas from the middle portion of the first pressure swing adsorption vessel; introducing at least a portion of the first equalization gas into a first end portion of a second pressure swing adsorption vessel; withdrawing a second equalization gas from the second end portion of the first pressure swing adsorption vessel; and introducing at least a portion of the second equalization gas into a second end portion of the second pressure swing adsorption vessel. 7. The method of claim 1 wherein the argon-containing fluid comprises greater than 50 volume % argon. 8. The method of claim 1 wherein the first argon-rich gas comprises greater than 90 volume % argon. 9. The method of claim 1 wherein the first argon-rich gas comprises less than 0.001 volume % oxygen. 10. The method of claim 1 wherein the final depressurization pressure is 0 psig to 20 psig. 11. The method of claim 1 further comprising: introducing a second argon-rich gas from at least one of the second pressure swing adsorption vessel and a third pressure swing adsorption vessel into the second end portion of the first pressure swing adsorption vessel during at least a portion of the step of withdrawing the depressurization gas. 12. The method of claim 1 further comprising: filtering at least one of the at least a portion of the depressurization gas and the at least a portion of the regulated depressurization gas. 13. The method of claim 1 further comprising: introducing at least a portion of the first argon-rich gas into a second cryogenic distillation column. 14. The method of claim 1 further comprising: introducing at least a portion of the first argon-rich gas into a purifier vessel containing a getter. 15. An apparatus for producing argon product comprising: a first distillation column having an inlet and an outlet, the outlet for withdrawing an argon-containing fluid; a means for increasing pressure of the argon-containing fluid having an inlet and an outlet, the inlet in fluid communication with the first distillation column outlet; a first pressure swing adsorption vessel having a first end portion, a middle portion, and a second end portion, the first end portion in selective fluid communication with the outlet of the means for increasing pressure; a second pressure swing adsorption vessel having a first end portion, a middle portion, and a second end portion, the first end portion of the second pressure swing adsorption vessel in selective fluid communication with the outlet of the means for increasing pressure; and a means for moderating flow having an inlet and an outlet, the inlet of the means for moderating flow in selective fluid communication with the first end portion of the first pressure swing adsorption vessel and in selective fluid communication with the first end portion of the second pressure swing adsorption vessel, the outlet of the means for moderating flow in fluid communication with at least one of the inlet of the first distillation column and the inlet of the means for increasing pressure. 16. The apparatus of claim 15 wherein: the means for moderating flow comprises a gas capacitance means and a downstream flow restriction. 17. The apparatus of claim 16 wherein the downstream flow restriction comprises at least one flow control valve. 18. The apparatus of claim 16 wherein the gas capacitance means has a volume 0.5 to 20 times greater than the volume of the first pressure swing adsorption vessel. 19. The apparatus of claim 15 wherein the first pressure swing adsorption vessel and the second pressure swing adsorption vessel contain carbon molecular sieve. 20. The apparatus of claim 15 wherein the middle portion of the first pressure swing adsorption vessel is in selective fluid communication with the first end portion of the second pressure swing adsorption vessel and wherein the second end portion of the first pressure swing adsorption vessel is in selective fluid communication with the second end portion of the second pressure swing adsorption vessel. 21. The apparatus of claim 15 further comprising: a particulate filter having an inlet and an outlet, the inlet of the particulate filter in fluid communication with the outlet of the means for moderating flow, the outlet in fluid communication with the inlet of the first distillation column. 22. The apparatus of claim 15 further comprising: a second distillation column having an inlet and an outlet, the inlet of the second distillation column in selective fluid communication with the second end of the first pressure swing adsorption vessel and in selective fluid communication with the second end of the second pressure swing adsorption vessel. 23. The apparatus of claim 22 further comprising: a purifier vessel containing a getter, the purifier vessel having an inlet and an outlet, the purifier vessel inlet in selective fluid communication with the second end portion of the first pressure swing adsorption vessel, the purifier outlet in fluid communication with the inlet of the second distillation column. 24. The method of claim 1 wherein, for at least 95% of a cycle time of the first pressure swing adsorption vessel, the at least a portion of the regulated depressurization gas has a molar flow rate within 66% and 200% of the time-averaged molar flow rate of the at least a portion of the regulated depressurization gas. 25. The method of claim 1 wherein, for at least 95% of a cycle time of the first pressure swing adsorption vessel, the at least a portion of the regulated depressurization gas has a molar flow rate within 80% and 120% of the time-averaged molar flow rate of the at least a portion of the regulated depressurization gas.