초록

Disclosed is a method for preparing polyolefins containing vinylidine end groups from quasiliving carbocationically terminated polyolefin polymers by contacting the quasiliving carbocationically terminated polymer with a suitable azole quenching agent and substituted derivatives thereof.

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What is claimed is: 1. A method for producing a vinylidene terminated polymer comprising: a. providing a quasiliving carbocationically terminated polyolefin polymer, b. contacting the polymer in step a) with a substituted azole quenching agent compound according to Formula I: wherein: R1 and R2

What is claimed is: 1. A method for producing a vinylidene terminated polymer comprising: a. providing a quasiliving carbocationically terminated polyolefin polymer, b. contacting the polymer in step a) with a substituted azole quenching agent compound according to Formula I: wherein: R1 and R2 are independently alkyl from 1 to 20 carbon atoms, cycloalkyl from about 3 to about 7 carbon atoms, aryl from 6 to about 20 carbon atoms, alkaryl from about 7 to 30 carbon atoms, aralkyl from about 7 to 30 atoms; or R1 and R2 together form a fused aromatic ring having from 6 to 10 carbon atoms which may be unsubstituted or substituted with 1 to 4 substituents selected independently from alkyl of one carbon atom to about 10 carbon atoms, cycloalkyl of about 3 to about 7 carbon atoms, aryl of about 6 to about 10 carbon atoms, alkaryl of about 7 to about 10 carbon atoms, aralkyl of about 7 to about 10 carbon atoms, alkoxy of about 1 to 6 carbon atoms, alkylthioether of about 1 to 6 carbon atoms, halo, or amino of the formula--NR*R**, where R* and R** are independently alkyl from about 4 to 10 carbon atoms, cycloalkyl of about 4 to about 7 carbon atoms, aryl of about 6 to about 10 carbon atoms, alkaryl of about 7 to about 10 carbon atoms, aralkyl of about 7 to about 10 carbon atoms; R is alkyl from 1 to 20 carbon atoms, cycloalkyl from about 3 to 7 carbon atoms, aryl from 6 to about 20 carbon atoms, alkaryl from about 7 to 30 carbon atoms, aralkyl from about 7 to 30 atoms, with the proviso that when R is methyl then R1 and R2 are independently selected from alkyl from 1 to 20 carbon atoms, cycloalkyl from about 3 to about 7 carbon atoms, aryl from 6 to about 20 carbon atoms, alkaryl from about 7 to 30 carbon atoms, aralkyl from about 7 to 30 atoms; and X is oxygen or sulfur. 2. The method of claim 1, wherein the quasiliving carbocationically terminated polymer is formed by contacting at least one cationically polymerizable olefin monomer with an initiator, in the presence of a Lewis acid and solvent under suitable quasiliving polymerization reaction conditions. 3. The method of claim 2, wherein the initiator is mono functional. 4. The method of claim 3, wherein the initiator is selected from the group consisting of 2-chloro-2-phenylpropane; 2-acetyl-2-phenylpropane; 2-propionyl-2-phenylpropane, 2-methoxy-2-phenylpropane, 2-ethoxy-2-phenylpropane, 2-chloro-2,4,4-trimethylpcntane, 2-acetyl-2,4,4,-trimethylpentane, 2-propionyl-2,4,4-trimethylpentane, 2-methoxy-2,4,4-trimethylpentane, and 2-ethoxy-2,4,4-trimethylpentane. 5. The method of claim 3, wherein the initiator is 2-chloro-2,4,4-trimethylpentane. 6. The method of claim 2, wherein the initiator is bifunctional. 7. The method of claim 6, wherein the initiator is selected from the group consisting of 1,3-di(2-chloro-2-propyl)benzene, 1 ,3-di(2-methoxy-2-propyl)benzene, 1,4-di(2-chloro-2-propyl)benzene, 1,4-di(2-methoxy-2-propyl)benzene, and 5-tert-butyl-1,3,-di(2-chloro-2-propyl) benzene. 8. The method of claim 7, wherein the initiator is 5-ter-butyl-1,3,-di(2-chloro-2-propyl) benzene. 9. The method of claim 2, wherein the initiator is multifunctional. 10. The method of claim 9, wherein the initiator is selected from the group consisting of 1,3,5-tri(2-chloro-2-propyl)benzene and 1,3,5-tri(2-methoxy-2-propyl)benzene. 11. The method of claim 2, wherein the at least one cationically polymerizable olefin monomer is selected from the group consisting of isobutene, 2-methyl-1-butene, 3-methyl-1-butene, and 4-methyl-1-pentene. 12. The method of claim 11, wherein the at least one cationically polymerizable olefin monomer is isobutylene. 13. The method of claim 2, wherein two different cationically polymerizable olefin monomers are employed. 14. The method of claim 2, wherein the Lewis acid is selected from the group consisting of titanium tetrahalide, boron trihalide, aluminum trichioride, tin tetrachioride, zinc chloride, and ethyl aluminum dichloride. 15. The method of claim 14, wherein the Lewis acid is selected from the group consisting of titanium tetrachloride, titanium tetrabromide, and boron trichioride. 16. The method of claim 15, wherein the Lewis acid is titanium tetrachloride. 17. The method of claim 2, wherein the quasiliving polymerization reaction conditions are selected to have a temperature range from between about-130�� C. and +10�� C. 18. The method of claim 17, wherein the quasiliving polymerization reaction conditions are selected to have a temperature range between-60�� C. and-10�� C. 19. The method of claim 18, wherein the quasiliving polymerization reaction conditions are selected to have a temperature range between-60�� C. and-20�� C. 20. The method of claim 1, wherein the quasiliving carbocationically terminated polyolefin polymer is formed by ionizing a polyolefin chain end in the presence of a Lewis acid and a solvent under suitable quasiliving polymerization reaction conditions. 21. The method of claim 20, wherein the quasiliving carbocationically terminated polyolefin polymer is formed by ionizing a polyolefin containing tert-halide chain ends in the presence of a Lewis acid and a solvent under suitable quasiliving polymerization reaction conditions. 22. The method of claim 20, wherein the quasiliving carbocationically terminated polyolefin polymer is formed by ionizing a polyolefin containing tert-chioride chain ends in the presence of a Lewis acid and a solvent under suitable quasiliving polymerization reaction conditions. 23. The method of claim 1 wherein R1 and R2 together form a fused aromatic ring having from 6 to 10 carbon atoms which is substituted with 1 to 4 substituents selected independently from alkyl of one carbon atom to about 10 carbon atoms, cycloalkyl of about 3 to about 7 carbon atoms, aryl of about 6 to about 10 carbon atoms, alkaryl of about 7 to about 10 carbon atoms, aralkyl of about 7 to about 10 carbon atoms. 24. The method of claim 1, wherein R is alkyl from 2 to 20 carbon atoms, cycloalkyl from about 3 to 7 carbon atoms, aryl from 6 to about 20 carbon atoms, alkaryl from about 7 to 30 carbon atoms, aralkyl from about 7 to 30 atoms. 25. The method of claim 1, wherein the contacting step is conducted under suitable reaction conditions to convert greater than 10 mole percent of the polymer in step a) to the vinylidene polymer product. 26. The method of claim 25, wherein the conversion is greater than 25 mole percent. 27. The method of claim 1, wherein the quenching agent in step b) is selected from the compound according to Formula I wherein: R1 and R2 are independently alkyl from 1 to 20 carbon atoms, aryl from 6 to about 20 carbon atoms, alkaryl from about 7 to 30 carbon atoms, aralkyl from about 7 to 30 atoms; or R1 and R2 together form a fused aromatic ring having from 6 to 10 carbon atoms; R is alkyl from 2 to 20 carbon atoms, aryl from 6 to about 20 carbon atoms, alkaryl from about 7 to 30 carbon atoms, aralkyl from about 7 to 30 atoms; and X is oxygen or sulfur. 28. The method of claim 27, wherein R1 and R2 are alkyl. 29. The method of claim 28, wherein X is oxygen. 30. The method of claim 28, wherein X is sulfur. 31. The method of claim 27, wherein the quenching agent in step b) is selected from the compound according to Formula II wherein R is alkyl from 2 to 20 carbon atoms, aryl from 6 to about 20 carbon atoms, alkaryl from about 7 to 30 carbon atoms, or aralkyl from about 7 to 30 atoms; and X is oxygen or sulfur. 32. The method of claim 31, wherein R is aryl, alkaryl, or aralkyl. 33. The method of claim 32, wherein the quenching agent is either 2-phenylbenzoxazole or 2-phenylbenzothiazole. 34. The method of claim 26 wherein the conversion is from 75 to 90 mole percent.