IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
UP-0345691
(2006-01-31)
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등록번호 |
US-RE40697
(2009-07-01)
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발명자
/ 주소 |
- Silvi, Norberto
- Giammattei, Mark Howard
- McCloskey, Patrick Joseph
- Nisoli, Alberto
- Day, James
- Ramesh, Narayan
- Smigelski, Jr., Paul Michael
- Wilson, Paul Russell
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출원인 / 주소 |
- Sabic Innovative Plastics IP B.V.
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대리인 / 주소 |
Marina Larson & Associates, LLC
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인용정보 |
피인용 횟수 :
1 인용 특허 :
31 |
초록
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This invention relates to an extrusion method preparing polycarbonates from a solution of an oligomeric polycarbonate. A mixture of bis(methyl salicyl)carbonate (BMSC), BPA and a transesterification catalyst are first equilibrated at moderate temperatures to provide a solution of polycarbonate oligo
This invention relates to an extrusion method preparing polycarbonates from a solution of an oligomeric polycarbonate. A mixture of bis(methyl salicyl)carbonate (BMSC), BPA and a transesterification catalyst are first equilibrated at moderate temperatures to provide a solution of polycarbonate oligomer in methyl salicylate. The solution is then fed to a devolatilizing extruder, where the polymerization reaction is completed and the methyl salicylate solvent is removed. The solution comprising the oligomeric polycarbonate can also be pre-heated under pressure to a temperature above the boiling point of methyl salicylate and subsequently fed to a devolatilizing extruder equipped for rapid flashing off the solvent. The method provides polycarbonate with greater efficiency than the corresponding process in which unreacted monomers are fed to the extruder. Additionally, the method of the invention does not require the isolation of a precursor polycarbonate comprising ester-substituted phenoxy terminal groups.
대표청구항
▼
What is claimed is: 1. A method for the preparation of polycarbonate, said method comprising extruding in the presence of a transesterification catalyst at one or more temperatures in a temperature range between about 100° C. and about 400° C. a solution comprising a solvent and an oligomeric polyc
What is claimed is: 1. A method for the preparation of polycarbonate, said method comprising extruding in the presence of a transesterification catalyst at one or more temperatures in a temperature range between about 100° C. and about 400° C. a solution comprising a solvent and an oligomeric polycarbonate, said extruding being carried out on an extruder equipped with at least one vent adapted for solvent removal, said oligomeric polycarbonate comprising polycarbonate repeat units derived from at least one dihydroxy aromatic compound, said oligomeric polycarbonate comprising ester substituted phenoxy terminal groups having structure I wherein R1 is a C1-C20 alkyl group, C4-C20 cycloalkyl group, or C4-C20 aryl group; R2 is independently each occurrence a halogen atom, cyano group, nitro group, C1-C20 alkyl group, C4-C20 cycloalkyl group, C4-C20 aryl group, C1-C20 alkoxy group, C4-C20 cycloalkoxy group, C4-C20 aryloxy group, C1-C20 alkylthio group, C4-C20 cycloalkylthio group, C4-C20 arylthio group, C1-C20 alkylsulfinyl group, C4-C20 cycloalkylsulfinyl group, C4-C20 arylsulfinyl group, C1-C20 alkylsulfonyl group, C4-C20 cycloalkylsulfonyl group, C4-C20 arylsulfonyl group, C1-C20 alkoxycarbonyl group, C4-C20 cycloalkoxycarbonyl group, C4-C20 aryloxycarbonyl group, C2-C60 alkylamino group, C6-C60 cycloalkylamino group, C5-C60 arylamino group, C1-C40 alkylaminocarbonyl group, C4-C40 cycloalkylaminocarbonyl group, C4-C40 arylaminocarbonyl group, or C1-C20 acylamino group; and b is an integer 0-4. 2. A method according to claim 1 wherein said ester substituted phenoxy terminal groups have structure II 3. A method according to claim 1 wherein said polycarbonate repeat units derived from at least one dihydroxy aromatic compound comprise repeat units having structure III wherein R3-R10 are independently a hydrogen atom, halogen atom, nitro group, cyano group, C1-C20 alkyl group, C4-C20 cycloalkyl group, or C6-C20 aryl group; W is a bond, an oxygen atom, a sulfur atom, a SO2 group, a C1-C20 aliphatic radical, a C6-C20 aromatic radical, a C6-C20 cycloaliphatic radical, or the group wherein R11 and R12 are independently a hydrogen atom, C1-C20 alkyl group, C4-C20 cycloalkyl group, or C4-C20 aryl group; or R11 and R12 together form a C4-C20 cycloaliphatic ring which is optionally substituted by one or more C1-C20 alkyl, C6-C20 aryl, C5-C21 aralkyl, C5-C20 cycloalkyl groups, or a combination thereof. 4. A method according to claim 1 wherein said polycarbonate repeat units derived from at least one dihydroxy aromatic compound comprise repeat units derived from bisphenol A, said bisphenol A derived repeat units having structure IV, and optionally repeat units having structure V 5. A method according to claim 1 wherein said solvent comprises from about 10 to about 99 percent by weight of said solution. 6. A method according to claim 1 wherein said solvent comprises at least one ester substituted phenol having structure VI wherein R1 is a C1-C20 alkyl group, C4-C20 cycloalkyl group, or C4-C20 aryl group; R2 is independently at each occurrence a halogen atom, cyano group, nitro group, C1-C20 alkyl group, C4-C20 cycloalkyl group, C4-C20 aryl group, C1-C20 alkoxy group, C4-C20 cycloalkoxy group, C4-C20 aryloxy group, C1-C20 alkylthio group, C4-C20 cycloalkylthio group, C4-C20 arylthio group, C1-C20 alkylsulfinyl group, C4-C20 cycloalkylsulfinyl group, C4-C20 arylsulfinyl group, C1-C20 alkylsulfonyl group, C4-C20 cycloalkylsulfonyl group, C4-C20 arylsulfonyl group, C1-C20 alkoxycarbonyl group, C4-C20 cycloalkoxycarbonyl group, C4-C20 aryloxycarbonyl group, C2-C60 alkylamino group, C6-C60 cycloalkylamino group, C5-C60 arylamino group, C1-C40 alkylaminocarbonyl group, C4-C40 cycloalkylaminocarbonyl group, C4-C40 arylaminocarbonyl group, or C1-C20 acylamino group; and b is an integer 0-4. 7. A method according to claim 6 wherein said solvent further comprises a halogenated aromatic solvent, a halogenated aliphatic solvent, a non-halogenated aromatic solvent, a non-halogenated aliphatic solvent, or a mixture thereof. 8. A method according to claim 1 wherein said solvent comprises methyl salicylate. 9. A method according to claim 8 wherein said solvent further comprises ortho-dichlorobenzene. 10. A method according to claim 1 wherein said transesterification catalyst comprises a quaternary ammonium compound, a quaternary phosphonium compound, or a mixture thereof. 11. A method according to claim 10 wherein said quaternary ammonium compound has structure VII wherein R13-R16 are independently a C1-C20 alkyl group, C4-C20 cycloalkyl group, or a C4-C20 aryl group; and X- is an organic or inorganic anion. 12. A method according to claim 11 wherein said anion is selected from the group consisting of hydroxide, halide, carboxylate, phenoxide, sulfonate, sulfate, carbonate, and bicarbonate. 13. A method according to claim 11 wherein said quaternary ammonium compound is tetramethylammonium hydroxide. 14. A method according to claim 10 wherein said phosphonium compound has structure VIII wherein R17-R20 are independently a C1-C20 alkyl group, C4-C20 cycloalkyl group, or a C4-C20 aryl group; and X- is an organic or inorganic anion. 15. A method according to claim 14 wherein said anion is selected from the group consisting of hydroxide, halide, carboxylate, phenoxide sulfonate, sulfate, carbonate, and bicarbonate. 16. A method according to claim 14 wherein said quaternary phosphonium compound is tetrabutylphosphonium acetate. 17. A method according to claim 10 wherein said transesterification catalyst further comprises at least one alkali metal hydroxide, alkaline earth hydroxide, or mixture thereof. 18. A method according to claim 1 wherein said transesterification catalyst comprises at least one alkali metal hydroxide, at least one alkaline earth hydroxide, or mixture thereof. 19. A method according to claim 18 wherein said alkali metal hydroxide is sodium hydroxide. 20. A method according to claim 1 wherein said transesterification catalyst comprises at least one alkali metal salt of a carboxylic acid, alkaline earth salt of a carboxylic acid, or a mixture thereof. 21. A method according to claim 20 in which said alkali metal salt of a carboxylic acid is Na2Mg EDTA. 22. A method according to claim 1 wherein said transesterification catalyst comprises at least one salt of a non-volatile inorganic acid. 23. A method according to claim 22 wherein said salt of a non-volatile acid is at least one salt selected from the group consisting of NaH2PO3, NaH2PO4, Na2HPO4, KH2PO4, CaH2PO4, Cs2HPO4, NaKHPO4, NaCsHPO4, and KCsHPO4. 24. A method according to claim 1 wherein said transesterification catalyst is present in an amount corresponding to between about 1.0×10-8 and about 1×10-3 moles of transesterification catalyst per mole of polycarbonate repeat units derived from aromatic dihydroxy compound present in the oligomeric polycarbonate. 25. A method according to claim 1 wherein said solution further comprises a monofunctional phenol chainstopper. 26. A method according to claim 25 wherein said chainstopper is p-cumylphenol. 27. A method according to claim 1 wherein said extruder has a screw speed, said solution being introduced into said extruder at a feed rate, said feed rate and said screw speed having a ratio, said extruder being operated such that the ratio of feed rate is pounds per hour to the screw speed expressed in revolutions per minute falls within a range of from about 0.01 to about 100. 28. A method according to claim 27 wherein the screw speed is in a range between about 50 and about 1200 revolutions per minute. 29. A method according to claim 27 wherein said extruder is equipped with at least one vacuum vent. 30. A method according to claim 27 wherein said extruder is selected from the group consisting of a co-rotating intermeshing double screw extruder, a counter-rotating non-intermeshing double screw extruder; a single screw reciprocating extruder, and a single screw non-reciprocating extruder. 31. A method according to claim 1 further comprising the steps of Step (A) heating the solution comprising the solvent and the oligomeric polycarbonate to a temperature greater than the boiling point of said solvent, said boiling point being the boiling point of said solvent at atmospheric pressure, said heating being carried out at a pressure greater than atmospheric pressure to provide a superheated mixture of oligomeric polycarbonate and solvent; and Step (B) introducing said superheated mixture of oligomeric polycarbonate and solvent into the extruder through at least one pressure control valve. 32. A method according to claim 31 wherein said extruder is selected from the group consisting of a co-rotating intermeshing double screw extruder, a counter-rotating non-intermeshing double screw extruder, a single screw reciprocating extruder, and a single screw non-reciprocating extruder. 33. A method according to claim 31 wherein said extruder is equipped with at least one vacuum vent and optionally one or more vents operated at about atmospheric pressure, said extruder being equipped with at least one side feeder, said side feeder being equipped with at least one vent, said vent being operated at atmospheric pressure. 34. A method according to claim 33 wherein said extruder is selected from the group consisting of a co-rotating, intermeshing double screw extruder, a counter-rotating, non-intermeshing double screw extruder, a single screw reciprocating extruder, and a single screw non-reciprocating extruder. 35. A method according to claim 1 further comprising removing a product polycarbonate from said extruder. 36. A method according to claim 35 wherein said product polycarbonate is introduced into a second extruder, said second extruder comprising at least one vacuum vent, said second extruder being operated at a temperature in a range between about 100° C. and about 400° C., and a screw speed in a range between about 50 rpm and about 1200 rpm. 37. A method according to claim 36 wherein said second extruder is selected from the group consisting of a co-rotating intermeshing double screw extruder, a counter-rotating non-intermeshing double screw extruder, a single screw reciprocating extruder, and a single screw non-reciprocating extruder. 38. A method for preparing polycarbonate, said method comprising: Step (I) heating a mixture comprising at least one dihydroxy aromatic compound, an ester substituted diaryl carbonate and a transesterification catalyst at a temperature in a range between about 100° C. and about 300° C. to provide a solution of an oligomeric polycarbonate in an ester substituted phenol solvent; and Step (II) extruding said solution of oligomeric polycarbonate in said ester substituted phenol at one or more temperatures in a range between about 100° C. and about 400° C., and at one or more screw speeds in a range between about 50 and about 1200 rpm, said extruding being carried out on an extruder comprising at least one vent adapted for solvent removal. 39. A method corresponding to claim 38 wherein in Step (I) the ester substituted diaryl carbonate is employed in an amount corresponding to between about 0.95 and about 1.05 moles per mole of said dihydroxy aromatic compound. 40. A method according to claim 38 wherein said transesterification catalyst is present in an amount corresponding to between about 1.0×10-8 and about 1×10-3 moles of transesterification catalyst per mole of said dihydroxy aromatic compound. 41. A method according to claim 38 wherein said ester-substituted diaryl carbonate has structure IX wherein R1 is independently at each occurrence C1-C20 alkyl group, C4-C20 cycloalkyl group, or C4-C20 aryl group; R2 is independently at each occurrence a halogen atom, cyano group, nitro group, C1-C20 alkyl group, C4-C20 cycloalkyl group, C4-C20 aryl group, C1-C20 alkoxy group, C4-C20 cycloalkoxy group, C4-C20 aryloxy group, C1-C20 alkylthio group, C4-C20 cycloalkylthio group, C4-C20 arylthio group, C1-C20 alkylsulfinyl group, C4-C20 cycloalkylsulfinyl group, C4-C20 arylsulfinyl group, C1-C20 alkylsulfonyl group, C4-C20 cycloalkylsulfonyl group, C4-C20 arylsulfonyl group, C1-C20 alkoxycarbonyl group, C4-C20 cycloalkoxycarbonyl group, C4-C20 aryloxycarbonyl group, C2-C60 alkylamino group, C6-C60 cycloalkylamino group, C5-C60 arylamino group, C1-C40 alkylaminocarbonyl group, C4-C40 cycloalkylaminocarbonyl group, C4-C40 arylaminocarbonyl group, or C1-C20 acylamino group; and b is independently at each occurrence an integer 0-4. 42. A method according to claim 41 wherein said ester substituted diaryl carbonate is bis(methyl salicyl)carbonate. 43. A method according to claim 38 wherein said dihydroxy aromatic compound has structure X wherein R3-R10 are independently a hydrogen atom, halogen atom, nitro group, cyano group, C1-C20 alkyl group, C4-C20 cycloalkyl group, or C6-C20 aryl group; W is a bond, an oxygen atom, a sulfur atom, a SO2 group, a C1-C20 aliphatic radical, a C6-C20 aromatic radical, a C6-C20 cycloaliphatic radical, or the group wherein R11 and R12 are independently a hydrogen atom, C1-C20 alkyl group, C4-C20 cycloalkyl group, or C4-C20 aryl group; or R11 and R12 together form a C4-C20 cycloaliphatic ring which is optionally substituted by one or more C1-C20 alkyl, C6-C20 aryl, C5-C21 aralkyl, C5-C20 cycloalkyl groups, or a combination thereof. 44. A method according to claim 38 wherein said at least one dihydroxy aromatic compound comprises hydroquinone and bisphenol A. 45. A product polycarbonate prepared by the method of claim 44. 46. A molded article comprising the polycarbonate of claim 45. 47. A method according to claim 38 wherein said at least one dihydroxy aromatic compound comprises bisphenol A and 4,4'-sulfonyldiphenol. 48. A product polycarbonate prepared by the method of claim 47. 49. A molded article comprising the polycarbonate of claim 48. 50. A method for preparing polycarbonate, said method comprising: Step (I) heating a mixture of bisphenol A, bis(methyl salicyl)carbonate and a transesterification catalyst at a temperature in a range between 100° C. and 300° C. a pressure between about 0.1 and about 10 atmospheres to provide a solution of an oligomeric bisphenol A polycarbonate in methyl salicylate, said bis(methyl salicyl)carbonate being present in an amount corresponding to between about 0.95 and about 1.05 moles bis(methylsalicyl)carbonate per mole bisphenol A, said transesterification catalyst being present in an amount corresponding to between 1×10-8 and 1×10-3 moles transesterification catalyst per mole bisphenol A, said oligomeric polycarbonate comprising methoxy carbonyl phenoxy terminal groups; and Step (II) extruding said solution of oligomeric bisphenol A polycarbonate in methyl salicylate at one or more temperatures in a range between about 100° C. and about 400° C., and at one or more screw seeds in a range between about 50 and about 1200 rpm. 51. A method according to claim 50 wherein the transesterification catalyst comprises tetrabutylphosphonium acetate. 52. A polycarbonate prepared by the method of claim 50, said polycarbonate comprising less than 10 ppm Fries product. 53. A polycarbonate according to claim 50, said polycarbonate having a percent endcapping of about at least 90 percent. 54. A polycarbonate according to claim 50, said polycarbonate having a percent endcapping of about at least 97 percent. 55. A molded article comprising the polycarbonate of claim 50. 56. A molded article according to claim 55 which is an optical disk. 57. A method for the preparation of polycarbonate, said method comprising extruding in the presence of a transesterification catalyst at one or more temperatures in a temperature range between about 100° C. and about 400° C. a solution comprising a solvent and a polycarbonate, said extruding being carried out on an extruder equipped with at least one vent adapted for solvent removal, said polycarbonate comprising polycarbonate repeat units derived from at least one dihydroxy aromatic compound, said polycarbonate comprising ester substituted phenoxy terminal groups having structure I wherein R1 is a C1-C20 alkyl group, C4-C20 cycloalkyl group, or C4-C20 aryl group; R2 is independently at each occurrence a halogen atom, cyano group, nitro group, C1-C20 alkyl group, C4-C20 cycloalkyl group, C4-C20 aryl group, C1-C20 alkoxy group, C4-C20 cycloalkoxy group, C4-C20 aryloxy group, C1-C20 alkylthio group, C4-C20 cycloalkylthio group, C4-C20 arylthio group, C1-C20 alkylsulfinyl group, C4-C20 cycloalkylsulfinyl group, C4-C20 arylsulfinyl group, C1-C20 alkylsulfonyl group, C4-C20 cycloalkylsulfonyl group, C4-C20 arylsulfonyl group, C1-C20 alkoxycarbonyl group, C4-C20 cycloalkoxycarbonyl group, C4-C20 aryloxycarbonyl group, C2-C60 alkylamino group, C6-C60 cycloalkylamino group, C5-C60 arylamino group, C1-C40 alkylaminocarbonyl group, C4-C40 cycloalkylaminocarbonyl group, C4-C40 arylaminocarbonyl group, or C1-C20 acylamino group; and b is an integer 0-4. 58. A method according to claim 57 wherein said polycarbonate has a number average molecular weight of at least 5000 daltons. 59. A method of forming a polycarbonate wherein the method comprises, extruding in the presence of a transesterification catalyst at one or more temperatures in a temperature range between about 100° C. and about 400° C. a solution comprising a solvent and an oligomeric polycarbonate, said extruding being carried out on an extruder equipped with at least one vent adapted for solvent removal, said oligomeric polycarbonate comprising polycarbonate repeat units of structure III: wherein R3-R10 are independently a hydrogen atom, halogen atom, nitro group, cyano group, C1-C20 alkyl group, C1-C20 cycloalkyl group, or C6-C20 aryl group; and W is a SO2 group, said oligomeric polycarbonate comprising ester substituted phenoxy terminal groups having structure I wherein R1 is a C1-C20 alkyl group, C1-C20 cycloalkyl group, or C1-C20 aryl group; R2 is independently at each occurrence a halogen atom, cyano group, nitro group, C1-C20 alkyl group, C1-C20 cycloalkyl group, C4-C20 aryl group, C1-C20 alkoxy group, C1-C20 cycloalkoxy group, C1-C20 aryloxy group, C1-C20 alkylthio group, C1-C20 cycloalkylthio group, C1-C20 arylthio group, C1-C20 alkylsulfinyl group, C4-C20 cycloalkylsulfinyl group, C4-C20 arylsulfinyl group, C1-C20 alkylsulfonyl group, C1-C20 cycloalkylsulfonyl group, C1-C20 arylsulfonyl group, C1-C20 alkoxycarbonyl group, C1-C20 cycloalkoxycarbonyl group, C1-C20 aryloxycarbonyl group, C3-C60 alkylamino group, C6-C60 cycloalkylamino group, C5-C60 arylamino group, C1-C40 alkylaminocarbonyl group, C4-C40 cycloalkylaminocarbonyl group, C4-C40 arylaminocarbonyl group, or C1-C20 acylamino group; and b is an integer 0-4, said solvent comprising an ester substituted phenol having structure VI, wherein R1 and R2 are defined above. 60. A method according to claim 59, wherein the repeat units having structure III are compounds of structure V: 61. A method according to claim 59 wherein said polycarbonate repeat units further comprise repeat units derived from bisphenol A, said bisphenol A derived repeat units having structure IV, 62. A method according to claim 61 wherein the repeat units having structure III are compounds of structure V: 63. A method for preparing polycarbonate, said method comprising: Step (I) heating a mixture comprising a dihydroxy aromatic compound, an ester substituted diaryl carbonate and a transesterification catalyst at a temperature in a range between about 100° C. and about 300° C. to provide a solution of an oligomeric polycarbonate in an ester substituted phenol solvent, wherein the dihydroxy compound has the structure, wherein R3-R10 are independently a hydrogen atom, halogen atom, nitro group, cyano group, C4-C20 alkyl group, C1-C20 cycloalkyl group, or C6-C20 aryl group; and W is a SO2 group; and Step (II) extruding said solution of oligomeric polycarbonate in said ester substituted phenol at one or more temperatures in a range between about 100° C. and about 400° C., and at one or more screw speeds in a range between about 50 and about 1200 rpm, said extruding being carried out on an extruder comprising at least one vent adapted for solvent removal. 64. A method according to claim 63, wherein the dihydroxy aromatic compound comprises 4,4'-sulfonyldiphenol. 65. The method of claim 64, wherein the mixture further comprises a second dihydroxy aromatic compound, wherein the second dihydroxy aromatic compound comprises bisphenol A. 66. The method of claim 63, wherein the mixture further comprises a second dihydroxy aromatic compound, wherein the second dihydroxy aromatic compound comprises bisphenol A. 67. A method for preparing polycarbonate, said method comprising: Step (I) heating a mixture of bisphenol A and 4,4'-sulfonyldiphenol, bis(methyl salicyl)carbonate and a transesterification catalyst at a temperature in a range between 100° C. and 300° C., a pressure between about 0.1 and about 10 atmospheres to provide a solution of an oligomeric bisphenol A and 4,4'-sulfonyldiphenol copolycarbonate in methyl salicylate, said bis(methyl salicyl)carbonate being present in an amount corresponding to between about 0.95 and about 1.05 moles bis(methyl salicyl)carbonate per (mole bisphenol A+mole 4,4'-sulfonyldiphenol), said transesterification catalyst being present in an amount corresponding to between 1×10-8 and 1×10-3 moles transesterification catalyst per (mole bisphenol A+mole 4,4'-sulfonyldiphenol), said oligomeric polycarbonate comprising methoxy carbonyl phenoxy terminal groups; and Step (II) extruding said solution of oligomeric bisphenol A and 4,4'-sulfonyldiphenol copolycarbonate in methyl salicylate at one or more temperatures in a range between about 100° C. and about 400° C., and at one or more screw speeds in a range between about 50 and about 1200 rpm. 68. A method for the preparation of polycarbonate, said method comprising extruding in the presence of a transesterification catalyst at one or more temperatures in a temperature range between about 100° C. and about 400° C. a solution comprising a solvent and a polycarbonate, said extruding being carried out on an extruder equipped with at least one vent adapted for solvent removal, said polycarbonate comprising polycarbonate repeat units derived from a dihydroxy aromatic compound having the structure, wherein R3-R10 are independently a hydrogen atom, halogen atom, nitro group, cyano group, C1-C20 alkyl group, C4-C20 cycloalkyl group, or C6-C20 aryl group; and W is a SO2 group; said polycarbonate comprising ester substituted phenoxy terminal groups having structure I, wherein R1 is a C1-C20 alkyl group, C1-C20 cycloalkyl group, or C1-C20 aryl group; R2 is independently at each occurrence a halogen atom, cyano group, nitro group, C1-C20 alkyl group, C1-C20 cycloalkyl group, C4-C20 aryl group, C1-C20 alkoxy group, C1-C20 cycloalkoxy group, C1-C20 aryloxy group, C1-C20 alkylthio group, C1-C20 cycloalkylthio group, C1-C20 arylthio group, C1-C20 alkylsulfinyl group, C4-C20 cycloalkylsulfinyl group, C4-C20 arylsulfinyl group, C1-C20 alkylsulfonyl group, C1-C20 cycloalkylsulfonyl group, C1-C20 arylsulfonyl group, C1-C20 alkoxycarbonyl group, C4-C20 cycloalkoxycarbonyl group, C4-C20 aryloxycarbonyl group, C2-C60 alkylamino group, C6-C60 cycloalkylamino group, C5-C60 arylamino group, C1-C40 alkylaminocarbonyl group, C4-C40 cycloalkylaminocarbonyl group, C4-C40 arylaminocarbonyl group, or C1-C20 acylamino group; and b is an integer 0-4. 69. A composition comprising: (a) a polycarbonate comprising repeat units of structure III: wherein R3-R10 are independently a hydrogen atom, halogen atom, nitro group, cyano group, C1-C20 alkyl group, C4-C20 cycloalkyl group, or C6-C20 aryl group; and W is a SO2 group, (b) a residue indicative of an ester substituted diaryl carbonate used in a melt transesterification reaction to produce the polycarbonate, wherein the residue indicative of an activated diaryl carbonate is selected from the group consisting of: (i) polymer units within the polycarbonate having the structure, wherein R1 is a C1-C20 alkyl group, C4-C20 cycloalkyl group, or C4-C20 aryl group; R2 is independently at each occurrence a halogen atom, cyano group, nitro group, C1-C20 alkyl group, C1-C20 cycloalkyl group, C4-C20 aryl group, C1-C20 alkoxy group, C1-C20 cycloalkoxy group, C1-C20 aryloxy group, C1-C20 alkylthio group, C4-C20 cycloalkylthio group, C4-C20 arylthio group, C1-C20 alkylsulfinyl group, C4-C20 cycloalkylsulfinyl group, C4-C20 arylsulfinyl group, C1-C20 alkylsulfonyl group, C4-C20 cycloalkylsulfonyl group, C4-C20 arylsulfonyl group, C1-C20 alkoxycarbonyl group, C4-C20 cycloalkoxycarbonyl group, C4-C20 aryloxycarbonyl group, C2-C60 alkylamino group, C6-C60 cycloalkylamino group, C5-C60 arylamino group, C1-C40 alkylaminocarbonyl group, C4-C40 cycloalkylaminocarbonyl group, C4-C40 arylaminocarbonyl group, or C1-C20 acylamino group; and b is an integer 0-4, (ii) oligomers within the composition with oligomer units having the structure, wherein R1 and R2 are defined above, (iii) an ester-substituted phenol within the composition having the structure, wherein R1 and R2 are defined above, and (iv) an ester substituted diaryl carbonate within the composition having the structure, wherein R1 and R2 are defined above. 70. The composition of claim 69, wherein the repeat units having structure III are compounds of structure V: 71. The composition of claim 70, wherein the polycarbonate further comprises repeat units derived from bisphenol A, said bisphenol A derived repeat units having structure IV, 72. The composition of claim 69, wherein the polycarbonate further comprises repeat units derived from bisphenol A, said bisphenol A derived repeat units having structure IV, 73. The composition of claim 69, wherein residue (iii) is present and is methyl salicylate. 74. The composition of claim 69, wherein residue (iv) is present and is bismethylsalicylcarbonate.
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