초록 ▼

The present invention provides systems and methods to improve the performance and emission control of internal combustion engines equipped with nitrogen oxides storage-reduction ("NSR") emission control systems. The system generally includes a NSR catalyst, a fuel processor located upstream of the N

The present invention provides systems and methods to improve the performance and emission control of internal combustion engines equipped with nitrogen oxides storage-reduction ("NSR") emission control systems. The system generally includes a NSR catalyst, a fuel processor located upstream of the NSR catalyst, and at least one fuel injection port. The fuel processor converts a fuel into a reducing gas mixture comprising CO and H2. The reducing gas mixture is then fed into the NSR catalyst, where it regenerates the NSR adsorbent, reduces the NOx to nitrogen, and optionally periodically desulfates the NSR catalyst. The fuel processor generally includes one or more catalysts, which facilitate reactions such as combustion, partial oxidation, and/or reforming and help consume excess oxygen present in an engine exhaust stream. The methods of the present invention provide for NSR catalyst adsorbent regeneration using pulsed fuel flow. Control strategies are also provided.

대표청구항 ▼

What we claim is: 1. A method of generating reductant in at least a portion of an exhaust stream comprising: injecting fuel into the exhaust stream upstream of a fuel processor, wherein the fuel processor comprises an inlet, an outlet, and at least one steam reforming catalyst, and the exhaust stre

What we claim is: 1. A method of generating reductant in at least a portion of an exhaust stream comprising: injecting fuel into the exhaust stream upstream of a fuel processor, wherein the fuel processor comprises an inlet, an outlet, and at least one steam reforming catalyst, and the exhaust stream comprises oxygen, whereby the injection of fuel leaves the exhaust stream overall lean and rapidly increases the temperature of at least a portion of the fuel processor to within the range from about 500° C. to about 750° C.; implementing one or a combination of strategies selected from the group consisting of increasing the fuel injection rate, decreasing the oxygen concentration in the exhaust stream, and decreasing the exhaust flow, to obtain rich conditions on at least a portion of the fuel processor catalyst; and allowing the fuel and exhaust stream mixture to react within the at least one fuel processor catalyst to generate a reducing gas mixture comprising CO and H2; wherein the exhaust upstream from the fuel processor is at a temperature of 300° C. or less and the fuel processor has a thermal mass sufficiently low that at least a portion of the fuel processor heats to within the range from about 500° C. to about 750° C. in 12 seconds or less. 2. The method of claim 1 wherein the fuel processor is operated within a temperature range of about 600° C. to about 750° C. 3. The method of claim 1 wherein the fuel processor comprises at least two distinct catalyst washcoats, at least one washcoat comprising and effect amount of a reforming catalyst and the other washcoat comprising an effective amount of an oxidation catalyst. 4. The method of claim 1 wherein the fuel is injected intermittently. 5. The method of claim 1, wherein the exhaust upstream from the fuel processor is at a temperature of 250° C. or less and the fuel processor has a thermal mass sufficiently low that at least a portion of the fuel processor heats to within the range from about 500° C. to about 750° C. in 10 seconds or less. 6. A method of operating a nitrogen oxide storage-reduction catalyst, comprising: treating an exhaust stream by trapping nitrogen oxide from the exhaust stream using the nitrogen oxide storage-reduction catalyst; detecting a need to reduce a nitrogen oxide storage amount in the nitrogen oxide storage-reduction catalyst; in response to the need, generating reductant in at least a portion of the exhaust stream according to the method of claim 1. 7. The method of claim 1, further comprising detecting a temperature of the fuel processor; and controlling the temperature of the fuel processor by varying the fuel injection rate. 8. The method of claim 1 wherein the exhaust oxygen concentration is adjusted to a range of about 2% to about 8% during the period when the fuel processor is under rich conditions. 9. The method of claim 8 wherein the oxygen concentration in the exhaust stream is adjusted by changing the rate of exhaust gas recirculation or by throttling the intake engine air flow. 10. The method of claim 1, further comprising: regenerating a nitrogen storage reduction catalyst using the reducing gas mixture; wherein the regeneration and the fuel processor warm-up are completed in 10 seconds or less. 11. The method of claim 10, wherein the fuel processor temperature is controlled while allowing the fuel and exhaust stream mixture to react within the at least one fuel processor catalyst to generate a reducing gas mixture comprising CO and H2.