Bioplastics, monomers thereof, and processes for the preparation thereof from agricultural feedstocks
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C07C-051/34
C07C-045/40
C07C-045/00
C07C-059/147
C07C-059/00
출원번호
UP-0649620
(2007-01-04)
등록번호
US-7538236
(2009-07-01)
발명자
/ 주소
Narine, Suresh
Sporns, Peter
Yue, Jin
대리인 / 주소
Hagan, Patrick J.
인용정보
피인용 횟수 :
2인용 특허 :
25
초록▼
The present invention relates generally to polymers and monomers derived from agricultural feedstocks, and more particularly to methods for the production of monomers from renewable agricultural resources such as feedstocks, for example canola, flax and tallow, and polymers, in particular polyuretha
The present invention relates generally to polymers and monomers derived from agricultural feedstocks, and more particularly to methods for the production of monomers from renewable agricultural resources such as feedstocks, for example canola, flax and tallow, and polymers, in particular polyurethanes produced from monomers derived from such feedstocks. The present invention also relates to novel processes for the production of short-chain alcohols, as well as hydroxyl wax esters, from renewable feedstocks. An improved apparatus for carrying out ozonolysis reactions is also disclosed.
대표청구항▼
The invention claimed is: 1. A method for producing a polyol from a renewable feedstock comprising one or more unsaturated fatty acid triacylglycerols, wherein the method comprises the steps of: (a) dissolving the feedstock in a solvent consisting of ethyl acetate to form a solution; (b) supplying
The invention claimed is: 1. A method for producing a polyol from a renewable feedstock comprising one or more unsaturated fatty acid triacylglycerols, wherein the method comprises the steps of: (a) dissolving the feedstock in a solvent consisting of ethyl acetate to form a solution; (b) supplying the solution of (a) with ozone to effect ozonolysis of two or more double bonds in the unsaturated fatty acids of the one or more triacylglycerols of the feedstock; (c) subjecting the solution containing the products of step (b) directly to reductive hydrogenation, without an intervening reduction step, under conditions effective to produce one or more corresponding polyols, wherein the one or more polyols comprise at least one triacylglycerol containing at least two primary hydroxyl groups. 2. The method of claim 1, wherein the one or more polyols comprise one or more dihydroxyl functionalized triacylglycerols, or one or more trihydroxyl functionalized triacylglycerols, or mixtures thereof. 3. The method of claim 1, wherein the feedstock comprises a vegetable oil or tallow. 4. The method of claim 2, wherein the vegetable oil is selected from the group comprising canola, linseed, sunflower, tung, lesqueralla, flaxseed, Jatupha, camelina sativa, hump, peanut, palm, soybean, cottonseed, corn, cashew nuts, calendula, mustard, sesame, safflower, sunflower, rapeseed, olive, castor, jojoba, brazil nuts, avocado, and kenaf. 5. The method of claim 1, wherein ozone used in the ozonolysis step (b) is substantially uniformly distributed throughout the reaction mixture. 6. The method of claim 1, wherein the ozonolysis conditions are selected to optimize the primary hydroxyl functionality of the one or more polyols. 7. The method of claim 6, wherein the ozonolysis conditions comprise ozonolysis time, ozone flow rate, and concentration of the renewable feedstock. 8. The method of claim 1, further comprising the step of isolating the one or more polyols from the reaction mixture of step (c). 9. The method of claim 8, wherein the one or more polyols are isolated in greater than about 90% purity relative to non-polyol components contained in or produced during the production of the one or more polyols. 10. The method of claim 1 wherein the ozonolysis reaction is performed at or above 0° C. 11. The method of claim 10, wherein the ozonolysis reaction is performed at room temperature. 12. The method of claim 8, wherein the separation step comprises the use of silica gel chromatography. 13. The method of claim 1, wherein said method further comprises the production of one or more short chain alcohols as a by-product, and said one or more short chain alcohols is separated from the one or more polyols. 14. The method of claim 13, wherein said separation of said one or more short chain alcohol by-products from the one or more polyols is carried out prior to isolating the one or more polyols from the reaction mixture of step (c). 15. The method of claim 13 or 14, wherein said separation of said one or more short chain alcohol by-products from the one or more polyols comprises the use of wiped-blade molecular distillation. 16. A method for producing nonanol, hexanol, propanol, and/or 1,3-propanediol from a renewable feedstock comprising a fatty acid triacylglycerol having at least one unsaturated fatty acid chain, the method comprising the steps of: (a) dissolving the feedstock in a solvent consisting of ethyl acetate to form a solutions; (b) supplying the solution of (a) with ozone to effect ozonolysis of the double bonds in the fatty acid chain of the triacylglycerol of the feedstock; (c) subjecting the solution containing the products of step (b) directly to reductive hydrogenation, without an intervening reduction step, to produce nonanol, hexanol, propanol, and/or 1,3-propanediol; and (d) separating nonanol, hexanol, propanol, and/or 1,3-propanediol from the products of step (c) by wiped-blade molecular distillation. 17. The method of claim 16, wherein the feedstock comprises canola oil.
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