Catalytic material and method of production thereof
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C07C-011/24
C07C-011/00
B01D-053/02
B01J-023/00
B01J-021/00
출원번호
UP-0885968
(2004-07-07)
등록번호
US-7541012
(2009-07-01)
발명자
/ 주소
Yeung, King Lun
Yao, Nan
Ho, Ka Yee
출원인 / 주소
The Hong Kong University of Science and Technology
대리인 / 주소
Wilkinson & Grist
인용정보
피인용 횟수 :
72인용 특허 :
19
초록▼
The present invention features a catalytic material which includes a metal catalyst anchored to a nano-sized crystal containing a metal oxide. Furthermore, the present invention features a method of producing the catalytic material described herein. Finally, the present invention features using the
The present invention features a catalytic material which includes a metal catalyst anchored to a nano-sized crystal containing a metal oxide. Furthermore, the present invention features a method of producing the catalytic material described herein. Finally, the present invention features using the catalytic material for removing contaminants and for getting the desired products.
대표청구항▼
We claim: 1. A catalytic material, comprising: a first metal oxide and a metal catalyst, wherein the first metal oxide comprises nano-sized crystal particles having (a) size of about 4 to about 15 nm; (b) crystallinity greater than about 60%; and (c) a surface of hydration of about 5 to about 100 m
We claim: 1. A catalytic material, comprising: a first metal oxide and a metal catalyst, wherein the first metal oxide comprises nano-sized crystal particles having (a) size of about 4 to about 15 nm; (b) crystallinity greater than about 60%; and (c) a surface of hydration of about 5 to about 100 mg per gram of the dry metal oxide; wherein the metal catalyst comprises a transitional metal; and wherein at least about 70% of the first metal oxide comprises an anatase crystal structure. 2. The catalytic material of claim 1, wherein the first metal oxide comprises TiO2. 3. The catalytic material of claim 1, wherein the metal catalyst comprises one metal selected from the group consisting of Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt, Au, Ag, and Cu. 4. A process of producing the catalytic material of claim 1, comprising: (a) forming amorphous material of a first metal oxide; (b) crystallizing said first metal oxide into particles of about 4 to about 15 nm; (c) controlling the level of surface hydration of said metal oxide particle to a range of about 5 to about 100 mg per gram of the dry first metal oxide; (d) depositing a metal catalyst precursor to the first metal oxide from (c); and (e) converting the metal catalyst precursor to a metal catalyst. 5. A method of purifying air by removing contaminants containing organic, inorganic, and/or biological species in the air, the method comprising contacting the contaminants with the catalytic material of claim 1. 6. A catalytic material, comprising: TiO2 and a metal catalyst comprising Au, wherein the TiO2 has (a) size of about 4 to about 15 nm; (b) crystallinity greater than about 60%; and (c) a surface of hydration of about 5 to about 100 mg per gram of the dry metal oxide; wherein at least about 70% of the TiO2 comprises an anatase crystal structure. 7. A catalytic material, comprising: a first metal oxide, a second metal oxide and a metal catalyst; wherein the first metal oxide comprises nano-sized crystal particles having (a) size of about 4 to about 15 nm; (b) crystallinity greater than about 60%; and (c) a surface of hydration of about 5 to about 100 mg per gram of the dry first metal oxide; wherein the second metal oxide is deposited onto the surface of the first metal oxide and forms monomeric or oligomeric form on the surface of the first metal oxide; wherein the metal catalyst comprises a transitional metal; and wherein at least about 60% of the second metal oxide is in monomeric form. 8. The catalytic material of claim 7, wherein the first metal oxide is one selected from the group consisting of TiO2, SiO2, Al2O3, ZrO2, and WO3. 9. The catalytic material of claim 7, wherein the second metal oxide comprises a transitional metal. 10. The catalytic material of claim 7, wherein the second metal oxide is one selected from the group consisting of vanadium oxide, manganese oxide, chromium oxide, molybdenum oxide. 11. The catalytic material of claim 7, wherein the metal catalyst comprises one metal selected from the group consisting of Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt, Au, Ag, and Cu. 12. A catalytic material, comprising: a first metal oxide selected from the group consisting of TiO2, SiO2, Al2O3, ZrO2, and WO3, said first metal oxide having (a) size of about 4 to about 15 nm; (b) crystallinity greater than about 60%; and (c) a surface of hydration of about 5 to about 100 mg per gram of the dry first metal oxide; a second metal oxide selected from the group consisting of vanadium oxide, manganese oxide, chromium oxide, molybdenum oxide, and a metal catalyst comprising one metal selected from the group consisting of Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt, Au, Ag, and Cu, wherein the second metal oxide is deposited onto the surface of the first metal oxide and forms monomeric or oligomeric form on the surface of the first metal oxide; and wherein at least about 60% of the second metal oxide is in monomeric form. 13. A process of producing the catalytic material of claim 12, comprising: (a) forming amorphous material of a first metal oxide; (b) crystallizing said first metal oxide into particles of about 4 to about 15 Nm; (c) controlling the level of surface hydration of said metal oxide particle to a range of about 5 to about 100 mg per gram of the dry first metal oxide; (d) depositing a second metal oxide to the first metal oxide from (c); (e) depositing a metal catalyst precursor to the second metal oxide; and (f) converting the metal catalyst precursor to a metal catalyst. 14. A method of purifying air by removing contaminants containing organic, inorganic, and/or biological species in the air, the method comprising contacting the contaminants with the catalytic material of claim 12. 15. A catalytic material, comprising: TiO2, V2O5, and Au, wherein the TiO2 has (a) size of about 4 to about 15 nm; (b) crystallinity greater than about 60%; and (c) a surface of hydration of about 5 to about 100 mg per gram of the dry TiO2; wherein the V2O5 is deposited onto the surface of the TiO2 and forms monomeric or oligomeric form on the surface of the TiO2; and wherein at least about 60% of the V2O5 is in monomeric form.
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