초록 ▼

A process for producing an absorbent polymer including a first mixing event, in which a plurality of absorbent polymer particles (1) are mixed with a liquid (2) and a second mixing event, in which the liquid (2) is homogenized within the interior of the polymer particles. The polymer particles (1)

A process for producing an absorbent polymer including a first mixing event, in which a plurality of absorbent polymer particles (1) are mixed with a liquid (2) and a second mixing event, in which the liquid (2) is homogenized within the interior of the polymer particles. The polymer particles (1) in the first mixing event are mixed with a speed such that the kinetic energy of the individual polymer particles (1) is on average larger than the adhesion energy of the individual polymer particles (1), and the polymer particles (1) in the second mixing event are stirred at a lower speed than in the first mixing event. The different speeds effect a fluidization of the polymer particles (1), which prevents a clumping of the polymer particles (1) during the mixing event. The absorbent polymers thus produced are distinguished by a particularly rapid swelling behavior.

대표청구항 ▼

The invention claimed is: 1. A process for producing an absorbent polymer composition comprising the steps of: a first mixing event, wherein a plurality of absorbent polymer particles are mixed with a liquid in a mixer; and a second mixing event, wherein the liquid is distributed within the polymer

The invention claimed is: 1. A process for producing an absorbent polymer composition comprising the steps of: a first mixing event, wherein a plurality of absorbent polymer particles are mixed with a liquid in a mixer; and a second mixing event, wherein the liquid is distributed within the polymer particles; wherein the polymer particles in the first mixing event are mixed with a first mixing speed, and the polymer particles in the second mixing event are stirred with a lower speed than in the first mixing event; and wherein the first mixing event is a continuous mixing process wherein in the first mixing event the polymer particles are back-mixed in such a way that a flow of the new polymer particles entering in the mixer is overlaid by a flow of polymer particles already present in the mixer and opposed to this flow, wherein the ratio of the opposed flow to the flow of newly entering polymer particles averages about 5 to about 50% by wt. 2. The process according to claim 1 wherein before the first mixing event the absorbent polymer particles have been secondary cross-linked in the surface portion and have been brought into contact with a composition comprising an Al3+ ion before the secondary cross-linking. 3. The process according to claim 1 wherein the average speed of the polymer particles in the first mixing event amounts to between about 8 and about 80 m/sec. 4. The process according to claim 1 wherein the Froude number in the first mixing event amounts to between about 1 and about 50. 5. The process according to claim 1 wherein a back-mixing from about 10% to about 30% occurs. 6. The process according to claim 1 wherein the average residence time of the first mixing event amounts to between about 5 and about 200sec. 7. The process according to claim 1 wherein the static pressure build up during the first mixing event amounts to less than about 0.1 bar. 8. The process according to claim 1 wherein water or aqueous solution is added as liquid. 9. The process according to claim 8, wherein the liquid comprises additives. 10. The process according to claim 1, wherein the polymer particles are based on: (α1) about 0.1 to about 99.999 wt.% polymerized, ethylenically unsaturated, acidic group-containing monomers containing a protonated or a quaternary nitrogen, or mixtures thereof, (α2) 0 to about 70 wt.% of polymerized, ethylenically unsaturated monomers which can be co-polymerized with (α1), (α3) about 0.001 to about 10 wt.% of one or more cross-linkers, (α4) 0 to about 30 wt.% of water soluble polymers, as well as (α5) 0 to about 20 wt.% of one or more additives, wherein the sum of the component weights (α1) to (α5) amounts to 100 wt.%. 11. The process according to claim 1 wherein the polymer particles have at least one of the following properties: (A)the maximum absorption of 0.9 wt.% NaCl solution is within a range from at least about 10 to about 1000 g/g SAP granulate, (B) the part extractable with 0.9 wt.% aqueous NaCl solution amounts to less than about 30 wt.%, based on the SAP granulate, (C) the bulk density is within a range from about 300 to about 1000 gl, (D) the pH value for 1 g of the SAP granulate in 1 l water is within a range from about 4 to about 10, (E) the CRC value is within a range from about 10 to about 100 g/g, (F) the AAP value under a pressure of 0.7 psi is within a range from about 10 to about 60 g/g, (G)the AAP value under a pressure of 0.3 psi is within a range from about 10 to about 100 g/g. 12. A process for producing a composite, wherein the absorbent polymer composition made according to claim 1 and a substrate and optionally an additive are brought into contact with each other. 13. The process according to claim 3 wherein the speed of the polymer particles in the second mixing process amounts to under about 3 m/sec. 14. The process according to claim 1 wherein the Froude number in the second mixing event amounts to between about 0.001 and about 1.