초록

The present invention provides for a method for purifying carbon dioxide. Moisture, sulfur species and other impurities are removed from the carbon dioxide by a series of steps which include adsorption means and reaction means. All the steps are preferably carried out in a single vessel.

대표청구항 ▼

What is claimed is: 1. A method for purifying a carbon dioxide gas stream comprising passing a carbon dioxide gas stream for treatment through at least one adsorbent bed containing at least two adsorbent layers selected from the group consisting of a desiccant; a zeolite; a zeolite in its ion excha

What is claimed is: 1. A method for purifying a carbon dioxide gas stream comprising passing a carbon dioxide gas stream for treatment through at least one adsorbent bed containing at least two adsorbent layers selected from the group consisting of a desiccant; a zeolite; a zeolite in its ion exchange form; and an activated carbon; wherein at least one of the at least two adsorbent layers comprises a Y zeolite or a Y zeolite in its ion exchange form capable of removing an impurity comprising at least one of aldehydes, alcohols, acetates or sulfur compounds. 2. The method as claimed in claim 1 wherein the desiccant is selected from the group consisting of a 4A, 5A, 13X and NaY zeolite. 3. The method as claimed in claim 1 wherein the zeolite is NaY or its ion exchange form, KY or KNaY. 4. The method as claimed in claim 1 wherein the activated carbon is an impregnated activated carbon. 5. The method as claimed in claim 1 further comprising heating the carbon dioxide gas stream to about 50° C.-150° C. after the carbon dioxide gas stream passes through the zeolite bed. 6. The method as claimed in claim 1 comprising passing the carbon dioxide gas stream through a single vessel. 7. The method as claimed in claim 1 comprising passing the carbon dioxide gas stream in a plurality of vessels. 8. The method as claimed in claim 1 comprising purifying the carbon dioxide gas stream in an on-site facility. 9. A system for purifying a gas stream comprising at least one adsorbent bed containing at least two adsorbent layers selected from the group consisting of a desiccant; a zeolite; a zeolite in its ion exchange form; and an activated carbon; wherein at least one of the at least two adsorbent layers comprises a Y zeolite or a Y zeolite in its ion exchange form capable of removing an impurity comprising at least one of aldehydes, alcohols, acetates or sulfur compounds. 10. The system as claimed in claim 9 wherein the gas stream is a carbon dioxide gas stream. 11. The system as claimed in claim 9 wherein the desiccant is selected from the group consisting of a 4A, 5A, 13X and NaY zeolite. 12. The system as claimed in claim 9 wherein the zeolite is NaY or its ion exchange form, KY or KNaY. 13. The system as claimed in claim 9 wherein the activated carbon is an impregnated activated carbon. 14. The system as claimed in claim 9 further comprising a heat source to apply to the gas stream after the gas stream passes through the zeolite bed. 15. The system as claimed in claim 9 wherein the at least one absorbent bed is contained in a single vessel. 16. The system as claimed in claim 9 wherein the at least one adsorbent bed is contained in a plurality of vessels. 17. A system for purifying a carbon dioxide gas stream comprising at least one adsorbent bed containing a first adsorbent layer comprising a desiccant, and a second adsorbent layer comprising a Y zeolite or an ion exchanged Y zeolite capable of removing an impurity comprising at least one of aldehydes, alcohols, acetates or sulfur compounds. 18. The system as claimed in claim 17 wherein the at least one adsorbent bed contains a third layer comprising at least one material capable of removing at least one of sulfur impurities or aromatic hydrocarbons. 19. The system as claimed in claim 17 further comprising a second adsorbent bed containing at least one material capable of removing at least one of sulfur impurities or aromatic hydrocarbons. 20. The system as claimed in claim 19 wherein the second adsorbent bed contains at least one of activated carbon, an impregnated activated carbon, or DAY zeolite. 21. The system as claimed in claim 17 wherein the at least one adsorbent bed contains at least one of activated carbon, an impregnated activated carbon, or DAY zeolite. 22. The system as claimed in claim 17 wherein the desiccant is selected from the group consisting of a 4A, 5A, 13X and NaY zeolite. 23. The system as claimed in claim 17 wherein the at least one adsorbent bed comprises at least one of NaY zeolite, ion exchanged KY zeolite, or ion exchanged KNaY zeolite. 24. The system as claimed in claim 17 further comprising a heat source for application of heat to the gas stream after the gas stream passes through the zeolite bed. 25. The system as claimed in claim 17 wherein the at least one absorbent bed is contained in a single vessel. 26. The system as claimed in claim 17 wherein the at least one adsorbent bed is contained in a plurality of vessels. 27. A method for purifying a carbon dioxide gas stream comprising passing a carbon dioxide gas stream for treatment through at least one adsorbent bed containing a first adsorbent layer comprising a desiccant, and a second adsorbent layer comprising a Y zeolite or an ion exchanged Y zeolite capable of removing an impurity comprising at least one of aldehydes, alcohols, acetates or sulfur compounds. 28. The method as claimed in claim 27 wherein the at least one adsorbent bed contains a third layer comprising at least one material capable of removing at least one of sulfur impurities or aromatic hydrocarbons. 29. The method as claimed in claim 27 further comprising passing the carbon dioxide gas stream through a second adsorbent bed containing at least one material capable of removing at least one of sulfur impurities or aromatic hydrocarbons. 30. The method as claimed in claim 29 wherein the second adsorbent bed contains at least one of activated carbon, an impregnated activated carbon, or DAY zeolite. 31. The method as claimed in claim 29 further comprising heating the carbon dioxide gas stream to about 50° C.-150° C. before passing the carbon dioxide gas stream through the second adsorbent bed. 32. The method as claimed in claim 27 wherein the at least one adsorbent bed contains at least one of activated carbon, an impregnated activated carbon, or DAY zeolite. 33. The method as claimed in claim 27 wherein the desiccant is selected from the group consisting of a 4A, 5A, 13X and NaY zeolite. 34. The method as claimed in claim 27 wherein the at least one adsorbent bed comprises at least one of NaY zeolite, ion exchanged KY zeolite, or ion exchanged KNaY zeolite.