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An alcohol steam reforming catalyst for generating hydrogen contains palladium, yttrium, and at least one of cerium and a metal oxide. The catalyst displays both an improved alcohol conversion rate and improved carbon dioxide selectivity. Methods of making and using the alcohol steam reforming cata

An alcohol steam reforming catalyst for generating hydrogen contains palladium, yttrium, and at least one of cerium and a metal oxide. The catalyst displays both an improved alcohol conversion rate and improved carbon dioxide selectivity. Methods of making and using the alcohol steam reforming catalyst are described.

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What is claimed is: 1. An alcohol steam reforming catalyst for generating hydrogen consisting essentially of: from about 10% to about 99% by weight of cerium oxide, from about 0.1% to about 50% by weight of a palladium containing compound, from about 0.1% to about 50% by weight of an yttrium contai

What is claimed is: 1. An alcohol steam reforming catalyst for generating hydrogen consisting essentially of: from about 10% to about 99% by weight of cerium oxide, from about 0.1% to about 50% by weight of a palladium containing compound, from about 0.1% to about 50% by weight of an yttrium containing compound, from about 0.1% to about 99% by weight of a zinc containing compound, and optionally at least one selected from the group consisting of ceramic materials, zeolites, clays, calcined clays, and alumina-silicates. 2. A monolith substrate coated with the alcohol steam reforming catalyst of claim 1. 3. The monolith substrate of claim 2, wherein the monolith substrate comprises a fired ceramic. 4. The alcohol steam reforming catalyst of claim 1, the catalyst consisting of: from about 10% to about 99% by weight of cerium oxide, from about 0.1% to about 50% by weight of a palladium containing compound, from about 0.1% to about 50% by weight of a yttrium containing compound, from about 0.1% to about 99% by weight of a zinc containing compound, and optionally at least one selected from the group consisting of ceramic materials, zeolites, clays, calcined clays, and alumina-silicates. 5. The alcohol steam reforming catalyst of claim 1, the catalyst consisting of: from about 10% to about 99% by weight of cerium oxide, from about 0.1% to about 50% by weight of a palladium containing compound, from about 0.1% to about 50% by weight of a yttrium containing compound, and from about 0.1% to about 99% by weight of a zinc containing compound. 6. The alcohol steam reforming catalyst of claim 1, wherein at least a portion of the palladium containing compound and the zinc containing compound form an alloy of palladium and zinc. 7. The alcohol steam reforming catalyst of claim 1, wherein at least a portion of the palladium containing compound and the yttrium containing compound form an alloy of palladium and yttrium. 8. The alcohol steam reforming catalyst of claim 1, wherein at least a portion of the palladium containing compound and the cerium oxide form an alloy of palladium and cerium. 9. The alcohol steam reforming catalyst of claim 1, wherein at least a portion of the yttrium containing compound and the zinc containing compound form an alloy of yttrium and zinc. 10. The alcohol steam reforming catalyst of claim 1, wherein at least a portion of the yttrium containing compound and the cerium oxide form an alloy of yttrium and cerium. 11. The alcohol steam reforming catalyst of claim 1, wherein at least a portion of the zinc containing compound and the cerium oxide form an alloy of zinc and cerium. 12. The alcohol steam reforming catalyst of claim 1, wherein the palladium containing compound is at least one selected from the group consisting of metallic palladium, ionic palladium, and palladium oxide. 13. The alcohol steam reforming catalyst of claim 1, wherein the yttrium containing compound is at least one selected from the group consisting of metallic yttrium, ionic yttrium, and yttrium oxide. 14. The alcohol steam reforming catalyst of claim 1, wherein the zinc containing compound is at least one selected from the group consisting of metallic zinc, ionic zinc, and zinc oxide. 15. An alcohol steam reforming catalyst for generating hydrogen consisting essentially of: from about 10% by to about 99% by weight of cerium oxide, from about 0.1% to about 50% by weight of palladium oxide, from about 0.1% to about 50% by weight of yttrium oxide, from about 0.1% to about 99% by weight of zinc oxide, and optionally at least one selected from the group consisting of ceramic materials, zeolites, clays, calcined clays, and alumina-silicates. 16. The alcohol steam reforming catalyst of claim 15, wherein at least a portion of the palladium oxide and zinc oxide form an alloy of palladium and zinc. 17. A monolith substrate coated with the alcohol steam reforming catalyst of claim 15. 18. The monolith substrate of claim 17, wherein the monolith substrate comprises a fired ceramic. 19. The alcohol steam reforming catalyst of claim 15, the catalyst consisting of: from about 10% by to about 99% by weight of cerium oxide, from about 0.1% to about 50% by weight of palladium oxide, from about 0.1% to about 50% by weight of yttrium oxide, from about 0.1% to about 99% by weight of zinc oxide, and optionally at least one selected from the group consisting of ceramic materials, zeolites, clays, calcined clays, and alumina-silicates. 20. The alcohol steam reforming catalyst of claim 15, wherein at least a portion of the palladium oxide and the yttrium oxide form an alloy of palladium and yttrium. 21. The alcohol steam reforming catalyst of claim 15, wherein at least a portion of the palladium oxide and the cerium oxide form an alloy of palladium and cerium. 22. The alcohol steam reforming catalyst of claim 15, wherein at least a portion of the yttrium oxide and the zinc oxide form an alloy of yttrium and zinc. 23. The alcohol steam reforming catalyst of claim 15, wherein at least a portion of the yttrium oxide and the cerium oxide form an alloy of yttrium and cerium. 24. The alcohol steam reforming catalyst of claim 15, wherein at least a portion of the zinc oxide and the cerium oxide form an alloy of zinc and cerium.