Sealant composition having reduced permeability to gas
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08G-018/06
C08G-018/00
출원번호
UP-0345563
(2006-02-01)
등록번호
US-7569653
(2009-08-24)
발명자
/ 주소
Landon, Shayne J.
출원인 / 주소
Momentive Performance Materials Inc.
대리인 / 주소
Vicari, David G.
인용정보
피인용 횟수 :
29인용 특허 :
60
초록
This invention relates to a moisture-curable silylated resin-containing composition containing, inter alia, moisture-curable silylated resin, the cured composition exhibiting low permeability to gas(es).
대표청구항▼
What is claimed is: 1. A moisture-curable silylated resin-containing composition comprising: a) moisture-curable silylated resin, prepared by reacting a hydroxyl-terminated polyurethane prepolymer with and isocyanatosilane, wherein the hydroxyl terminated prepolymer is prepared by reacting a molar
What is claimed is: 1. A moisture-curable silylated resin-containing composition comprising: a) moisture-curable silylated resin, prepared by reacting a hydroxyl-terminated polyurethane prepolymer with and isocyanatosilane, wherein the hydroxyl terminated prepolymer is prepared by reacting a molar excess of a polyol selected from the group consisting of poly(oxyethylene) diols, poly(oxypropylene) diols, poly(oxyethylene-oxypropylene) diols, polyoxyalkylene triols and polytetramethylene glycols, having a number average molecular weight of from 4,000 to 18,000 grams/mole and an end group unsaturation level no greater than 0.04 milliequivalent per gram of polyol with a diisocyanate and wherein the isocyanatosilane is of the formula: OCN--R5--Si(R6)y(OR7) 3-y where R5 is an alkylene group of up to 12 carbon atoms; R6 is a alkyl or aryl group of up to 8 carbon atoms; R7 is the same or different alkyl group of up to 6 carbon atoms; and y is 0, 1 or 2 which upon curing, provides a cured resin exhibiting permeability to gas; b) at least one other polymer having a permeability to gas that is less than the permeability of cured resin (a); and, c) at least one nanoclay modified with a cationic surfactant-exfoliating agent, wherein the nanoclay particles have a lateral dimension of between 0.01 microns and 5 microns and a vertical dimension of between 0.5 nanometers to 10 nanometers. 2. The composition of claim 1 wherein moisture-curable silylated resin (a) ranges from about 10 to about 50 weight percent of the total composition. 3. The composition of claim 1 wherein moisture-curable silylated resin (a) ranges from about 20 to about 30 weight percent of the total composition. 4. The composition of claim 1 wherein polymer (b) is selected from the group consisting of low density polyethylene, very low density polyethylene, linear low density polyethylene, high density polyethylene, polypropylene, polyisobutylene, polyvinyl acetate, polyvinyl alcohol, polystyrene, polycarbonate, polyester, such as, polyethylene terephthalate, polybutylene terephthalate, polyethylene napthalate, glycol-modified polyethylene terephthalate, polyvinylchloride, polyvinylidene chloride, polyvinylidene fluoride, thermoplastic polyurethane, acrylonitrile butadiene styrene, polymethylmethacrylate, polyvinyl fluoride, polyamides, polymethylpentene, polyimide, polyetherimide, polyether ether ketone, polysulfone, polyether sulfone, ethylene chlorotrifluoroethylene, polytetrafluoroethylene, cellulose acetate, cellulose acetate butyrate, plasticized polyvinyl chloride, ionomers, polyphenylene sulfide, styrene-maleic anhydride, modified polyphenylene oxide, ethylene-propylene rubber, polybutadiene, polychloroprene, polyisoprene, polyurethane, styrene-butadiene-styrene, styrene-ethylene-butadiene-styrene, polymethylphenyl siloxane and mixtures thereof. 5. The composition of claim 4 wherein polymer (b) is selected from the group consisting of low density polyethylene, very low density polyethylene, linear low density polyethylene, high density polyethylene, and mixtures thereof. 6. The composition of claim 5 wherein polymer (b) is selected from the group consisting of low density polyethylene, very low density polyethylene, linear low density polyethylene, and mixtures thereof. 7. The composition of claim 1, wherein polymer (b) ranges from about 5 to about 50 weight percent of the total composition. 8. The composition of claim 1, wherein polymer (b) ranges from about 10 to about 20 weight percent of the total composition. 9. The composition of claim 1 further comprising a catalyst wherein the catalyst is a tin catalyst. 10. The composition of claim 1 wherein the tin catalyst is selected from the group consisting of dibutyltin dilaurate, dibutyltindiacetate, dibutyltindimethoxide, tinoctoate, isobutyltintriceroate, dibutyltinoxide, solubilized dibutyl tin oxide, dibutyltin bis-diisooctylphthalate, bis-tripropoxysilyl dioctyltindibutyltin bis-acetylacetone, silylated dibutyltin dioxide, carbomethoxyphenyl tin tris-uberate, isobutyltin triceroate, dimethyltin dibutyrate, dimethyltin di-neodecanoate, triethyltin tartarate, dibutyltin dibenzoate, tin oleate, tin naphthenate, butyltintri-2-ethylhexylhexoate, tinbutyrate, diorganotin bis β-diketonates, and mixtures thereof. 11. The composition of claim 1 further comprising an adhesion promoter wherein the adhesion promoter is selected from the group consisting of N-2-aminoethyl-3-aminopropyltrimethoxysilane, 1,3,5-tris(trimethoxysilylpropyl)isocyanu rate, γ-aminopropyltriethoxysilane, γ-aminopropyltrimethoxysilane, aminopropyltrimethoxysilane, bis-γ-(trimethoxysilylpropyl)amine, N-phenyl-γ-aminopropyltrimethoxysilane, triaminofunctionaltrimethoxysilane, γ-aminopropylmethyldiethoxysilane, γ-aminopropylmethyldiethoxysilane, methacryloxypropyltrimethoxysilane, methylaminopropyltrimethoxysilane, γ-glycidoxypropylethyldimethoxysilane, γ-glycidoxypropyltrimethoxysilane, γ-glycidoxyethyltrimethoxysilane, β-(3,4-epoxycyclohexyl)propyltrimethoxysilane, β-(3,4-epoxycyclohexyl)ethylmethyldimethoxysilane, isocyanatopropyltriethoxysilane, isocyanatopropylmethyldimethoxysilane, β-cyanoethyltrimethoxysilane, γ-acryloxypropyltrimethoxysilane, γ-methacryloxypropylmethyldimethoxysilane, 4-amino-3,3,-dimethylbutyltrimethoxysilane, N-ethyl-3-trimethoxysilyl-2-methylpropanamine, and mixtures thereof. 12. The composition of claim 1 further comprising at least one additional filler wherein said at least one additional filler is selected from the group consisting of calcium carbonate, precipitated calcium carbonate, colloidal calcium carbonate, calcium carbonate treated with compounds such as stearic acid or stearate esters fumed silica, precipitated silica, silica gels, hydrophobized silicas, hydrophilic silica gels, crushed quartz, ground quartz, alumina, aluminum hydroxide, titanium hydroxide, clay, kaolin, bentonite montmorillonite, diatomaceous earth, iron oxide, carbon black and graphite, mica, talc, and mixtures thereof. 13. The composition of claim 1 wherein the nanoclay is selected from the group consisting of montmorillonite, sodium montmorillonite, calcium montmorillonite, magnesium montmorillonite, nontronite, beidellite, volkonskoite, laponite, hectorite, saponite, sauconite, magadite, kenyaite, sobockite, svindordite, stevensite, vermiculite, halloysite, aluminate oxides, hydrotalcite, illite, rectorite, tarosovite, ledikite, kaolinite and, mixtures thereof. 14. The composition of claim 13 wherein the nanoclay is modified with ammonium, primary alkylammonium, secondary alkylammonium, tertiary alkylammonium, quaternary alkylammonium, phosphonium derivatives of aliphatic, aromatic or arylaliphatic amines, phosphines or sulfides or sulfonium derivatives of aliphatic, aromatic or arylaliphatic amines, phosphines or sulfides. 15. The composition of claim 13 wherein the nanoclay is modified with at least one tertiary amine compound R3R4R5N and/or quarternary ammonium compound R5R6R7R8N+ X- wherein R3, R4, R5, R6, R7 and R8 each independently is an alkyl, alkenyl or alkoxy silane group of up to 60 carbon atoms and X- is an anion. 16. The composition of claim 1 further comprising a surfactant, wherein the surfactant is a nonionic surfactant selected from the group consisting of polyethylene glycol, polypropylene glycol, ethoxylated castor oil, oleic acid ethoxylate, alkylphenol ethoxylates, copolymers of ethylene oxide and propylene oxide and copolymers of silicones and polyethers, copolymers of silicones and copolymers of ethylene oxide and propylene oxide and mixtures thereof. 17. The composition of claim 16 wherein the non-ionic surfactant is selected from the group consisting of copolymers of ethylene oxide and propylene oxide, copolymers of silicones and polyethers, copolymers of silicones and copolymers of ethylene oxide and propylene oxide and mixtures thereof. 18. A sealant, adhesive or coating composition prepared with the moisture-curable silylated resin-containing-composition of claim 1. 19. A sealant, adhesive or coating composition prepared with polymer (b) of claim 4. 20. A sealant, adhesive or coating composition prepared with the nanoclay composition of claim 15. 21. The cured silylated resin-containing composition of claim 1. 22. The cured silylated resin-containing composition of claim 4. 23. The cured silylated resin-containing composition of claim 15.
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