초록 ▼

An optical nose for detecting the presence of molecular contaminants in gaseous samples utilizes a tunable seed laser output in conjunction with a pulsed reference laser output to generate a mid-range IR laser output in the 2 to 20 micrometer range for use as a discriminating light source in a photo

An optical nose for detecting the presence of molecular contaminants in gaseous samples utilizes a tunable seed laser output in conjunction with a pulsed reference laser output to generate a mid-range IR laser output in the 2 to 20 micrometer range for use as a discriminating light source in a photo-acoustic gas analyzer.

대표청구항 ▼

What is claimed is: 1. An optical nose system having a broadly tunable, narrow linewidth mid-IR laser source wherein the laser source has a modular structure and comprises a) a tunable seed laser unit including a single-longitudinal mode, widely tunable TM2+:II-VI master oscillator with a TM2+:II-V

What is claimed is: 1. An optical nose system having a broadly tunable, narrow linewidth mid-IR laser source wherein the laser source has a modular structure and comprises a) a tunable seed laser unit including a single-longitudinal mode, widely tunable TM2+:II-VI master oscillator with a TM2+:II-VI power amplifier having a laser output, where TM2+ stands for transition metal ion selected from the group consisting of Cr2+, Fe2+, Co2+ and Ni2+, and II-VI stands for ZnS, ZnSe, CdS, CdSe, ZnTe, CdTe and their mixtures wherein said seed laser is a broadly tunable single frequency laser without mode hoping which is comprised of Littrow or Littman dispersive cavity with accompanied by dynamic correction of cavity length; b) a pulsed pump laser unit including a single-frequency, high energy, Q-switch laser having a laser output; c) an Optical Parametric Generator-Amplifier, pumped by said pulsed pump laser unit and seeded by said seed tunable laser unit having a mid-IR output selectively variable over about 2 to 20 μm; and wherein said pulsed pump and seed tunable lasers are pumped by a single diode, diode array, or fiber laser. 2. The optical nose system as defined in claim 1 wherein correction of cavity length is controlled by piezoelectric transducers. 3. The optical nose system as defined in claim 2 further comprising a Master Control Computer, single frequency pump pulsed laser unit with a wavelength locking, single frequency seed tunable laser unit with a feedback system for frequency stabilization, Optical Parametric Generator-Amplifier and wherein the length of said seed tunable laser cavity is controlled by a piezoelectric controller, a grating step motor driver connected to a step motor for diffraction grating or mirror of the tunable laser cavity, a wavelength controller operatively connected to send signals to said grating stepper motor driver dependant on inputs from said master control computer. 4. The optical nose system as defined in claim 3 wherein said Optical Parametric Generator-Amplifier is a difference frequency generator device where the laser radiations from the seed tunable laser unit and a high power pump laser unit are mixed in nonlinear crystal, selected from the group of ZGP, CdSe or GaSe. 5. The optical nose system as defined in claim 4 wherein the orientation of said nonlinear crystal is controlled by a rotation step motor receiving a control signal from said wavelength controller. 6. A method for analyzing a gaseous sample contained in a photoacoustic gas cell, said method comprising the steps of: a) pumping a pulsed pump and tunable seed lasers and generating laser oscillation of the said lasers; b) pumping optical parametric generator-optical parametric amplifier unit (OPG-OPA) with radiations of the pulsed pump and seed lasers and generating of tunable mid-IR signal and idler waves; c) directing a tunable laser radiation from said OPG-OPA to the gas cell and measuring absorption spectrum; and d) comparing the measured absorption spectrum with the known absorption spectra of the gaseous sample to determine the composition of the gaseous sample; wherein step a) further comprises: Pumping of the said seed and pulsed pump lasers with Tm-fiber or Er-fiber pump lasers, and step b) further comprises the step of providing a ZGP nonlinear crystal in said OPG-OPA generating radiation over the 2-10 μm mid-IR spectral range, rotating the position of said ZGP nonlinear crystal with a ZGP stepping motor, providing a wavelength controller connected with a ZGP stepping motor, calculating the required angle of rotation of the ZGP for the current wavelength, and rotating the ZGP according to calculations. 7. A method for analyzing a gaseous sample contained in a photoacoustic gas cell, said method comprising the steps of: a) pumping a pulsed pump and tunable seed lasers and generating laser oscillation of the said lasers; b) pumping optical parametric generator-optical parametric amplifier unit (OPG-OPA) with radiations of the pulsed pump and seed lasers and generating of tunable mid-IR signal and idler waves; c) directing a tunable laser radiation from said OPG-OPA to the gas cell and measuring absorption spectrum; and d) comparing the measured absorption spectrum with the known absorption spectra of the gaseous sample to determine the composition of the gaseous sample, and wherein step a) further includes: generating a Q-switched Holmium laser radiation as a pump source for said OPG-OPA. 8. A method for analyzing a gaseous sample contained in a photoacoustic gas cell, said method comprising the steps of: a) pumping a pulsed pump and tunable seed lasers and generating laser oscillation of the said lasers; b) pumping optical parametric generator-optical parametric amplifier unit (OPG-OPA) with radiations of the pulsed pump and seed lasers and generating of tunable mid-IR signal and idler waves; c) directing a tunable laser radiation from said OPG-OPA to the gas cell and measuring absorption spectrum; and d) comparing the measured absorption spectrum with the known absorption spectra of the gaseous sample to determine the composition of the gaseous sample; wherein step a) further includes: generating a Q-switched Erbium laser radiation as a pump source for said OPG-OPA, and step b) further comprises the step of providing a ZGP nonlinear crystal in said OPG-OPA generating radiation over the 2-10 μm mid-IR spectral range, rotating the position of said ZGP nonlinear crystal with a ZGP stepping motor, providing a wavelength controller connected with a ZGP stepping motor, calculating the required angle of rotation of the ZGP for the current wavelength, and rotating the ZGP according to calculations. 9. A method for analyzing a gaseous sample contained in a photoacoustic gas cell, said method comprising the steps of: a) pumping a pulsed pump and tunable seed lasers and generating laser oscillation of the said lasers; b) pumping optical parametric generator-optical parametric amplifier unit (OPG-OPA) with radiations of the pulsed pump and seed lasers and generating of tunable mid-IR signal and idler waves; c) directing a tunable laser radiation from said OPG-OPA to the gas cell and measuring absorption spectrum; and d) comparing the measured absorption spectrum with the known absorption spectra of the gaseous sample to determine the composition of the gaseous sample; wherein step a) further comprises: generating a single frequency tunable Cr2+:II-VI laser radiation using a Cr2+:II-VI master oscillator and Cr2+:II-VI a power amplifier, where II-VI stands for Zn, Se, CdSe, ZnS, and their mixtures, and transmitting said Cr2+:II-VI widely tunable seed laser radiation to said OPG-OPA wherein said Cr2+:II-VI widely tunable seed laser radiation is continuously tunable over a 2-3.5 μm spectral range. 10. A method for analyzing a gaseous sample contained in a photoacoustic gas cell, said method comprising the steps of: a) pumping a pulsed pump and tunable seed lasers and generating laser oscillation of the said lasers; b) pumping optical parametric generator-optical parametric amplifier unit (OPG-OPA) with radiations of the pulsed pump and seed lasers and generating of tunable mid-IR signal and idler waves; c) directing a tunable laser radiation from said OPG-OPA to the gas cell and measuring absorption spectrum; and d) comparing the measured absorption spectrum with the known absorption spectra of the gaseous sample to determine the composition of the gaseous sample, and wherein step b) further comprises the step of providing a ZGP nonlinear crystal in said OPG-OPA generating radiation over the 2-10 μm mid-IR spectral range; rotating the position of said ZGP nonlinear crystal with a ZGP stepping motor; providing a wavelength controller connected with a ZGP stepping motor; calculating the required angle of rotation of the ZGP for the current wavelength; and rotating the ZGP according to calculations. 11. An optical nose system having a broadly tunable, narrow linewidth mid-IR laser source wherein the laser source has a modular structure and comprises a) a tunable seed laser unit including a single-longitudinal mode, widely tunable TM2+:II-VI master oscillator with a TM2+:II-VI power amplifier having a laser output, where TM2+ stands for transition metal ion selected from the group consisting of Cr2+, Fe2+, Co2+ and Ni2+, and II-VI stands for ZnS, ZnSe, CdS, CdSe, ZnTe, CdTe and their mixtures; b) a pulsed pump laser unit including a single-frequency, high energy, Q-switch laser having a laser output; and, c) an Optical Parametric Generator-Amplifier, pumped by said pulsed pump laser unit and seeded by said seed tunable laser unit having a mid-IR output selectively variable over about 2 to 20 μm, and wherein said Optical Parametric Generator-Amplifier is a difference frequency generator device where the laser radiations from the seed tunable laser unit and a high power pump laser unit are mixed in nonlinear crystal, selected from the group of ZGP, CdSe or GaSe. 12. The optical nose system as defined in claim 11, further comprising a photo-acoustic cell receiving an optical input from said Optical Parametric Generator-Amplifier for analyzing a gaseous sample.