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The invention includes methods for producing dianhydrosugar alcohol by providing an acid catalyst within a reactor and passing a starting material through the reactor at a first temperature. At least a portion of the staring material is converted to a monoanhydrosugar isomer during the passing throu

The invention includes methods for producing dianhydrosugar alcohol by providing an acid catalyst within a reactor and passing a starting material through the reactor at a first temperature. At least a portion of the staring material is converted to a monoanhydrosugar isomer during the passing through the column. The monoanhydrosugar is subjected to a second temperature which is greater than the first to produce a dianhydrosugar. The invention includes a method of producing isosorbide. An initial feed stream containing sorbitol is fed into a continuous reactor containing an acid catalyst at a temperature of less than 120° C. The residence time for the reactor is less than or equal to about 30 minutes. Sorbitol converted to 1,4-sorbitan in the continuous reactor is subsequently provided to a second reactor and is dehydrated at a temperature of at least 120° C. to produce isosorbide.

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The invention claimed is: 1. A method for production of a dianhydrosugar alcohol, comprising: providing a solid acid catalyst within a continuous reactor, the solid acid catalyst being selected from the group consisting of heteropolyacid and an ion exchange resin, acidic clay, molecular sieve mater

The invention claimed is: 1. A method for production of a dianhydrosugar alcohol, comprising: providing a solid acid catalyst within a continuous reactor, the solid acid catalyst being selected from the group consisting of heteropolyacid and an ion exchange resin, acidic clay, molecular sieve material, and sulfated zirconia; passing a feed stream through the continuous reactor at a first temperature of from about 70° C. to about 120° C., the feed stream comprising at least one sugar and/or sugar alcohol in an absence of solvent upon entry into the reactor, at least a portion of the at least one sugar and/or sugar alcohol being converted to a monoanhydrosugar isomer during the passing, the residence within the continuous reactor being from about 10 minutes to about 30 minutes; obtaining a product material from the continuous reactor, the product material comprising the monoanhydrosugar isomer at an abundance of at least 50% relative to a total of monoanhydrosugars in the product material; separating the monoanhydrosugar isomer from undesirable monoanhydrosugars present in the product material; and after the separating, subjecting the monoanhydrosugar isomer to a second temperature to convert at least some of the monoanhydrosugar isomer to a dianhydrosugar alcohol, the second temperature being greater than the first temperature. 2. The method of claim 1 wherein the subjecting comprises providing the monoanhydrosugar isomer to a second reactor and dehydrating the monoanhydrosugar isomer to the dianhydrosugar alcohol. 3. The method of claim 2 wherein the second temperature is equal to or greater than 120° C. 4. The method of claim 2 wherein the dehydrating converts at least 90% of the monoanhydrosugar Isomer to a single dianhydrosugar alcohol. 5. The method of claim 1 wherein the initial compound is sorbitol. 6. The method of claim 1 wherein the monoanhydrosugar isomer is 1,4-sorbitan. 7. A method of producing isosorbide comprising: feeding an initial feed stream into a continuous reactor, the initial feed stream comprising sorbitol; exposing the sorbitol to an acid catalyst selected from the group consisting of heteropolyacid and an ion exchange resin, acidic clay, molecular sieve material, sulfated zirconia, sulfuric acid, phosphoric acid, hydrochloric acid p-toluenesulfonic acid and organic acids, within the continuous reactor, the exposing being conducted at a temperature of less than 120° C., a residence time for the reactor being less than or equal to about 30 minutes; converting at least some of the sorbitol to 1 ,4-sorbitan during the exposing; removing at least a portion of any 2,5-monoanhydrosugar produced during the exposing; after the removing, providing the 1,4-sorbitan in a second feed stream to a second reactor; and dehydrating at least some of the 1,4-sorbitan to produce isosorbide within the second reactor, the dehydrating being conducted at a temperature of at least 120° C. 8. The method of claim 7 wherein the dehydrating converts at least 83% of the 1,4-sorbitan to isosorbide. 9. The method of claim 7 wherein the acid catalyst comprises a mineral acid catalyst. 10. The method of claim 7 wherein the acid catalyst comprises a solid acid catalyst. 11. The method of claim 7 wherein the initial feed stream comprises from about 30% to about 70% water. 12. The method of claim 7 wherein the initial feed stream provides sorbitol in an absence of water. 13. A method for production of a dianhydrosugar alcohol, comprising: providing an acid catalyst within a first continuous reactor, the acid catalyst being selected from the group consisting of heteropolyacid and an ion exchange resin, acidic clay, molecular sieve material, sulfated zirconia, sulfuric acid, phosphoric acid, hydrochloric acid p-toluenesulfonic acid and organic acids; passing a feed stream comprising water and at least one of a sugar and a monoanhydrosugar through the first continuous reactor and subjecting the feed stream to a temperature of from about 70° C. to about 120° C. in the first continuous reactor for a residence time of from 10 minutes to 30 minutes; obtaining a product material from the first continuous reactor, the product material comprising a predominant monoanhydrosugar isomer and one or more additional monoanhydrosugar isomers; separating the predominant monoanhydrosugar isomer from the additional monoanhydrosugar isomers; and after the separating, in a second reactor, subjecting the predominant monoanhydrosugar isomer to a temperature of at least 120° C. to produce a dianhydrosugar alcohol. 14. The method of claim 13 wherein the second reactor contains an acid catalyst selected from the group consisting of heteropolyacid and an ion exchange resin, acidic clay, molecular sieve material, sulfated zirconia, sulfuric acid, phosphoric acid, hydrochloric acid p-toluenesulfonic acid and organic acids. 15. The method of claim 13 wherein the feed stream contains from 30% to about 70% water. 16. The method of claim 13 wherein a residence time in the second reactor is less than or equal to 30 minutes. 17. The method of claim 13 wherein the second reactor is a batch reactor. 18. The method of claim 13 wherein the second reactor is a continuous reactor.