Powder coated roving for making structural composite
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B05D-001/36
B29C-070/52
출원번호
UP-0858692
(2004-06-02)
등록번호
US-7648733
(2010-02-22)
발명자
/ 주소
Adzima, Leonard J.
Strait, Michael A.
Hager, William G.
출원인 / 주소
OCV Intellectual Capital, LLC
대리인 / 주소
Dottavio, James J.
인용정보
피인용 횟수 :
1인용 특허 :
17
초록▼
A polymer composite multiend roving material used to make structural composite parts includes a bundle of fibers held together by a high integrity sizing composition and surrounded by a powder coating polymer material. The powder coating material is approximately 10-80% of the dry weight of the mult
A polymer composite multiend roving material used to make structural composite parts includes a bundle of fibers held together by a high integrity sizing composition and surrounded by a powder coating polymer material. The powder coating material is approximately 10-80% of the dry weight of the multiend composite roving weight. The multiend composite roving material may then be easily processed further to form a molded composite part having good mechanical properties and high fiber content.
대표청구항▼
What is claimed is: 1. A method for forming a composite roving for use in structural composites comprising the steps of: forming a sized fiber bundle of a first type, said fibers forming said sized fiber bundle being sized with a sizing composition that maintains said fibers in said bundle; applyin
What is claimed is: 1. A method for forming a composite roving for use in structural composites comprising the steps of: forming a sized fiber bundle of a first type, said fibers forming said sized fiber bundle being sized with a sizing composition that maintains said fibers in said bundle; applying a first amount of an aqueous powder coating to an outer portion of said sized fiber bundle to form a coated fiber bundle; and drying said coated fiber bundle to remove water from said aqueous powder coating, wherein said sized fiber bundle comprises a plurality of inner fibers and a plurality of outer fibers held together by said sizing composition, and wherein only an outer surface of said plurality of outer fibers are coated with said powder coating. 2. The method of claim 1, wherein the step of applying a first amount of an aqueous powder coating comprises the steps of: dipping said sized fiber bundle into an aqueous slurry of a powder coating material; and metering the amount of said aqueous slurry applied to said sized fiber bundle to a first amount. 3. The method of claim 2, wherein the step of metering the amount of said aqueous slurry applied to said sized fiber bundle to a first amount comprises the step of metering the amount of said aqueous slurry applied to said sized fiber bundle to a first amount using a stripper die. 4. The method of claim 2, wherein the step of metering the amount of said aqueous slurry applied to said sized fiber bundle to a first amount comprises the step of metering the amount of said aqueous slurry applied to said sized fiber bundle to a first amount using a squeegee. 5. The method of claim 1, further comprising the steps of: chopping said composite roving into a plurality of chopped strands having a first length; and compression molding said plurality of chopped strands to a desired shape to form the structural composite part. 6. The method of claim 5, wherein the step of metering the amount of said aqueous slurry applied to said sized fiber bundle to a first amount comprises the step of metering the amount of said aqueous slurry applied to said sized fiber bundle to a first amount using a stripper die. 7. The method of claim 5, wherein the step of metering the amount of said aqueous slurry applied to said sized fiber bundle to a first amount comprises the step of metering the amount of said aqueous slurry applied to said sized fiber bundle to a first amount using a squeegee. 8. The method of claim 5, wherein the step of drying said coated fiber bundle to form a composite roving comprises the step of air-drying said coated fiber bundle to form a composite roving, wherein the weight of said plurality of inner fibers and said plurality of outer fibers within said composite roving after the drying step comprises between approximately ten and eighty percent of the total dry weight of said coated fiber bundle. 9. The method of claim 5, wherein the step of drying said coated fiber bundle to form a composite roving comprises the step of heating said coated fiber bundle in a drying oven to remove a quantity of water from said aqueous powder coating to form a composite roving, wherein the weight of said plurality of inner fibers and said plurality of outer fibers within said composite roving after the drying step comprises between approximately ten and eighty percent of the total dry weight of said coated fiber bundle. 10. The method of claim 5, wherein the step of drying said coated fiber bundle to form a composite roving comprises the step of air-drying said coated fiber bundle to remove a quantity of water from said aqueous powder coating to form a composite roving, wherein the weight of said plurality of inner fibers and said plurality of outer fibers within said composite roving after the air-drying step comprises between approximately ten and eighty percent of the total weight of said coated fiber bundle. 11. The method of claim 5, wherein the step of chopping said composite roving into a plurality of chopped strands comprising the steps of chopping said composite roving in the presence of a hot air source device, wherein said hot air source device partially melts and tackified said powder coating material on said composite roving; and impacting said composite roving on a mold surface with sufficiently high temperature to keep said powder coating material tackified without reversibly curing said powder coating material. 12. The method of claim 5, wherein the step of compression molding said plurality of chopped strands to a desired shape to form the structural composite part comprises the steps of: placing said plurality of chopped stands onto a preforming screen to form a preform; heat consolidating said preform to form a handleable perform; placing said handleable preform between a lower mold section and an upper mold section of a press; compressing said handleable preform between said lower mold section and said upper mold section of said press for a predetermined amount of time at a predetermined pressure and at a predetermined elevated temperature of said upper mold section sufficient to melt flow and cure a powder coating material contained within said composite roving to form the structural composite part; and releasing the structural composite part from said press. 13. The method of claim 12, wherein said predetermined elevated temperature is between approximately 300 and 450 degrees Fahrenheit and said predetermined pressure is between approximately 300 and 1200 pounds per square inch. 14. The method of claim 5, wherein the step compression molding said plurality of chopped strands to a desired shape to form the structural composite part comprises the steps of: placing said plurality of chopped stands onto a moving belt; compacting and heating said plurality of chopped strands to form a perform; cutting said preform to a desired size and shape; placing at least one layer of said preform between a lower mold section and an upper mold section of a press; compressing said preform between said lower mold section and said upper mold section of said press for a predetermined amount of time at a predetermined pressure and at a predetermined elevated temperature of said upper mold section sufficient to melt, flow and cure a powder coating material contained within said composite roving to form the structural composite part; and releasing the structural composite part from said press. 15. The method of claim 14, wherein said predetermined elevated temperature is between approximately 300 and 450 degrees Fahrenheit and said predetermined pressure is between approximately 300 and 1200 pounds per square inch. 16. The method of claim 1, further comprising the steps of: coupling a plurality of strands of said composite roving to form a fabric; placing at least one layer of said fabric in a mold; and compression molding said at least one layer of fabric at a predetermined temperature and a predetermined pressure to form the structural composite part, wherein the weight of said plurality of inner fibers and said pluratilty of outer fibers within said coin composite roving corn rises between a approximately ten and eighty percent of the dry total weight of said coated fiber bundle. 17. The method of claim 16, wherein the step of coupling a plurality of strands of said composite roving to form a fabric comprises the step of weaving a plurality of strands of said composite roving to form a fabric. 18. The method of claim 16, wherein the step of coupling a plurality of strands of said composite roving to form a fabric comprises the step of knitting a plurality of strands of said composite roving to form a fabric. 19. The method of claim 16, wherein the step of coupling a plurality of strands of said composite roving to form a fabric comprises the step of braiding a plurality of strands of said composite roving to form a fabric. 20. The method of claim 1, wherein said first fiber type is selected from the group consisting of e-type glass, s-type glass, carbon fiber, aramid fibers, synthetic fibers, and natural fibers. 21. The method of claim 1, wherein the step of applying a first amount of an aqueous powder coating comprises the step of metering said coating between approximately ten and eighty percent by weight of the dry total weight the composite roving. 22. The method of claim 1, wherein the step of applying a first amount of an aqueous powder coating comprises the step of metering said coating between approximately twenty and thirty percent by weight of the dry total weight the composite roving. 23. The method of claim 1, wherein the step of applying said powder coating comprises the step of applying a powder coating selected from the group consisting of a polyester powder coating, a bisphenol-type epoxy powder coating, a novalac epoxy powder coating, a phenolic powder coating, a hybrid epoxy and polyester powder coating, a polyurethane powder coating, and an acrylic powder coating. 24. The method of claim 1, wherein the step of applying said powder coating comprises the step of applying a thermoplastic powder coating. 25. The method of claim 1, wherein said aqueous powder coating comprises a powdered polymer, water and one or more members selected from a film former and a thickener. 26. A method for forming a composite roving package for use in structural composites comprising: forming a coated fiber bundle, said bundle being formed of a plurality of inner fibers and a plurality of outer fibers surrounding said inner fibers, said inner and outer fibers being held together by a size composition that maintains said inner and outer fibers in said bundle during subsequent processing; applying a first amount of an aqueous powder coating to an outer portion of said sized fiber bundle to form a coated fiber bundle; drying said coated fiber bundle to remove water from said aqueous powder coating and form a dried composite roving; cooling said dried composite roving; and winding said cooled composite roving into a roving package. 27. The method of claim 26, wherein said aqueous powder coating comprises a powdered polymer, water, and at least one member selected from a film former and thickener. 28. A method for forming a composite roving for use in structural composites comprising the steps of: forming a sized fiber bundle, said bundle being formed of a plurality of inner fibers and a plurality of outer fibers surrounding said inner fibers, said inner and outer fibers being held together by a size composition that maintains said inner and outer fibers in said bundle during subsequent processing; applying a first amount of an aqueous powder coating including a water, one or more powdered polymer, and at least one member selected from a film former and a thickener to an outer portion of said outer fibers to form a coated fiber bundle, said aqueous powder coating substantially surrounding said fiber bundle; and drying said coated fiber bundle to remove water from said aqueous powder coating.
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