초록 ▼

This catalyst system simultaneously removes ammonia and enhances net NOx conversion by placing an NH3—SCR catalyst formulation downstream of a lean NOx trap. By doing so, the NH3—SCR catalyst adsorbs the ammonia from the upstream lean NOx trap generated during the rich pulses. The stor

This catalyst system simultaneously removes ammonia and enhances net NOx conversion by placing an NH3—SCR catalyst formulation downstream of a lean NOx trap. By doing so, the NH3—SCR catalyst adsorbs the ammonia from the upstream lean NOx trap generated during the rich pulses. The stored ammonia then reacts with the NOx emitted from the upstream lean NOx trap-enhancing the net NOx conversion rate significantly, while depleting the stored ammonia. By combining the lean NOx trap with the NH3—SCR catalyst, the system allows for the reduction or elimination of NH3 and NOx slip, reduction in NOx spikes and thus an improved net NOx conversion during lean and rich operation.

대표청구항 ▼

We claim: 1. An NOx purifying catalyst for purifying NOx in exhaust gas discharged from an internal combustion engine with air-fuel ratios controlled to be lean and rich, comprising: a first catalytic layer that includes a zeolite having at least one element selected from the group consisting of ir

We claim: 1. An NOx purifying catalyst for purifying NOx in exhaust gas discharged from an internal combustion engine with air-fuel ratios controlled to be lean and rich, comprising: a first catalytic layer that includes a zeolite having at least one element selected from the group consisting of iron and cerium elements; a second catalytic layer that includes a noble metal and cerium oxide-based material; wherein the second and the first catalytic layers are coated on a support in that order, so that the first catalytic layer is the uppermost layer, NOx passes through the first catalytic layer and is oxidized and adsorbed on the second catalytic layer in the lean condition, NOx adsorbed on the second catalytic layer is converted to NH3 by the reaction with a reductant on the second catalytic layer, the NH3 is then transferred to and adsorbed on the first catalytic layer in the rich region, and the NH3 reacts with NOx to be converted to nitrogen and water. 2. The NOx purifying catalyst according to claim 1, wherein the noble metal is at least one selected from the group consisting of platinum, rhodium and palladium. 3. The NOx purifying catalyst according to claim 1, wherein the reductant is at least one selected from the group consisting of CO and HC components of the exhaust gas, and hydrogen generated from at least one of the CO and HC components contacting with the second catalytic layer. 4. The NOx purifying catalyst according to claim 1, wherein the second catalytic layer further comprises heat resisting inorganic oxide. 5. The NOx purifying catalyst according to claim 4, wherein the inorganic oxide comprises a zirconium oxide-based material. 6. The NOx purifying catalyst according to claim 5, wherein the zirconium oxide-based material is at least one oxide selected from zirconium oxide and composite oxide of zirconium and rare earth elements. 7. The NOx purifying catalyst according to claim 1, wherein the cerium oxide-based material in the second catalytic layer is at least one oxide selected from cerium oxide and composite oxide of cerium and rare earth elements. 8. The NOx purifying catalyst according to claim 1, wherein the second catalytic layer further comprises a washcoat. 9. The NOx purifying catalyst according to claim 1, wherein the second catalytic layer further comprises an inorganic oxide including at least one of alkali metals, alkali earth metals, rare earth metals, a composite of cerium and zirconium or combinations thereof.