초록 ▼

The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on the weigh

The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on the weight of the second part of i) a halogenated polyolefin having halosulfonyl groups or ii) a mixture of a halogenated polyolefin and an organic sulfonyl halide. The second part may further contain a compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprise one or more compounds capable of free radical polymerization.

대표청구항 ▼

The invention claimed is: 1. A method of polymerization comprising contacting the components of a polymerizable composition comprising a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species wherein the organoboron compo

The invention claimed is: 1. A method of polymerization comprising contacting the components of a polymerizable composition comprising a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species wherein the organoboron compound is a complex of a trialkyl borane and a compound having a primary amine and one or more hydrogen bond accepting groups, wherein the one or more hydrogen bond accepting group is selected from ether, polyether or thioether, and there are at least two carbon atoms between the primary amine and the hydrogen bond accepting groups and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on 100 parts by weight of the second part of a chlorinated polyethylene having chlorosulfonyl groups and a liberating compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts under conditions such that the one or more compounds capable of free radical polymerization undergo polymerization. 2. A method of polymerization according to claim 1 wherein the contacting occurs at, or near, ambient temperature. 3. A method of bonding two or more substrates together which comprises: contacting the components of a composition comprising a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species wherein the organoboron compound is a complex of a trialkyl borane and a compound having a primary amine and one or more hydrogen bond accepting groups, wherein the one or more hydrogen bond accepting groups is selected from ether, polyether, or thioether, and there are at least two carbon atoms between the primary amine and the hydrogen bond accepting groups and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on 100 parts by weight of the second part of a chlorinated polyethylene having chlorosulfonyl groups and a liberating compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts together under conditions such that polymerization is initiated; contacting the composition with the two or more substrates; positioning the two or more substrates such that the composition is located between the two or more substrates wherein they are in contact with one another; and allowing the composition to cure so as to bind the two or more substrates together. 4. A method of bonding according to claim 3 wherein the contacting of the two part polymerizable composition and of the composition with the substrates occurs at, or near, ambient temperature. 5. A method of coating a substrate which comprises contacting the components a composition comprising a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species wherein the organoboron compound is a complex of a trialkyl borane and a compound having a primary amine and one or more hydrogen bond accepting groups, wherein the one or more hydrogen bond accepting groups is selected from ether, polyether, or thioether, and there are at least two carbon atoms between the primary amine and the hydrogen bond accepting groups, and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on 100 parts by weight of the second part of a chlorinated polyethylene having chlorosulfonyl groups and a liberating compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts; contacting the contacted composition with one or more surfaces of a substrate; and allowing the composition to cure. 6. A coating composition comprising a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species wherein the organoboron compound is a complex of a trialkyl borane and a compound having a primary amine and one or more hydrogen bond accepting groups, wherein the one more hydrogen bond accepting groups is selected from ether, polyether, or thioether, and there are at least two carbon atoms between the primary amine and the hydrogen bond accepting groups and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on 100 parts by weight of the second part of a chlorinated polyethylene having chlorosulfonyl groups and a liberating compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts; and one or more of one or more carriers or one or more pigments. 7. A method according to claim 1 wherein the first part further comprises one or more compounds capable of free radical polymerization. 8. A method according to claim 1 wherein the one or more compounds capable of free radical polymerization comprise acrylate or methacrylate based monomers, oligomers, polymers or a mixture thereof. 9. A method according to claim 1 wherein the weight of the chlorine on the chlorinated polyethylene having chlorosulfonyl groups is about 20 percent to about 45 percent based on the weight of the chlorinated polyethylene having chlorosulfonyl groups. 10. A method according to claim 3 wherein the first part further comprises one or more compounds capable of free radical polymerization. 11. A method according to claim 3 wherein the one or more compounds capable of free radical polymerization comprise acrylate or methacrylate based monomers, oligomers, polymers or a mixture thereof. 12. A method according to claim 3 wherein the weight of the chlorine on the chlorinated polyethylene having chlorosulfonyl groups is about 20 percent to about 45 percent based on the weight of the chlorinated polyethylene having chlorosulfonyl groups. 13. A composition according to claim 6 wherein the first part further comprises one or more compounds capable of free radical polymerization. 14. A composition according to claim 6 wherein the one or more compounds capable of free radical polymerization comprise acrylate or methacrylate based monomers, oligomers, polymers or a mixture thereof. 15. A composition according to claim 6 wherein the weight of the chlorine on the chlorinated polyethylene having chlorosulfonyl groups is about 20 percent to about 45 percent based on the weight of the chlorinated polyethylene having chlorosulfonyl groups.