Methods for reducing bond strengths, dental compositions, and the use thereof
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08J-003/28
C08F-002/50
C08F-002/46
A61K-006/08
A61K-006/083
A61K-006/00
출원번호
UP-0275238
(2005-12-20)
등록번호
US-7776940
(2010-09-06)
발명자
/ 주소
Kalgutkar, Rajdeep S.
Brennan, Joan V.
Gaddam, Babu N.
출원인 / 주소
3M Innovative Properties Company
대리인 / 주소
Weber, Kevin W.
인용정보
피인용 횟수 :
0인용 특허 :
137
초록▼
Hardenable and hardened dental compositions, and articles including such hardenable and hardened compositions, are provided. In some embodiments, the hardenable dental compositions include an acid-generating component and an acid-reactive component including one or more acid-reactive groups. Upon ir
Hardenable and hardened dental compositions, and articles including such hardenable and hardened compositions, are provided. In some embodiments, the hardenable dental compositions include an acid-generating component and an acid-reactive component including one or more acid-reactive groups. Upon irradiating, and optionally heating, the hardened compositions are useful, for example, for reducing the bond strength of orthodontic appliances adhered to tooth structures with the hardened compositions.
대표청구항▼
What is claimed is: 1. A method for reducing the bond strength of an orthodontic appliance adhered to a tooth structure with a hardened dental composition, the method comprising irradiating the hardened dental composition, wherein the hardened dental composition comprises an acid-generating compone
What is claimed is: 1. A method for reducing the bond strength of an orthodontic appliance adhered to a tooth structure with a hardened dental composition, the method comprising irradiating the hardened dental composition, wherein the hardened dental composition comprises an acid-generating component and an acid-reactive component that comprises one or more acid-reactive groups. 2. The method of claim 1 wherein irradiating the hardened dental composition results in the acid-generating component generating an acid that reacts with greater than a stoichiometric amount of the one or more acid-reactive groups. 3. The method of claim 2 wherein the acid-generating component comprises a sulfonium salt, and optionally a sensitizer. 4. The method of claim 3 wherein irradiating comprises irradiating with ultraviolet A radiation and/or visible radiation. 5. The method of claim 1 wherein the acid-reactive component is formed by polymerizing one or more compounds including a compound selected from the group consisting of: compounds represented by the formula (Formula I): wherein R1 and R2 each independently represent an organic group; R3 and R4 each independently represent hydrogen or an organic group, with the proviso that only one of R3 and R4 can be hydrogen; each E1 and E2 independently represents an ethylenically unsaturated group; and m and n are each independently 0 or 1, and wherein R1 and E1 can optionally be combined to form one or more rings and/or two or more groups among R2, R3, R4, and E2 can optionally be combined to form one or more rings; compounds represented by the formula (Formula II): wherein R5, R6, R7, and R8 each independently represent an organic group; each E3 and E4 independently represents an ethylenically unsaturated group; and x, y, and z are each independently 0 or 1, with the proviso that if z=0, then at least one of R7 and R8 represents an ethylenically unsaturated group, with R5 and R6 being selected to allow for, upon exposure to acid, preferential cleavage from the acetal of the oxygen atom attached to R5 over the oxygen atom attached to R6; and wherein two or more of R5, R6, R7, R8, E3, and/or E4 can optionally be combined to form one or more rings, with the proviso that the one or more rings do not interfere with the ability of the acid-reactive group to form two or more separate groups upon reaction with acid; and combinations thereof 6. The method of claim 1 further comprising heating at least a portion of the irradiated hardened dental composition to at least 42° C. 7. The method of claim 1 wherein the hardened dental composition is a hardened primer, and the orthodontic appliance is further adhered to a primed tooth structure with a hardened orthodontic adhesive. 8. The method of claim 7 further comprising removing the orthodontic appliance from the tooth structure, wherein the hardened orthodontic adhesive is substantially retained on the removed orthodontic appliance. 9. A method for reducing the adherence of a hardened dental composition to a tooth structure, the method comprising irradiating the hardened dental composition to reduce the adherence, wherein the hardened dental composition comprises an acid-generating component and an acid-reactive component comprising one or more acid-reactive groups. 10. A method for reducing the bond strength of an orthodontic appliance adhered to a tooth structure with a hardened dental composition, the method comprising: irradiating the hardened dental composition; and subsequently heating the irradiated hardened dental composition, resulting in a reduced bond strength. 11. The method of claim 10 wherein the hardened dental composition comprises a radiation-to-heat converter, and heating comprises irradiating the hardened dental composition. 12. A hardenable dental composition comprising: a hardenable component comprising one or more acid-reactive groups; and an acid-generating component, wherein the hardenable component comprising the one or more acid-reactive groups is selected from the group consisting of: compounds represented by the formula (Formula I): wherein R1 and R2 each independently represent an organic group; R3 and R4 each independently represent hydrogen or an organic group, with the proviso that only one of R3 and R4 can be hydrogen; each E1 and E2 independently represents an ethylenically unsaturated group; and m and n are each independently 0 or 1, and wherein R1 and E1 can optionally be combined to form one or more rings and/or two or more groups among R2, R3, R4, and E2 can optionally be combined to form one or more rings; compounds represented by the formula (Formula II): wherein R5, R6, R7, and R8 each independently represent an organic group; each E3 and E4 independently represents an ethylenically unsaturated group; and x, y, and z are each independently 0 or 1, with the proviso that if z=0, then at least one of R7 and R8 represents an ethylenically unsaturated group, with R5 and R6 being selected to allow for, upon exposure to acid, preferential cleavage from the acetal of the oxygen atom attached to R5 over the oxygen atom attached to R6; and wherein two or more of R5, R6, R7, R8, E3, and/or E4 can optionally be combined to form one or more rings, with the proviso that the one or more rings do not interfere with the ability of the acid-reactive group to form two or more separate groups upon reaction with acid; and combinations thereof. 13. An orthodontic appliance having a base for bonding the appliance to a tooth structure; and a hardenable dental composition on the base of the appliance, wherein the hardenable dental composition comprises: an acid-generating component; a hardenable component comprising one or more acid-reactive groups; and an initiator for initiating the hardening of the hardenable dental composition, wherein the hardenable component comprising the one or more acid-reactive groups is selected from the group consisting of: compounds represented by the formula (Formula I): wherein R1 and R2 each independently represent an organic group; R3 and R4 each independently represent hydrogen or an organic group, with the proviso that only one of R3 and R4 can be hydrogen; each E1 and E2 independently represents an ethylenically unsaturated group; and m and n are each independently 0 or 1, and wherein R1 and E1 can optionally be combined to form one or more rings and/or two or more groups among R2, R3, R4, and E2 can optionally be combined to form one or more rings; compounds represented by the formula (Formula II): wherein R5, R6, R7, and R8 each independently represent an organic group; each E3 and E4 independently represents an ethylenically unsaturated group; and x, y, and z are each independently 0 or 1, with the proviso that if z=0, then at least one of R7 and R8 represents an ethylenically unsaturated group, with R5 and R6 being selected to allow for, upon exposure to acid, preferential cleavage from the acetal of the oxygen atom attached to R5 over the oxygen atom attached to R6; and wherein two or more of R5, R6, R7, R8, E3, and/or E4 can optionally be combined to form one or more rings, with the proviso that the one or more rings do not interfere with the ability of the acid-reactive group to form two or more separate groups upon reaction with acid; and combinations thereof. 14. An orthodontic appliance having a base for bonding the appliance to a tooth structure; and a hardened dental composition on the base of the appliance, wherein the hardened dental composition comprises an acid-generating component and an acid-reactive component comprising one or more acid-reactive groups; and one or more additional layers of different hardenable and/or hardened dental compositions. 15. A method for bonding an orthodontic appliance to a tooth, the method comprising: providing a precoated orthodontic appliance having a base for bonding the appliance to a tooth structure, wherein the appliance includes a hardened dental composition comprising an acid-generating component and an acid-reactive component on the base thereof and a hardenable orthodontic adhesive on the hardened dental composition; applying the base of the appliance having the hardenable orthodontic adhesive on the hardened dental composition thereon to the tooth structure; and hardening the orthodontic adhesive, wherein the precoated appliance further comprises one or more additional layers of different hardenable and/or hardened dental compositions.
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