Ammonia SCR catalyst and method of using the catalyst
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01D-053/56
B01J-023/00
B01J-023/10
B01J-023/34
B01J-023/26
B01J-023/74
B01J-023/72
출원번호
UP-0313501
(2008-11-20)
등록번호
US-7785551
(2010-09-20)
발명자
/ 주소
Golden, Stephen J.
Iretskaya, Svetlana
출원인 / 주소
Catalytic Solutions, Inc.
대리인 / 주소
McNichol, Jr., William J.
인용정보
피인용 횟수 :
4인용 특허 :
30
초록▼
A catalyst and a method for selectively reducing nitrogen oxides with ammonia are provided. The catalyst includes a first component of copper, chromium, cobalt, nickel, manganese, iron, niobium, or mixtures thereof, a second component of cerium, a lanthanide, a mixture of lanthanides, or mixtures th
A catalyst and a method for selectively reducing nitrogen oxides with ammonia are provided. The catalyst includes a first component of copper, chromium, cobalt, nickel, manganese, iron, niobium, or mixtures thereof, a second component of cerium, a lanthanide, a mixture of lanthanides, or mixtures thereof, and a zeolite. The catalyst may also include strontium as an additional second component. The catalyst selectively reduces nitrogen oxides to nitrogen with ammonia at low temperatures. The catalyst has high hydrothermal stability. The catalyst has high activity for conversion of nitrogen oxides in exhaust streams, and are not significantly influenced by the NO/NO2 ratio. The catalyst and the method may have special application to selective reduction of nitrogen oxides in exhaust gas from diesel vehicles, although the catalyst and the method have broad application to a wide range of gas streams that contain nitrogen oxides.
대표청구항▼
What is claimed is: 1. A catalyst for selective catalytic reduction of nitrogen oxides with ammonia, the catalyst comprising: a first component comprising at least one selected from the group consisting of copper, chromium, cobalt, nickel, manganese, iron, niobium, and mixtures thereof; a second co
What is claimed is: 1. A catalyst for selective catalytic reduction of nitrogen oxides with ammonia, the catalyst comprising: a first component comprising at least one selected from the group consisting of copper, chromium, cobalt, nickel, manganese, iron, niobium, and mixtures thereof; a second component comprising at least one selected from the group consisting of cerium, a lanthanide, a mixture of lanthanides, and mixtures thereof; and at least one unexchanged zeolite. 2. The catalyst of claim 1, wherein the catalyst comprises approximately 1 to approximately 20 weight percent of the first component, approximately 2 to approximately 35 weight percent of the second component, and approximately 10 to approximately 90 weight % of the at least one zeolite, wherein the weight percentages of the first component and the second component are on the basis of the metals. 3. The catalyst of claim 1, wherein the zeolite is selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-18, ZSM-23, MCM-zeolites, mordenite, faujasite, ferrierite, zeolite beta, and mixtures thereof. 4. The catalyst of claim 1, wherein the first component is manganese, the second component is cerium, and the zeolite is ZSM-5. 5. A catalyst composition comprising: a substrate; and a catalyst for selective catalytic reduction of nitrogen oxides with ammonia, the catalyst comprising: a first component comprising at least one selected from the group consisting of copper, chromium, cobalt, nickel, manganese, iron, niobium, and mixtures thereof; a second component comprising at least one selected from the group consisting of cerium, a lanthanide, a mixture of lanthanides, and mixtures thereof; and at least one unexchanged zeolite, wherein the catalyst is placed on the substrate. 6. The catalyst composition of claim 5, further comprising at least one inorganic oxide selected from the group consisting of alumina, silica, titania, and silica-alumina solutions, composites, and mixtures thereof. 7. A method for selective reduction of nitrogen oxides in a gas stream with ammonia, wherein the gas stream comprises nitrogen oxides, the method comprising: contacting the gas stream with ammonia in the presence of a catalyst, the catalyst comprising: a first component comprising at least one selected from the group consisting of copper, chromium, cobalt, nickel, manganese, iron, niobium, and mixtures thereof; a second component comprising at least one selected from the group consisting of cerium, a lanthanide, a mixture of lanthanides, and mixtures thereof; and at least one unexchanged zeolite. 8. The method of claim 7, wherein the gas stream is contacted with ammonia at a temperature of approximately 140 to approximately 700 degrees Centigrade and has an ammonia/NOx mole ratio of approximately 0.6 to approximately 2.0. 9. The method of claim 7, wherein the catalyst comprises approximately 1 to approximately 20 weight percent of the first component, approximately 2 to approximately 35 weight percent of the second component, and approximately 10 to approximately 90 weight % of the at least one zeolite, wherein the weight percentages of the first component and the second component are on the basis of the metals. 10. The method of claim 7, wherein the zeolite is selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-18, ZSM-23, MCM-zeolites, mordenite, faujasite, ferrierite, zeolite beta, and mixtures thereof. 11. The method of claim 7, wherein the first component is manganese, the second component is cerium, and the zeolite is ZSM-5. 12. The method of claim 7, further comprising contacting the gas stream and ammonia with at least one inorganic oxide selected from the group consisting of alumina, silica, titania, and silica-alumina solutions, composites, and mixtures thereof.
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이 특허에 인용된 특허 (30)
Golden, Stephen J.; Iretskaya, Svetlana, Ammonia SCR catalyst and method of using the catalyst.
Domesle Rainer (Maintal DEX) Engler Bernd (Hanau DEX) Koberstein Edgar (Alzenau DEX) Vlker Herbert (Hanau DEX), Apparatus for the purification of exhaust gas from diesel motors.
Farnos Maria D. (Wilmington DE) McWilliams John P. (Woodbury NJ) Sharma Sanjay B. (Langhorne PA) Shihabi David S. (Pennington NJ), Catalytic system for the reducton of nitrogen oxides.
Viel Lamare Charles,FIX ; Hiltunen Matti,FIX ; Lee Yam, Method of purifying gases containing nitrogen oxides and an apparatus for purifying gases in a steam generation boiler.
Ito Eri,JPX ; C.M. van den Bleek Cornelis Maria,NLX ; van Bekkum Herman H.,NLX ; J.C. Jansen Jacobus Cornelis,NLX ; R.J. Hultermans Ronald Johannes,NLX ; P. M. Lugt Pieter Martin,NLX, Process for treating nitrogen oxide-containing gas using a cerium zeolite.
Chojnacki, Dennis A.; Rabovitser, Iosif K.; Knight, Richard A.; Cygan, David F.; Korenberg, Jacob, Super low NOx, high efficiency, compact firetube boiler.
Tran, Pascaline Harrison; Liu, Xinsheng; Liu, Ye; Galligan, Michael P.; Zhang, Qinglin; Horimura, Hiroyuki; Iwasa, Akiko, Base metal catalyst composition and methods of treating exhaust from a motorcycle.
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