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The present invention is directed to methods and systems for processing triglyceride-containing, biologically-derived oils, wherein such processing comprises conversion of triglycerides to free fatty acids and the separation of these fatty acids by saturation type. Such separation by type enables th

The present invention is directed to methods and systems for processing triglyceride-containing, biologically-derived oils, wherein such processing comprises conversion of triglycerides to free fatty acids and the separation of these fatty acids by saturation type. Such separation by type enables the efficient preparation of both lubricants and transportation fuels from a common source using a single integrated method and/or system.

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What is claimed: 1. A method comprising the steps of: a) providing a quantity of biologically-derived oil comprising triglycerides; b) processing the biologically-derived oil so as to hydrolyze at least some of the triglycerides contained therein so as to form free fatty acids therefrom, wherein th

What is claimed: 1. A method comprising the steps of: a) providing a quantity of biologically-derived oil comprising triglycerides; b) processing the biologically-derived oil so as to hydrolyze at least some of the triglycerides contained therein so as to form free fatty acids therefrom, wherein the fatty acids are of a type selected from the group consisting of saturated fatty acids, monounsaturated fatty acids, and polyunsaturated fatty acids, and combinations thereof; c) separating the fatty acids by type, such that at least the monounsaturated fatty acids are substantially isolated from the saturated fatty acids and the polyunsaturated fatty acids; d) modifying at least some of the monounsaturated fatty acids to form an ester product; and e) hydrotreating at least some of the fatty acids selected from the group consisting of saturated fatty acids, polyunsaturated fatty acids, and combinations thereof, so as to yield alkanes. 2. The method of claim 1, further comprising a step of subjecting biomass to an extraction process, wherein said extraction process provides for a quantity of biologically-derived oil comprising triglycerides. 3. The method of claim 1, further comprising a step of catalytically isomerizing at least some of the alkanes to yield an isomerized alkane mixture. 4. The method of claim 1, wherein the ester product comprises triester species. 5. The method of claim 1, wherein the biologically-derived oil originated from a biomass source selected from the group consisting of crops, vegetables, microalgae, and combinations thereof. 6. The method of claim 1, wherein the processing step comprises acid- or base-catalyzed hydrolysis. 7. The method of claim 1, wherein the separating step comprises fractional crystallization. 8. The method of claim 1, wherein the saturated fatty acids and the polyunsaturated fatty acids are substantially isolated from each other. 9. The method of claim 8, wherein at least some of the saturated fatty acids are esterified to yield a biodiesel product. 10. The method of claim 1, wherein the step of modifying comprises the following substeps: a) esterifying monounsaturated fatty acids so as to form unsaturated esters; b) epoxidizing the unsaturated esters to form epoxy-ester species comprising an epoxide ring; c) opening the ring of the epoxy-ester species to form dihydroxy esters; and d) esterifying at least some of the dihydroxy esters with an esterifying species to form the ester product, wherein the esterifying species is selected from the group consisting of carboxylic acids, acyl halides, acyl anhydrides, and combinations thereof. 11. The method of claim 10, wherein the substep of esterifying the monounsaturated fatty acids involves at least one alcohol species. 12. The method of claim 11, wherein the substep of esterifying the monounsaturated fatty acids with at least one alcohol species involves conversion of the fatty acids to species selected from the group consisting of acyl halide species, acyl anhydride species, and combinations thereof. 13. The method of claim 10, wherein the substep of opening the ring of the epoxy-ester species to form dihydroxy esters involves an acid-catalyzed reaction. 14. The method of claim 1, further comprising a step of blending the ester product with one or more other ester species derived from a different source. 15. The method of claim 1, further comprising a step of blending the ester product with a base oil selected from the group consisting of Group I oils, Group II oils, Group III oils, and combinations thereof. 16. The method of claim 1, wherein the step of hydrotreating involves a hydroprocessing catalyst and a hydrogen-containing environment. 17. The method of claim 16, wherein the hydroprocessing catalyst is selected from the group consisting of cobalt-molybdenum (Co—Mo) catalyst, nickel-molybdenum (Ni—Mo) catalyst, noble metal catalyst, and combinations thereof. 18. The method of claim 3, wherein the step of catalytically-isomerizing involves an isomerization catalyst comprising metal selected from the group consisting of Pt, Pd, and combinations thereof. 19. The method of claim 3, wherein the isomerized alkane mixture is suitable for use as a transportation fuel. 20. The method of claim 3, wherein the isomerized alkane mixture is mixed with existing transportation fuels in order to modify their properties. 21. A method comprising the steps of: a) extracting, from a biomass source, a quantity of vegetable oil comprising triglycerides; b) processing the vegetable oil to hydrolyze at least some of the triglycerides contained therein so as to form free fatty acids therefrom, wherein the fatty acids are of a type selected from the group consisting of saturated fatty acids, monounsaturated fatty acids, and polyunsaturated fatty acids, and combinations thereof; c) separating the fatty acids by type, such that at least the monounsaturated fatty acids are substantially isolated from the saturated fatty acids and the polyunsaturated fatty acids, wherein such separation is effected by fractional crystallization; d) modifying at least some of the monounsaturated fatty acids to form an ester product suitable for use as a lubricant, wherein such modifying comprises the following substeps: i) esterifying monounsaturated fatty acids so as to form unsaturated esters; ii) epoxidizing the unsaturated esters to form epoxy-ester species comprising an epoxide ring; iii) opening the ring of the epoxy-ester species to form dihydroxy esters, wherein said opening involves an acid-catalyzed reaction; and iv) esterifying the dihydroxy esters with an esterifying species to form the ester product, wherein the esterifying species is selected from the group consisting of carboxylic acids, acyl halides, acyl anhydrides, and combinations thereof; e) catalytically hydrotreating at least some of the fatty acids selected from the group consisting of saturated fatty acids, polyunsaturated fatty acids, and combinations thereof, so as to yield alkanes; and f) catalytically isomerizing at least some of the alkanes to yield an isomerized alkane mixture suitable for use as a transportation fuel or component thereof. 22. A system for processing triglyceride-containing, biologically-derived oil, the system comprising the following elements: a) a hydrolysis unit for treating the biologically-derived oil so as to hydrolyze at least some of the triglycerides contained therein, thereby forming free fatty acids; b) a separation unit for separating the free fatty acids by saturation type, wherein said separating provides for i) a first portion comprising predominately monounsaturated fatty acids; and ii) a second portion comprising predominately fatty acids other than monounsaturated fatty acids, wherein said other fatty acids are selected from the group consisting of saturated fatty acids, polyunsaturated fatty acids, and combinations thereof; c) an esterification unit for converting at least some of the monounsaturated fatty acids in the first portion so as to provide for an ester product suitable for use as a biolubricant; and d) a hydroprocessing unit for hydrotreating saturated and polyunsaturated fatty acids in the second portion so as to produce paraffinic species. 23. The system of claim 22, further comprising an oil extraction unit for extracting the triglyceride-containing oil from biomass. 24. The system of claim 22, further comprising an isomerization unit for isomerizing at least some of the paraffinic species produced by the hydroprocessing unit. 25. The system of claim 22, further comprising a secondary separation unit for treating the second portion so as to substantially isolate the saturated fatty from the polyunsaturated fatty acids.