The invention is amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate anion wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyam
The invention is amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate anion wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms, and a cationic counter ion.
대표청구항▼
What is claimed is: 1. An amido-borate compound which corresponds to one of the formulas: R1 is independently in each occurrence an alkyl or cycloalkyl group, or two or more of R1 may combine to form a cycloaliphatic ring; R2 is independently in each occurrence an alkyl, cycloalkyl, aryl, alkary
What is claimed is: 1. An amido-borate compound which corresponds to one of the formulas: R1 is independently in each occurrence an alkyl or cycloalkyl group, or two or more of R1 may combine to form a cycloaliphatic ring; R2 is independently in each occurrence an alkyl, cycloalkyl, aryl, alkaryl, or aralkyl group containing one or more heteroatoms; R3 is independently in each occurrence hydrogen, an alkyl or an aryl group which may optionally contain one or more heteroatoms; R4 is independently in each occurrence a divalent hydrocarbyl moiety which may optionally contain one or more heteroatoms; R5 is independently in each occurrence a t-valent hydrocarbyl group; X is independently in each occurrence a cation; Y is independently in each occurrence Z is independently in each occurrence N, P, Si or C; p is independently in each occurrence 0 or 1; q is independently in each occurrence 1 or 2; with the proviso that the sum of p and q on each linked boron and nitrogen pair is 2 and the sum of the p and q is 1 or 2; where q is 2 the nitrogen to which it is bonded is quaternary and carries a positive charge which balances the negative charge found on the boron of the borate and a cation is not needed to neutralize the borate; t is independently in each occurrence 2 or greater; and w is independently in each occurrence either 0 or 1. 2. Compounds according to claim 1 wherein: R1 is independently in each occurrence a C1-10 alkyl, C3-10 cycloalkyl or two or more of R1 may combine to form a cycloaliphatic ring; R2 is independently in each occurrence C1-10 alkyl, C3-10 cycloalkyl, C6-12 aryl, C7-20 alkaryl or C7-20 aralkyl wherein such groups contain one or more heteroatoms of O or S, or an O or S containing functional moieties; R3 is independently in each occurrence hydrogen C1-10 alkyl, C3-20 cycloalkyl, C6-20 aryl, C7-20 alkaryl, C7-20 aralkyl optionally containing one or more heteroatoms or heteroatom containing functional moieties; R5 is independently in each occurrence a t-valent alkylene group; X is independently in each occurrence is an onium or an alkali metal ion; Y is independently in each occurrence Z is independently in each occurrence is N or C; and t is 2 or 3. 3. Compounds according to claim 2 wherein: R1 is independently each in occurrence C1-4 alkyl; R2 is independently in each occurrence C1-10 alkoxyalkyl; R3 is independently in each occurrence hydrogen, C1-4 alkyl or C1-10 alkoxyalkyl; R4 is independently in each occurrence C2-20 alkylene or C2-20 alkylene containing one or more oxygen atoms; R5 is independently in each occurrence a t-valent, C2-6 alkylene moiety; X is an ammonium, phosphonium, sodium or lithium ion; and t is 2. 4. Compounds according to claim 3 wherein: R1 is independently in each occurrence C2-4 alkyl; R2 is independently in each occurrence methoxy propyl, alkoxypropyl or propoxypropyl; R3 is independently in each occurrence hydrogen, methyl, ethyl or propyl; R4 is independently in each occurrence C2-4 alkylene; R5 is a divalent C2-4 alkylene group, and X is tetraethyl ammonium, tetraethyl phosphonium, tetraphenyl phosphonium, sodium or lithium. 5. Compounds according to claim 1 which correspond to one of the formulas: wherein; R1 is independently in each occurrence an alkyl or cycloalkyl group, or two or more or R1 may combine to form a cycloaliphatic ring; R2 is independently in each occurrence an alkyl, cycloalkyl, aryl, alkaryl, or aralkyl group containing one or more heteroatoms or heteroatom containing functional moieties; R3 is independently in each occurrence hydrogen, an alkyl or an aryl group which may optionally contain one or more heteroatoms or heteroatom containing functional moieties; R4 is independently in each occurrence a divalent hydrocarbyl moiety which may optionally contain one or more heteroatoms or heteroatom containing functional moieties; X is independently in each occurrence a cation; Z is independently in each occurrence N, P, Si or C; p is independently in each occurrence 0 or 1; q is independently in each occurrence 1 or 2; with the proviso that the sum of p and q on each linked boron and nitrogen pair is 2 and the sum of the p and q is 1 or 2 wherein q is 2, the nitrogen atom is the cation counter-balancing the borate anion; w is independently in each occurrence either 0 or 1. 6. Amido-borates according to claim 1 which correspond to one of the formulas: R1 is independently in each occurrence an alkyl or cycloalkyl group, or two or more of R1 may combine to form a cycloaliphatic ring; R2 is independently in each occurrence an alkyl, cycloalkyl, aryl, alkaryl, or aralkyl group containing one or more heteroatoms or heteroatom containing functional moieties; R3 is independently in each occurrence hydrogen, an alkyl or an aryl group which may optionally contain one or more heteroatoms or heteroatom containing functional moieties; R4 is independently in each occurrence a divalent hydrocarbyl moiety which may optionally contain one or more heteroatoms or heteroatom containing functional moieties; R5 is independently in each occurrence a t-valent hydrocarbylene group optionally containing one or more heteroatoms or heteroatom containing functional moieties; X is independently in each occurrence a cation; t is independently in each occurrence 2 or greater; Y is independently in each occurrence Z is independently in each occurrence N, P, Si or C; p is independently in each occurrence 0 or 1; q is independently in each occurrence 1 or 2; with the proviso that the sum of p and q on each linked boron and nitrogen pair is 2; and w is independently in each occurrence either 0 or 1. 7. Compounds according to claim 6 wherein: R1 is independently in each occurrence a C1-10 alkyl, C3-10 cycloalkyl or two or more of R1 may combine to form a cycloaliphatic ring; R2 is independently in each occurrence C1-10 alkyl, C3-10 cycloalkyl, C6-12 aryl, C7-20 alkaryl or C7-20 aralkyl wherein such groups contain one or more heteroatoms of O or S, or an O or S containing functional moieties; R3 is independently in each occurrence hydrogen' C1-10 alkyl, C3-20 cycloalkyl, C6-20 aryl, C7-20 alkaryl, C7-20 aralkyl optionally containing one or more heteroatoms or heteroatom containing functional moieties; R5 is independently in each occurrence a t-valent alkylene group; X is independently in each occurrence is an onium or an alkali metal ion; Y is independently in each occurrence Z is independently in each occurrence is N or C; and t is 2or 3. 8. Compounds according to claim 7 wherein: R1 is independently each in occurrence C1-4 alkyl; R2 is independently in each occurrence C1-10 alkoxyalkyl; R3 is independently in each occurrence hydrogen, C1-4 alkyl or C1-10alkoxyalkyl; R4 is independently in each occurrence C2-20 alkylene or C2-20 alkylene containing one or more oxygen atoms; R5 is independently in each occurrence a t-valent, C2-6 alkylene moiety; X is an ammonium, phosphonium, sodium or lithium ion; and t is 2. 9. Compounds according to claim 8 wherein: R1 is independently in each occurrence C2-4 alkyl; R2 is independently in each occurrence methoxypropyl, ethoxypropyl or propoxypropyl; R3 is independently in each occurrence hydrogen, methyl, ethyl or propyl; R4 is independently in each occurrence C2-4 alkylene; R5 is a divalent C2-4 alkylene group, and X is tetraethyl ammonium, tetraethyl phosphonium, tetraphenyl phosphonium; sodium or lithium. 10. An amido-borate corresponding to the formula 11. An amido-borate corresponding to the formula
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