[특허]Method of restoring catalytic activity to a spent hydrotreating catalyst, the resulting restored catalyst, and a method of hydroprocessing

Shell Oil Company

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Method of restoring catalytic activity to a spent hydrotreating catalyst, the resulting restored catalyst, and a method of hydroprocessing

특허상세정보
국가/구분	United States(US) Patent 등록
국제특허분류(IPC7판)	B01J-038/50 B01J-038/62 B01J-038/12
미국특허분류(USC)	502/029; 502/028; 502/038
출원번호	UP-0038291 (2005-01-19)
등록번호	US-7820579 (2010-11-15)
발명자 / 주소	Ginestra, Josiane Marie-Rose Seamans, James Dallas Lee, Kenneth Scott
출원인 / 주소	Shell Oil Company
대리인 / 주소	Stewart, Charles W.
인용정보	피인용 횟수 : 20 인용 특허 : 5

초록
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A method of restoring catalytic activity to a spent hydroprocessing catalyst that has a first carbon concentration. The concentration of carbon on the spent hydroprocessing catalyst is reduced to provide a carbon-reduced catalyst having a second carbon concentration that is less than the first carbon concentration. The carbon-reduced catalyst is exposed to a solution, comprising a chelating agent and a solvent, for an aging time period sufficient to provide for a restored catalytic activity thereby resulting in an aged catalyst having incorporated therein the chelating agent and the solvent. The aged catalyst is exposed to conditions, including a drying temperature, so as to remove from the aged catalyst a portion of the solvent without removing a significant portion of the chelating agent from the aged catalyst thereby resulting in a dried aged catalyst. The dried aged catalyst is then sulfur treated to thereby provide a restored catalyst. The restored catalyst and those catalysts made by the treatment method can be used in a hydroprocessing process comprising contacting the restored catalyst with a hydrocarbon feedstock under hydroprocessing conditions.

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That which is claimed is: 1. A method of restoring the activity of a spent non-additive based hydroprocessing catalyst comprising a catalytically active metal component and a support, said method comprising: Contacting with a solution said spent non-additive based hydroprocessing catalyst having a reduced catalytic activity relative to a non-additive based hydroprocessing catalyst in its fresh state prior to use thereof to thereby become said spent non-additive based hydroprocessing catalyst, wherein said solution comprises a solvent and a chelating agent capable of forming a complex with said catalytically active metal component of said spent non-additive based hydroprocessing catalyst, and wherein said contacting is done for a time period from about 10 hours to about 900 hours during which time period said chelating agent reacts with and re-disperses said catalytically active metal component thereby resulting in an aged catalyst having incorporated therein said chelating agent and said solvent and a re-dispersed catalytically active metal component; Exposing said aged catalyst to conditions including a drying temperature less than 250° C. so as to remove from said aged catalyst a portion of said solvent without removing more than 50 weight percent of said chelating agent from said aged catalyst thereby resulting in a dried aged catalyst; and Sulfur treating said dried aged catalyst without prior exposure to a calcination temperature exceeding 400° C., to yield a restored hydroprocessing catalyst. 2. A method as recited in claim 1, wherein said solution and said spent non-additive based hydroprocessing catalyst are contacted for a time period of from 20 hours to 600 hours at a temperature between 5° C. and 90° C. 3. A method as recited in claim 2, wherein said chelating agent of said solution is a chelant that contains at least one nitrogen atom that is capable of serving as the electron donor atom for forming a complex with a metal of said spent hydroprocessing catalyst. 4. A method as recited in claim 3, wherein said chelating agent is selected from the group of compounds consisting of aminocarboxylic acids, polyamines, aminoalcohols, oximes, and polyethyleneimines. 5. A method as recited in claim 4, wherein the contacting of said spent non-additive based hydroprocessing catalyst with said solution is such as to incorporate into said spent non-additive based hydroprocessing catalyst an amount of said chelating agent in the range of from 0.005 moles chelating agent per mole of active metal to 1 mole of chelating agent per mole of active metal. 6. A method as recited in claim 5, wherein said time period for the contacting of said spent non-additive based hydroprocessing catalyst with said solution exceeds about 40 hours thereby providing said aged catalyst. 7. A method as recited in claim 6, the contacting of said spent non-additive based hydroprocessing catalyst with said solution is conducted at an aging temperature in the range of about the freezing temperature of said solution to about the boiling temperature of said solution. 8. A method as recited in claim 7, wherein the conditions to which said aged catalyst is exposed prior to the sulfur treating of said dried aged catalyst includes a maximum exposure temperature that is less than a calcination temperature of 300° C. 9. A method as recited in claim 8, wherein said maximum exposure temperature is said drying temperature that is less than 175° C. 10. A method as recited in claim 9, wherein said dried aged catalyst has a concentration of said chelating agent and the amount of said chelating agent removed from said aged catalyst is less than 25 weight percent of the chelating agent incorporated into said spent catalyst. 11. A method as recited in claim 10, wherein the amount of said chelating agent removed from said aged catalyst is less than 10 weight percent of the chelating agent incorporated into said spent non-additive based hydroprocessing catalyst. 12. A method of restoring catalytic activity to a spent non-additive based hydrotreating catalyst, said method comprises: providing said spent hydrotreating catalyst having a first carbon concentration; reducing the concentration of carbon on said spent hydrotreating catalyst to provide a carbon-reduced catalyst having a second carbon concentration that is less than said first carbon concentration; exposing said carbon-reduced catalyst to a solution comprising a chelating agent and a solvent for an aging time period from about 10 hours to about 900 hours during which time period said chelating agent reacts with and re-disperses catalytically active metals present in said spent non-additive based hydrotreating catalyst, thereby resulting in an aged catalyst having incorporated therein said chelating agent and said solvent and re-dispersed catalytically active metals; exposing said aged catalyst to conditions including a drying temperature of from 90° C. to 200° C. so as to remove from said aged catalyst a portion of said solvent without removing a significant portion of said chelating agent from said aged catalyst thereby resulting in a dried aged catalyst; and Sulfur treating said dried aged catalyst without prior exposure to a calcination temperature exceeding 400° C., to yield a restored catalyst. 13. A method as recited in claim 12, wherein said first carbon concentration exceed 3 weight percent, with the weight percent being based on the total weight of said spent hydrotreating catalyst. 14. A method as recited in claim 13, wherein said second carbon concentration is less than 3 weight percent, with the weight percent being based on the total weight of said carbon-reduced catalyst. 15. A method as recited in claim 14, wherein said chelating agent of said solution is a chelant that contains at least one nitrogen atom that is capable of serving as the electron donor atom for forming a complex with a metal of said spent hydroprocessing catalyst. 16. A method as recited in claim 15, wherein said chelating agent is selected from the group of compounds consisting of aminocarboxylic acids, polyamines, aminoalcohols, oximes, and polyethyleneimines. 17. A method as recited in claim 16, wherein the exposing of said carbon-reduced catalyst with said solution is such as to incorporate into said carbon-reduced catalyst an amount of said chelating agent in the range of from 0.005 moles chelating agent per mole of active metal to 1 mole of chelating agent per mole of active metal. 18. A method as recited in claim 17, wherein said aging time period for exposing said carbon-reduced catalyst with said solution exceeds about 20 hours thereby providing said agent catalyst. 19. A method as recited in claim 18, the exposing of said carbon-reduced catalyst with said solution is conducted at an aging temperature in the range of from about 0° C. to about 100° C. 20. A method as recited in claim 19, wherein the condition to which said aged catalyst is exposed prior to sulfur treating said dried aged catalyst includes a maximum exposure temperature that is less than a calcination temperature of 300° C. 21. A method as recited in claim 20, wherein said maximum exposure temperature is said drying temperature that is less than 175° C. 22. A method as recited in claim 21, wherein said dried aged catalyst has a concentration of said chelating agent and said significant portion of said chelating agent removed from said aged catalyst is less than 50 weight percent of the chelating agent incorporated into said carbon-reduced catalyst. 23. A method as recited in claim 22, wherein said significant portion of said chelating agent removed from said aged catalyst is less than 25 weight percent of the chelating agent incorporated into said carbon-reduced catalyst. 24. A method, comprising: providing a spent non-additive based hydrotreating catalyst further containing carbon; removing a portion of said carbon from said spent hydrotreating catalyst to thereby provide a carbon-reduced catalyst; incorporating a chelating agent into said carbon-reduced catalyst by exposing said carbon-reduced catalyst to a solution comprising said chelating agent and a solvent; aging the resulting chelant-incorporated carbon-reduced catalyst for an aging time period from about 20 hours to about 600 hours during which time period said chelating agent reacts with and re-disperses catalytically active metals present in said spent non-additive based hydrotreating catalyst, to thereby provide an aged catalyst; drying said aged catalyst at a drying temperature so as to remove from said aged catalyst a portion of said solvent without removing a significant portion of said chelating agent from said aged catalyst thereby resulting in a dried aged catalyst; and Sulfur treating said dried aged catalyst without prior exposure to a calcination temperature exceeding 400° C., to yield a restored catalyst. 25. A method as recited in claim 24, wherein said chelating agent of said solution is a chelant that contains at least one nitrogen atom that is capable of serving as the electron donor atom for forming a complex with a metal of said spent hydroprocessing catalyst. 26. A method as recited in claim 25, wherein said chelating agent is selected from the group of compounds consisting of aminocarboxylic acids, polyamines, aminoalcohols, oximes, and polyethyleneimines. 27. A method as recited in claim 26, wherein the amount of said chelating agent incorporated into said carbon-reduced catalyst is in the range of from 0.005 moles chelating agent per mole of active metal to 1 mole of chelating agent per mole of active metal. 28. A method as recited in claim 27, wherein said aging time period for exposing said carbon-reduced catalyst with said solution exceeds about 40 hours thereby providing said aged catalyst. 29. A method as recited in claim 28, the exposing of said carbon-reduced catalyst with said solution is conducted at an aging temperature in the range of from about 0° C. to about 100° C. 30. A method as recited in claim 29, wherein said drying temperatures to which said aged catalyst is exposed prior to sulfur treating said dried aged catalyst includes a maximum exposure temperature that is less than a calcination temperature of 300° C. 31. A method as recited in claim 30, wherein said maximum exposure temperature is said drying temperature that is less than 250° C. 32. A method as recited in claim 31, wherein said dried aged catalyst has a concentration of said chelating agent and said significant portion of said chelating agent removed from said aged catalyst is less than 50 weight percent of the chelating agent incorporated into said carbon-reduced catalyst. 33. A method as recited in claim 32, wherein said significant portion of said chelating agent removed from said aged catalyst is less than 25 weight percent of the chelating agent incorporated into said carbon-reduced catalyst. 34. A method as recited in claim 33, wherein said aging time period for exposing said carbon-reduced catalyst with said solution is from 40 to 400 hours at a temperature of from 10° C. to 60° C.; said drying temperature for drying said aged catalyst is 100° C. to 175° C.; the amount of chelating agent removed from said aged catalyst is less than 10 weight percent of the chelating agent incorporated into said carbon-reduced catalyst; and the said restored hydroprocessing catalyst has a relative volumetric activity (RVA) exceeding the relative volumetric activity of said spent non-additive based hydroprocessing catalyst in its fresh state prior to use.

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Method of restoring catalytic activity to a spent hydrotreating catalyst, the resulting restored catalyst, and a method of hydroprocessing

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