Simplified article for carbon monoxide removal
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-008/04
C01B-003/50
출원번호
UP-0425922
(2006-06-22)
등록번호
US-7837953
(2011-01-22)
발명자
/ 주소
Shore, Lawrence
출원인 / 주소
BASF Corporation
대리인 / 주소
Lau, Bernard
인용정보
피인용 횟수 :
6인용 특허 :
5
초록▼
Provided are improved carbon monoxide removal articles and processes for treating hydrogen gas streams to achieve very low threshold levels of carbon monoxide. The articles have a substrate with an inlet end, an outlet end, a length extending between the inlet end to the outlet end, wall elements an
Provided are improved carbon monoxide removal articles and processes for treating hydrogen gas streams to achieve very low threshold levels of carbon monoxide. The articles have a substrate with an inlet end, an outlet end, a length extending between the inlet end to the outlet end, wall elements and a plurality of cells defined by the wall elements. A first layer is deposited on the wall elements from the inlet end and extending at least partially toward the outlet end. The first layer has a preferential carbon monoxide oxidation catalyst. A second layer contains a methanation catalyst, and is deposited on at least part of the first layer from the outlet end. The second layer has a length that is about 10-70% of the substrate length.
대표청구항▼
What is claimed: 1. An article, comprising: a substrate comprising an inlet end, an outlet end, a length extending between the inlet end to the outlet end, wall elements and a plurality of cells defined by the wall elements; a first layer deposited on the wall elements from the inlet end and extend
What is claimed: 1. An article, comprising: a substrate comprising an inlet end, an outlet end, a length extending between the inlet end to the outlet end, wall elements and a plurality of cells defined by the wall elements; a first layer deposited on the wall elements from the inlet end and extending at least partially toward the outlet end, wherein the first layer comprises a preferential carbon monoxide oxidation catalyst, wherein the preferential carbon monoxide oxidation catalyst is a platinum-metal based catalyst, a palladium metal-based catalyst, or a mixture of thereof, the platinum-metal based catalyst consisting of about 1 to 5 wt. % of platinum, a support and an optional promoter, and the palladium metal-based catalyst consisting of about 1 to 5 wt. % of palladium, a support and an optional promoter; and a second layer deposited on at least part of the first layer from the outlet end and having a length that is about 10-70% of the wall elements' length beginning from the outlet end, the second layer comprises a methanation catalyst consisting of a ruthenium component and a support, wherein the first layer and the second layer are arranged to form three zones where a first zone extending from the inlet end has the first layer not overlaid by the second layer, a second zone downstream from the inlet end and upstream from the output end has the first layer overlaid by the second layer, and a third zone extending from the outlet end has the second layer not overlying the first layer, and the first layer extends from the inlet end and the second layer extends from the outlet end. 2. The article of claim 1, wherein the substrate is a honeycomb substrate having a plurality of parallel, axially enclosed cells. 3. The article of claim 1, wherein the substrate is an open-celled foam substrate. 4. The article of claim 1, wherein the second layer has a length of at least about 30% of the wall elements' length. 5. The article of claim 1, wherein the optional promoter comprises an iron component. 6. The article of claim 1, wherein the platinum-metal based catalyst consists of about 1 to 5 wt. % of platinum, and a support and about 0.1 to 0.5 wt. % of iron, and the palladium metal-based catalyst consists of about 1 to 5 wt. % palladium, a support and about 0.1 to 0.5 wt. % of iron. 7. The article of claim 1, wherein the platinum-metal based catalyst consists of about 5 wt. % of platinum, a support and about 0.1 to 0.5 wt. % of iron, and the palladium metal-based catalyst consists of about 5 wt. % of palladium, a support and about 0.1 to 0.5 wt. % of iron. 8. The article of claim 1, wherein the methanation catalyst consists of ruthenium and an alumina support. 9. The article of claim 1, wherein the methanation catalyst consists of about 1 to 10 wt. % of ruthenium and a support. 10. An article, comprising: a substrate comprising an inlet end, an outlet end, wall elements having a length extending between the inlet end to the outlet end, and a plurality of axially enclosed cells defined by the wall elements; a first layer deposited on the substrate from the inlet end and extending at least partially toward the outlet end, wherein the first layer comprises a platinum-based, iron-promoted catalyst consisting of platinum, iron and a support; and a second layer deposited on at least part of the first layer from the outlet end and having a length that is about 10-70% of the wall elements' length beginning from the outlet end, the second layer overlaying the first layer for a length of at least about 10% of the wall elements' length, wherein the second layer comprises a methanation catalyst consisting of a ruthenium component and an alumina support, wherein the first layer and the second layer are arranged to form three zones where a first zone extending from the inlet end has the first layer not overlaid by the second layer, a second zone downstream from the inlet end and upstream from the output end has the first layer overlaid by the second layer, and a third zone extending from the outlet end has the second layer not overlying the first layer, and the first layer extends from the inlet end and the second layer extends from the outlet end. 11. The article of claim 10, wherein the first layer has a length of at least about 80% of the wall elements' length. 12. The article of claim 10, wherein the second layer has a length of at least about 30% of the wall elements' length. 13. The article of claim 10, wherein the platinum-metal based, iron-promoted catalyst consists of about 1 to 5 wt. % of platinum, and about 0.1 to 0.5 wt. % of iron, and a support. 14. The article of claim 10, wherein the platinum-metal based, iron-promoted catalyst consists of about 5 wt. % of platinum, and about 0.1 to 0.5 wt. % of iron, and a support. 15. The article of claim 10, wherein the platinum-metal based, iron-promoted catalyst consists of about 5 wt. % of platinum, and about 0.3 wt. % of iron, and a support. 16. The article of claim 10, wherein the methanation catalyst consists of about 1 to 10 wt. % of ruthenium and an alumina support. 17. A process for removing carbon monoxide in a hydrogen stream, comprising contacting the hydrogen stream with the article of claim 1. 18. The process of claim 17, wherein the hydrogen stream is at a temperature of about 80 to 180° C.
연구과제 타임라인
LOADING...
LOADING...
LOADING...
LOADING...
LOADING...
이 특허에 인용된 특허 (5)
Atmur Steven Donald ; Strasser Thomas Edward, Ceramic catalytic converter.
Plog Carsten (Markdorf DEX) Maunz Werner (Markdorf DEX) Stengel Thomas (Friedrichshafen DEX) Andorf Renato (Meckenbeuren DEX), Reactor for the catalytic removal of CO in high-H2gas.
Chiffey, Andrew Francis; Collins, Neil Robert; Goodwin, John Benjamin; Moreau, Francois; Phillips, Paul Richard, Oxidation catalyst for a compression ignition engine.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.