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Conductive curable compositions contain a free radical polymerizable monomer, oligomer or polymer (i); an organoborane amine complex (ii), and an electrically or thermally conductive filler (iii). The conductive curable compositions can also contain an amine reactive compound having amine reactive g

Conductive curable compositions contain a free radical polymerizable monomer, oligomer or polymer (i); an organoborane amine complex (ii), and an electrically or thermally conductive filler (iii). The conductive curable compositions can also contain an amine reactive compound having amine reactive groups (iv); and (v) a component capable of generating a gas when mixed with a compound bearing active hydrogen and a catalyst. The electrically conductive curable compositions can be used in composite articles of manufacture in which substrates are coated or bonded together with the composition and cured; and as electrically conductive rubbers, electrically conductive tapes, electrically conductive adhesives, electrically conductive foams, and electrically conductive pressure sensitive adhesives. The thermally conductive compositions can also be used in composite articles of manufacture in which substrates are coated or bonded together with the composition and cured, and as thermal interface materials, thermally conductive rubbers, thermally conductive tapes, thermally conductive adhesives, thermally conductive foams, thermally conductive seals and gaskets, and thermally conductive pressure sensitive adhesives.

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What is claimed is: 1. A method for preparing a conductive curable composition comprising combining and mixing ingredients comprising: A. 1-50 parts by weight of a free radical polymerizable monomer, oligomer or polymer (i); B. 0.1-50 parts by weight of an organoborane amine complex (ii) sufficient

What is claimed is: 1. A method for preparing a conductive curable composition comprising combining and mixing ingredients comprising: A. 1-50 parts by weight of a free radical polymerizable monomer, oligomer or polymer (i); B. 0.1-50 parts by weight of an organoborane amine complex (ii) sufficient to cure the composition, the amount depending on the molecular weight of the complex and the number of boron atoms per molecule; either C. 0.5-80 percent by volume of an electrically conductive filler (iii) based on the total volume of the conductive curable composition sufficient to impart electrical conductivity to the curable composition; or C. 25-96 percent by weight of a thermally conductive filler (iii) based on the total weight of the conductive curable composition sufficient to impart thermal conductivity to the curable composition; D. greater than 0 to 50 parts by weight of an amine reactive compound having amine reactive groups (iv) sufficient to decomplex boron depending on the molecular weight of the compound; E. 0 to 50 parts by weight of a component capable of generating gas (v) when mixed with a compound bearing active hydrogen and a catalyst; and F. 0 to 50 parts by weight of any optional ingredient(s); based on the total weight of the conductive curable composition; wherein the amine reactive compound (iv) is present; and the electrically or thermally conductive filler (iii) is treated with the amine reactive compound (iv). 2. A method according to claim 1 wherein the free radical polymerizable monomer, oligomer, or polymer (i) is an organic compound (a), an organosilicon monomer, oligomer, or polymer (b), or (c) a mixture of difunctional organopolysiloxanes and hexafunctional organopolysiloxanes, in which (a), (b), and (c) are unsaturated and capable of undergoing free radical polymerization. 3. A method according to claim 1 wherein the organoborane amine complex (ii) is a complex formed between an organoborane and an amine compound, the organoborane having the formula B—R″3 where R″ is a linear, branched, aliphatic, or aromatic hydrocarbon group containing 1-20 carbon atoms; and wherein the amine compound is an organic amine compound or a silicon containing amine compound. 4. A method according to claim 1 wherein the electrically conductive filler (iii) comprises a metal particle, a conductive non-metal particle, a metal particle having an outer surface of a metal, or a conductive non-metal particle having an outer surface of a metal; wherein the outer surface metal is selected from the group consisting of silver, gold, platinum, palladium, nickel, aluminum, copper, and steel; wherein the particles have an average particle size of 0.005-20 μm; and wherein the particles having an outer surface of a metal have an average particle size of 15-100 μm. 5. A method according to claim 4 wherein the particles having an outer surface of a metal have a core of particles selected from the group consisting of copper, solid glass, hollow glass, mica, nickel, ceramic fiber, polystyrene, and polymethylmethacrylate. 6. A method according to claim 1 wherein the thermally conductive filler (iii) comprises a metal particle, a metal oxide particle, a thermally conductive non-metal powder, or a combination thereof. 7. A method according to claim 6 wherein the thermally conductive filler (iii) is selected from the group consisting of aluminum, copper, gold, nickel, silver, alumina, magnesium oxide, beryllium oxide, chromium oxide, titanium oxide, zinc oxide, barium titanate, diamond, graphite, carbon nanoparticles, silicon nanoparticles, boron nitride, aluminum nitride, boron carbide, titanium carbide, silicon carbide, tungsten carbide, and combinations thereof. 8. A method according to claim 1 wherein the amine reactive compound (iv) is a compound having amine reactive groups and is selected from the group consisting of mineral acids, Lewis acids, carboxylic acids, carboxylic acid derivatives, carboxylic acid metal salts, isocyanates, aldehydes, epoxides, acid chlorides, and sulphonyl chlorides. 9. A method according to claim 8 wherein the amine reactive groups are borne by an organic molecule, an organosilane, an organopolysiloxane, an organotitanate, or an organozirconate. 10. A method according to claim 8 wherein the amine reactive compound (iv) is attached to solid particles selected from the group consisting of ground silica, precipitated silica, calcium carbonate, carbon black, carbon nanoparticles, silicon nanoparticles, barium sulfate, titanium dioxide, aluminum oxide, boron nitride, silver, gold, platinum, palladium, nickel, aluminum, copper, and steel. 11. A method according to claim 1 further comprising a component capable of generating a gas (v) when mixed with a compound bearing active hydrogen and a catalyst, the component (v) being a silicon hydride functional compound; the compound bearing active hydrogen being water, an alcohol, or a carboxylic acid; and the catalyst being platinum, a platinum group metal, tin, titanium, or zirconium. 12. A method according to claim 1 wherein the organoborane amine complex (ii) is packaged separately from the amine reactive compound (iv). 13. A method according to claim 1 wherein the electrically or thermally conductive filler (iii) treated with the amine reactive compound (iv) is packaged together in one part that is separate from the organoborane amine complex (ii). 14. A method according to claim 1 wherein the free radical polymerizable monomer, oligomer or polymer (i), the organoborane amine complex (ii), the electrically or thermally conductive filler (iii), and the amine reactive compound (iv) are packaged together in one part in a substantially oxygen free environment. 15. A method according to claim 1 wherein the free radical polymerizable monomer, oligomer or polymer (i), the organoborane amine complex (ii), and the electrically or thermally conductive filler (iii) are packaged together in one part. 16. An electrically conductive rubber, electrically conductive tape, electrically conductive adhesive, electrically conductive foam, or electrically conductive pressure sensitive adhesive, comprising as a component thereof, the cured product prepared by the method according to claim 1. 17. An electrically conductive rubber, electrically conductive tape, electrically conductive adhesive, electrically conductive foam, or electrically conductive pressure sensitive adhesive, according to claim 16 wherein the rubber, tape, adhesive or pressure sensitive adhesive are an electrically conductive silicone rubber, an electrically conductive silicone tape, an electrically conductive silicone adhesive, an electrically conductive silicone foam, or an electrically conductive silicone pressure sensitive adhesive. 18. A thermal interface material, thermally conductive rubber, thermally conductive tape, thermally conductive curable adhesive, thermally conductive foam, or thermally conductive pressure sensitive adhesive, comprising as a component thereof, the cured product prepared by the method according to claim 1. 19. A thermal interface material, thermally conductive rubber, thermally conductive tape, thermally conductive curable adhesive, thermally conductive foam, or thermally conductive pressure sensitive adhesive, according to claim 18, wherein the rubber, tape, adhesive or pressure sensitive adhesive are a silicone thermal interface material, a thermally conductive silicone rubber, a thermally conductive silicone tape, a thermally conductive silicone adhesive, a thermally conductive silicone foam, or a thermally conductive silicone pressure sensitive adhesive. 20. A composite article of manufacture comprising a substrate coated with a composition prepared by a method comprising: combining and mixing ingredients comprising: A. 1-50 parts by weight of a free radical polymerizable monomer, oligomer or polymer (i); B. 0.1-50 parts by weight of an organoborane amine complex (ii) sufficient to cure the composition, the amount depending on the molecular weight of the complex and the number of boron atoms per molecule; either C. 0.5-80 percent by volume of an electrically conductive filler (iii) based on the total volume of the conductive curable composition sufficient to impart electrical conductivity to the curable composition; or C. 25-96 percent by weight of a thermally conductive filler (iii) based on the total weight of the conductive curable composition sufficient to impart thermal conductivity to the curable composition; D. great than 0 to 50 parts by weight of an amine reactive compound having amine reactive groups (iv) sufficient to decomplex boron depending on the molecular weight of the compound; E. 0 to 50 parts by weight of a component capable of generating gas (v) when mixed with a compound bearing active hydrogen and a catalyst; and F. 0 to 50 parts by weight of any optional ingredient(s); based on the total weight of the conductive curable composition, wherein the amine reactive compound (iv) is present; and the electrically or thermally conductive filler (iii) is treated with the amine reactive compound (iv). 21. A composite article of manufacture according to claim 20 wherein the composition on the substrate is cured. 22. A composite article of manufacture comprising two or more substrates coated with a composition, and the composition is disposed between the substrates as a bond line of a fixed or a varying thickness, with the proviso that the composition is prepared by a method comprising: combining and mixing ingredients comprising: A. 1-50 parts by weight of a free radical polymerizable monomer, oligomer or polymer (i); B. 0.1-50 parts by weight of an organoborane amine complex (ii) sufficient to cure the composition, the amount depending on the molecular weight of the complex and the number of boron atoms per molecule; either C. 0.5-80 percent by volume of an electrically conductive filler (iii) based on the total volume of the conductive curable composition sufficient to impart electrical conductivity to the curable composition; or C. 25-96 percent by weight of a thermally conductive filler (iii) based on the total weight of the conductive curable composition sufficient to impart thermal conductivity to the curable composition; D. great than 0 to 50 parts by weight of an amine reactive compound having amine reactive groups (iv) sufficient to decomplex boron depending on the molecular weight of the compound; E. 0 to 50 parts by weight of a component capable of generating gas (v) when mixed with a compound bearing active hydrogen and a catalyst; and F. 0 to 50 parts by weight of any optional ingredient(s); based on the total weight of the conductive curable composition; wherein the amine reactive compound (iv) is present; and the electrically or thermally conductive filler (iii) is treated with the amine reactive compound (iv). 23. A composite article of manufacture according to claim 22 wherein the composition disposed between the substrates is cured.