Bimetallic catalyst for the treatment of water containing nitrates
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C02F-001/70
A62D-003/37
B01J-023/00
B01J-021/00
B01J-020/00
출원번호
UP-0195401
(2008-08-20)
등록번호
US-7857981
(2011-02-24)
우선권정보
ES-200101471(2001-06-15)
발명자
/ 주소
Corma Canós, Avelino
Palomares Gimeno, Antonio Eduardo
Prato Moreno, Jose Gregorio
출원인 / 주소
Consejo Superior de Investigaciones Cientificas
Universidad Politecnica de Valencia
대리인 / 주소
Klauber & Jackson, LLC
인용정보
피인용 횟수 :
1인용 특허 :
13
초록▼
A catalyst which, by means of a reduction reaction at ambient temperature, permits the elimination of nitrates and nitrites in waters. The catalyst comprises a combination of a noble metal and a non-noble metal supported on or incorporated into the structure of a support which, in elemental and anhy
A catalyst which, by means of a reduction reaction at ambient temperature, permits the elimination of nitrates and nitrites in waters. The catalyst comprises a combination of a noble metal and a non-noble metal supported on or incorporated into the structure of a support which, in elemental and anhydrous form, has the formula XYMgAl, in which X is at least one noble metal, Y is at least one non-noble metal, Mg is magnesium and Al is aluminum, the Mg and Al preferably forming the structure of a hydrotalcite or a mixed oxide deriving from a hydrotalcite.
대표청구항▼
The invention claimed is: 1. A process for treating waters to eliminate nitrates present in liquid phase therein, said process comprising (a) treating said waters with a bimetallic catalyst said bimetallic catalyst in elemental and anhydrous form, having a composition corresponding to the formula X
The invention claimed is: 1. A process for treating waters to eliminate nitrates present in liquid phase therein, said process comprising (a) treating said waters with a bimetallic catalyst said bimetallic catalyst in elemental and anhydrous form, having a composition corresponding to the formula XYMgAl wherein: X is at least one noble metal; Y is at least one non-noble metal; Mg is magnesium; and Al is aluminum, and (b) reducing the nitrates to nitrogen by adding a reducing agent. 2. A process in accordance with claim 1, wherein the reducing agent is selected from the group consisting of hydrogen, formic acid, hydrocarbons and combinations thereof. 3. A process in accordance with claim 1, wherein Mg and Al form a hydrotalcite structure. 4. A process in accordance with claim 1, wherein the noble metal is selected from the group consisting of Pd, Pt, Ru, Ir and Rh. 5. A process in accordance with claim 1, wherein the noble metal is present in a proportion of 0.1 to 30% by weight, preferably from 0.5 to 15% by weight, based on the total weight of the catalyst. 6. A process in accordance with claim 1, wherein the noble metal is Pd. 7. A process in accordance with claim 1, wherein the non-noble metal is selected from the group consisting of Cu, Sn, Zn, In, Ni, Ag, Fe and Co. 8. A process in accordance with claim 1, wherein the non-noble metal is present in a proportion 0.5 to 10% by weight, based on the total weight of the catalyst. 9. A process in accordance with claim 1, wherein the non-noble metal is Cu.
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이 특허에 인용된 특허 (13)
Bonse Dirk (Lehrte DEX) Bretz Karl-Heinz (Nienburg DEX) Derleth Helmut (Nienburg DEX) Sell Michael (Peine DEX) Bischoff Michael (Braunschweig DEX), Abrasion-resistant carrier catalyst.
Bhattacharyya Alakananda (Wheaton IL) Kleefisch Mark S. (Naperville IL) Udovich Carl A. (Joliet IL), Catalyzed vapor phase process for making synthesis gas.
Bhattacharyya Alakananda (Wheaton IL) Kleefisch Mark S. (Naperville IL) Udovich Carl A. (Joliet IL), Catalyzed vapor phase process for making synthesis gas.
Baird ; Jr. William C. ; McVicker Gary B. ; Schorfheide James J. ; Klein Darryl P. ; Hantzer Sylvain ; Daage Michel ; Touvelle Michele S. ; Ellis Edward S. ; Vaughan David E.W. ; Chen Jingguang G., Desulfurization process for refractory organosulfur heterocycles.
Van Berge, Peter Jacobus; Van De Loosdrecht, Jan; Caricato, Elsie Adriana; Barradas, Sean, Process for producing hydrocarbons from a synthesis gas, and catalysts therefor.
Vorlop Klaus-Dieter (Brunswick DEX) Tacke Thomas (Brunswick DEX) Sell Michael (Peine DEX) Strauss Gnther (Hanover DEX), Process for removing the nitrite and/or nitrate content in water.
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