초록 ▼

A catalyst for synthesizing acrylonitrile that enables acrylonitrile to be synthesized at high yield, and a process for producing acrylonitrile using that catalyst, are provided. A catalyst for synthesizing acrylonitrile is used having a composition represented by FeaSbbCcDdTeeFfXxYyZzOg(SiO2)h. In

A catalyst for synthesizing acrylonitrile that enables acrylonitrile to be synthesized at high yield, and a process for producing acrylonitrile using that catalyst, are provided. A catalyst for synthesizing acrylonitrile is used having a composition represented by FeaSbbCcDdTeeFfXxYyZzOg(SiO2)h. In the formula, component C represents at least one element selected from the group consisting of Cu, Ni and Co, component D from the group consisting of Mo, W and V, component F from the group consisting of P and B, component X from the group consisting of Sn, Ti, Zr, Nb, Ta, Cr, Ru, Pd, Ag, Al, Ga, In, Tl, Ge, As, Bi, La, Ce, Pr, Nd and Sm, component Y from the group consisting of Mg, Ca, Sr, Ba, Mn, Zn and Pb, and component Z from the group consisting of Li, Na, K, Rb and Cs, and SiO2 represents silica, when a=10, b=5 to 60, c=0.1 to 8.0, d=0.1 to 4.0, e=0.1 to 5.0, f=1.3 to 5.0, x=0 to 5, y=0 to 5, z=0 to 2, h=10 to 200 and g is the atomic ratio of oxygen required to satisfy the valence of each of the elements excluding silicon, and f/d=1 to 5.

대표청구항 ▼

The invention claimed is: 1. A catalyst for synthesizing acrylonitrile having the composition represented by the following general formula:FeaSbbCcDdTeeFfXxYyZzOg(SiO2)h (wherein, Fe represents iron, Sb represents antimony, Te represents tellurium, component C represents at least one element selecte

The invention claimed is: 1. A catalyst for synthesizing acrylonitrile having the composition represented by the following general formula:FeaSbbCcDdTeeFfXxYyZzOg(SiO2)h (wherein, Fe represents iron, Sb represents antimony, Te represents tellurium, component C represents at least one element selected from the group consisting of copper, nickel and cobalt, component D represents at least one element selected from the group consisting of molybdenum, tungsten and vanadium, component F represents at least one element selected from the group consisting of phosphorous and boron, component X represents at least one element selected from the group consisting of tin, titanium, zirconium, niobium, tantalum, chromium, ruthenium, palladium, silver, aluminum, gallium, indium, thallium, germanium, arsenic, bismuth, lanthanum, cerium, praseodymium, neodymium and samarium, component Y represents at least one element selected from the group consisting of magnesium, calcium, strontium, barium, manganese, zinc and lead, component Z represents at least one element selected from the group consisting of lithium, sodium, potassium, rubidium and cesium, O represents oxygen, SiO2 represents silica, a, b, c, d, e, f, x, y, z, g and h represent the atomic ratio of each element (silicon in the case of silica), when a=10, b=5 to 60, c=0.1 to 8.0, d=0.1 to 4.0, e=0.1 to 5.0, f=1.3 to 5.0, x=0 to 5, y=0 to 5, z=0 to 2, h=10 to 200 and g is the atomic ratio of oxygen required to satisfy the valence of each of the elements excluding silicon, and f/d=1 to 5).