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An igniter composition is provided including metal fuel particles having a predetermined average diameter and metallic oxide oxidizer particles having a predetermined average diameter. The metal fuel particles are mixed substantially homogeneously with the metallic oxide oxidizer particles and, upon

An igniter composition is provided including metal fuel particles having a predetermined average diameter and metallic oxide oxidizer particles having a predetermined average diameter. The metal fuel particles are mixed substantially homogeneously with the metallic oxide oxidizer particles and, upon initiation of the igniter composition, actively participate in an exothermic reaction with the metallic oxide oxidizer particles. Also provided are methods and devices containing the igniter composition.

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1. An igniter composition, comprising: metal fuel particles including an average diameter in a range of about 30 nm to about 200 nm; andmetallic oxide oxidizer particles including an average diameter less than about 400 nm, the metal fuel particles are mixed substantially homogeneously with the meta

1. An igniter composition, comprising: metal fuel particles including an average diameter in a range of about 30 nm to about 200 nm; andmetallic oxide oxidizer particles including an average diameter less than about 400 nm, the metal fuel particles are mixed substantially homogeneously with the metallic oxide oxidizer particles and, upon initiation of the igniter composition, which it substantially free of perchlorates, the metal fuel particles actively participate in an exothermic reaction with the metallic oxide oxidizer particles. 2. The igniter composition of claim 1, wherein the metal fuel particles are selected from at least one of aluminum, boron, hafnium, tantalum, zirconium, and alloys thereof. 3. The igniter composition of claim 1, wherein the metal fuel particles are comprised of aluminum. 4. The igniter composition of claim 1, wherein the average diameter of the metal fuel particles is in a predetermined range of about 50 nm to about 80 nm. 5. The igniter composition of claim 1, wherein the metallic oxide oxidizer particles are selected from at least one of bismuth oxide, molybdenum oxide, titanium oxide, iron oxide, tungsten oxide, copper oxide, zinc oxide and alloys thereof. 6. The igniter composition of claim 1, wherein the metallic oxide oxidizer particles is comprised of bismuth oxide. 7. The igniter composition of claim 1, wherein the metal fuel particles are comprised of aluminum, and wherein the metallic oxide oxidizer particles are comprised of bismuth oxide. 8. The igniter composition of claim 1, wherein the metal fuel particles are about 15 to about 85 weight percent of the igniter composition, and wherein the metallic oxide oxidizer particles are about 85 to about 15 weight percent of the igniter composition. 9. The igniter composition of claim 1, further comprising a binder. 10. The igniter composition of claim 1, wherein the igniter composition is free of perchlorates.