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A method for producing a hydrogen enriched fuel and carbon nanotubes includes the steps of providing a flow of methane gas, and providing a catalyst mixture comprising a Fe based catalyst and carbon. The method also includes the steps of pretreating the catalyst mixture using microwave irradiation a

A method for producing a hydrogen enriched fuel and carbon nanotubes includes the steps of providing a flow of methane gas, and providing a catalyst mixture comprising a Fe based catalyst and carbon. The method also includes the steps of pretreating the catalyst mixture using microwave irradiation and exposure to CH4, heating the catalyst mixture and the methane gas using microwave irradiation at a selected microwave power, directing the flow of methane gas over the catalyst mixture, and controlling the microwave power to produce a product gas having a selected composition and the carbon nanotubes. For producing multi walled carbon nanotubes (MWNTs) only a flow of methane gas into the reactor is required. For producing single walled carbon nanotubes (SWNTs), a combination of hydrogen gas and methane gas into the reactor is required.

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1. A method for producing a hydrogen enriched fuel and carbon nanotubes comprising: providing a reactor having a microwave transparent wall;providing a flow of methane gas into the reactor;preparing Fe based catalyst particles from a catalyst precursor by coprecipitation of an aqueous solution;mixin

1. A method for producing a hydrogen enriched fuel and carbon nanotubes comprising: providing a reactor having a microwave transparent wall;providing a flow of methane gas into the reactor;preparing Fe based catalyst particles from a catalyst precursor by coprecipitation of an aqueous solution;mixing the catalyst particles with carbon to form a catalyst mixture;placing the catalyst mixture in the reactor on a microwave transparent holder configured to allow the flow of methane gas to pass through the holder and around the catalyst mixture;pretreating the catalyst mixture in the reactor using microwave irradiation at a first microwave power directed through the wall of the reactor and the holder and the flow of methane gas through the holder;heating the catalyst mixture in the reactor at a pressure of about 1 atmosphere using microwave irradiation at a second microwave power less than the first microwave power directed through the wall of the reactor and the holder;directing the flow of methane gas through the holder and around the catalyst mixture; andcontrolling the second microwave power to produce the carbon nanotubes and a product gas comprising from about 15% to 20% hydrogen by volume, and from about 80% to 85% methane by volume. 2. The method of claim 1 wherein the first microwave power is between 300-1000W and the second microwave power is between 220-650 W. 3. The method of claim 1 further comprising providing a flow of hydrogen gas in combination with the flow of methane gas, and wherein the carbon nanotubes comprise single walled carbon nanotubes (SWNTs). 4. The method of claim 1 wherein the providing the flow of methane gas step is performed at about room temperature, and the heating step is performed at a temperature of from about 750-900° C. 5. The method of claim 1 wherein the catalyst particles have a diameter of from 74 μm to 140 μm and comprise a compound selected from the group consisting of FeAl; Fe3Al, Fe2CuAl, Fe2NiAl, and Fe2O3/MgO. 6. A method for producing a hydrogen enriched fuel and carbon nanotubes comprising: providing a reactor having a microwave transparent wall;providing a flow of methane gas and a flow of hydrogen gas into the reactor;preparing Fe based catalyst particles from a catalyst precursor by coprecipitation of an aqueous solution;mixing the catalyst particles with carbon to form a catalyst mixture;placing the catalyst mixture in the reactor on a microwave transparent holder configured to allow the flow of methane gas and the flow of hydrogen gas to pass through the wall of the reactor and the holder and around the catalyst mixture;pretreating the catalyst mixture using microwave irradiation at a first microwave power directed through the wall of the reactor and the reactor and the flow of methane gas directed through the holder;heating the catalyst mixture in the reactor using microwave irradiation at a pressure of about 1 atmosphere and a second microwave power less than the first microwave power directed through the wall of the reactor and the holder;directing the flow of methane gas and the flow of hydrogen gas through the holder and around the catalyst mixture; andcontrolling the second microwave power to produce a product gas comprising from about 15% to 20% hydrogen en by volume, and from about 80% to 85% methane by volume, and single walled carbon nanotubes (SWNTs). 7. The method of claim 6 wherein the flow of methane gas and the flow of hydrogen gas are provided in a ratio of about one to one. 8. The method of claim 6 wherein the catalyst particles have a diameter of from 74 μm to 140 μm and comprise a compound selected from the group consisting of FeAl; Fe3Al, Fe2CuAl, Fe2NiAl, and Fe2O3/MgO. 9. The method of claim 6 wherein the first microwave power is between 300-1000 W and the second microwave power is between 220-650 W. 10. The method of claim 6 wherein the pretreating step is performed at the first microwave power for at least a minute followed by reduction to the second microwave power. 11. The method of claim 6 wherein the heating step is performed at a temperature of from about 750-900° C. 12. A method for producing a hydrogen enriched fuel and carbon nanotubes comprising: providing a reactor having a microwave transparent wall;providing a flow of methane gas into the reactor;preparing catalyst particles from a catalyst precursor by coprecipitation of an aqueous solution, the catalyst particles comprising a compound selected from the group consisting of FeAl; Fe3Al, Fe2CuAl, Fe2NiAl, and Fe2O3/MgO;mixing the catalyst particles with carbon to form a catalyst mixture;placing the catalyst mixture in the reactor on a microwave transparent holder configured to allow the flow of methane gas to pass through the wall of the reactor and the holder and around the catalyst mixture;pretreating the catalyst mixture in the reactor using microwave irradiation at a first microwave power directed through the wall of the reactor and the holder and the flow of methane gas directed through the holder;heating the catalyst mixture in the reactor at a temperature between from about 750-900° C. and a pressure of about 1 atmosphere using microwave irradiation at a second microwave power less than the first microwave power directed through the wall of the reactor and the holder;directing the flow of methane gas through the holder and around the catalyst mixture; andcontrolling the second microwave power to produce a product gas comprising the carbon nanotubes, hydrogen of from about 15% to 20% by volume, and methane of from about 80% to 85% by volume. 13. The method of claim 12 wherein the first microwave power is about 500 W and the second microwave power is from about 325-365 W. 14. The method of claim 12 further comprising providing a flow of hydrogen gas in combination with the flow of methane gas, and wherein the carbon nanotubes comprise single walled carbon nanotubes (SWNTs). 15. The method of claim 12 wherein the providing the flow of methane gas step is performed at about room temperature and at about 1 atmosphere.