IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0416419
(2009-04-01)
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등록번호 |
US-8115047
(2012-02-14)
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발명자
/ 주소 |
- Foster, George G.
- Kesler, Frederick P.
- Draper, Malcolm
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출원인 / 주소 |
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대리인 / 주소 |
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인용정보 |
피인용 횟수 :
3 인용 특허 :
95 |
초록
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An improved oxidization process may be used to oxidize a wide variety of feedstocks. Oxidation takes place in a reactor where the feedstock is mixed with an oxidizing acid, such as nitric acid. The reaction mixture may also include a secondary oxidizing acid such as sulfuric acid as well as water an
An improved oxidization process may be used to oxidize a wide variety of feedstocks. Oxidation takes place in a reactor where the feedstock is mixed with an oxidizing acid, such as nitric acid. The reaction mixture may also include a secondary oxidizing acid such as sulfuric acid as well as water and/or dissolved and mechanically mixed oxygen gas. The reactor may be maintained at an elevated pressure such as at least approximately 2070 kPa or desirably at least approximately 2800 kPa. The temperature of the reaction mixture may be maintained at no more than 210° C. In the various embodiments described herein, the process may include: combining recycled effluent from the reactor with the feedstock, combining one or more oxidizing acids with the feedstock, comminuting the feedstock to reduce the size of the particles, feeding the feedstock into the high pressure reactor at an approximately constant feed rate, dispersing oxygen gas from the headspace of the reactor into the reaction mixture, and/or removing all or almost all of the gas from the reactor through the liquid effluent.
대표청구항
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1. A method comprising: comminuting an initial feedstock to form a primary feedstock that includes particles where the largest dimension of at least approximately 95% of the particles in the primary feedstock is no more than 7 mm; andoxidizing the primary feedstock in a reactor, the primary feedstoc
1. A method comprising: comminuting an initial feedstock to form a primary feedstock that includes particles where the largest dimension of at least approximately 95% of the particles in the primary feedstock is no more than 7 mm; andoxidizing the primary feedstock in a reactor, the primary feedstock being part of a reaction mixture that also includes nitric acid and a secondary oxidizing acid;wherein the reaction mixture, excluding solids, includes no more than 5 wt % of the secondary oxidizing acid. 2. The method of claim 1 comprising feeding the primary feedstock into the reactor at a feed rate that is approximately constant. 3. The method of claim 1 comprising combining an oxidizing acid with the initial feedstock and/or the primary feedstock before the primary feedstock enters the reactor. 4. The method of claim 1 comprising combining effluent from the reactor with the initial feedstock and/or the primary feedstock before the primary feedstock enters the reactor. 5. The method of claim 1 wherein the initial feedstock includes effluent from the reactor. 6. The method of claim 1 wherein the largest dimension of at least approximately 95% of the particles in the primary feedstock is no more than 4 mm. 7. The method of claim 1 wherein the largest dimension of at least approximately 95% of the particles in the primary feedstock is no more than 2.5 mm. 8. The method of claim 1 wherein the largest dimension of at least approximately 95% of the particles in the primary feedstock is no more than 1.5 mm. 9. The method of claim 1 wherein the largest dimension of at least approximately 95% of the particles in the primary feedstock is no more than 0.5 mm. 10. A method comprising: oxidizing a feedstock in a reactor, the feedstock being part of a reaction mixture that also includes nitric acid and a secondary oxidizing acid;wherein the reaction mixture, excluding solids, includes no more than 5 wt % of the secondary oxidizing acid. 11. The method of claim 10 comprising combining nitric acid with the feedstock before the feedstock enters the reactor. 12. The method of claim 10 comprising combining effluent from the reactor with the feedstock before the feedstock enters the reactor. 13. The method of claim 10 wherein the feedstock includes effluent from the reactor. 14. The method of claim 10 comprising maintaining the reaction mixture at a temperature that is no more than approximately 210° C. 15. The method of claim 10 wherein the feedstock is a primary feedstock, the method comprising comminuting an initial feedstock to form the primary feedstock, wherein the largest dimension of at least approximately 95% of the particles in the primary feedstock is no more than 7 mm. 16. A method comprising: oxidizing a feedstock in a reactor, the feedstock being part of a reaction mixture that also includes nitric acid and a secondary oxidizing acid;wherein the reaction mixture, excluding solids, includes no more than approximately 3 wt % of the secondary oxidizing acid. 17. The method of claim 16 comprising combining nitric acid and the secondary oxidizing acid with the feedstock before the feedstock enters the reactor. 18. The method of claim 16 comprising combining effluent from the reactor with the feedstock before the feedstock enters the reactor. 19. The method of claim 16 wherein the feedstock includes effluent from the reactor. 20. The method of claim 16 comprising maintaining a pressure in the reactor of at least approximately 2070 kPa. 21. The method of claim 20 wherein the pressure in the reactor is at least 2800 kPa. 22. A method comprising: oxidizing a feedstock in the reactor, the feedstock being part of a reaction mixture that also includes nitric acid, a secondary oxidizing acid, and oxygen gas;dispersing oxygen gas from a headspace of the reactor into the reaction mixture;maintaining the reaction mixture at a temperature that is no more than approximately 210° C.; andmaintaining a pressure in the reactor of at least approximately 2070 kPa;wherein the reaction mixture, excluding solids, includes no more than 5 wt % of the secondary oxidizing acid. 23. The method of claim 22 wherein the feedstock is a primary feedstock, the method comprising comminuting an initial feedstock to form the primary feedstock, wherein the largest dimension of at least approximately 95% of the particles in the primary feedstock is no more than 7 mm. 24. The method of claim 22 wherein the feedstock includes effluent from the reactor. 25. The method of claim 22 comprising combining nitric acid and the secondary oxidizing acid with the feedstock before the feedstock enters the reactor. 26. The method of claim 22 wherein the feedstock is a primary feedstock, the method comprising: combining effluent from the reactor with an initial feedstock to form an intermediate feedstock;comminuting the intermediate feedstock to form a comminuted feedstock; andcombining the comminuted feedstock, nitric acid, and the secondary oxidizing acid to form the primary feedstock. 27. The method of claim 1 wherein the secondary oxidizing acid includes sulfuric acid. 28. The method of claim 1 wherein the reaction mixture, excluding solids, includes no more than approximately 3 wt % of the secondary oxidizing acid. 29. The method of claim 28 wherein the secondary oxidizing acid includes sulfuric acid. 30. The method of claim 1 wherein the reaction mixture, excluding solids, includes no more than approximately 15 wt % nitric acid. 31. The method of claim 10 comprising maintaining a pressure in the reactor of at least approximately 2070 kPa. 32. The method of claim 10 comprising dispersing oxygen gas from a headspace of the reactor into the reaction mixture. 33. The method of claim 32 wherein the headspace includes 2 to 60 volume percent oxygen gas. 34. The method of claim 10 wherein the secondary oxidizing acid includes sulfuric acid. 35. The method of claim 10 wherein the reaction mixture, excluding solids, includes no more than approximately 15 wt % nitric acid. 36. The method of claim 16 wherein the feedstock is a primary feedstock, the method comprising comminuting an initial feedstock to form the primary feedstock, wherein the largest dimension of at least approximately 95% of the particles in the primary feedstock is no more than 7 mm. 37. The method of claim 16 wherein the secondary oxidizing acid includes sulfuric acid. 38. The method of claim 16 comprising dispersing oxygen gas from a headspace of the reactor into the reaction mixture. 39. The method of claim 38 wherein the headspace includes 2 to 60 volume percent oxygen gas. 40. The method of claim 16 wherein the reaction mixture, excluding solids, includes no more than approximately 15 wt % nitric acid. 41. The method of claim 16 comprising maintaining the reaction mixture at a temperature that is no more than approximately 210° C. 42. The method of claim 22 wherein the secondary oxidizing acid includes sulfuric acid. 43. The method of claim 22 wherein the reaction mixture, excluding solids, includes no more than approximately 3 wt % of the secondary oxidizing acid. 44. The method of claim 43 wherein the secondary oxidizing acid includes sulfuric acid. 45. The method of claim 22 wherein the reaction mixture, excluding solids, includes no more than approximately 15 wt % nitric acid.
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