초록 ▼

Provided are selective catalytic reduction (SCR) filters that effectively provide simultaneous treatment of particulate matter and NOx. Provided also are methods for reducing NOx concentration and particulate matter in a diesel engine exhaust by using the SCR filters. The SCR filter can include a fi

Provided are selective catalytic reduction (SCR) filters that effectively provide simultaneous treatment of particulate matter and NOx. Provided also are methods for reducing NOx concentration and particulate matter in a diesel engine exhaust by using the SCR filters. The SCR filter can include a fiber matrix wall flow filter comprising a plurality of non-woven inorganic fibers and a chabazite molecular sieve SCR catalyst on the fiber matrix wall flow filter. By combining a fiber matrix wall flow filter with a chabazite molecular sieve SCR catalyst, high catalyst loading can be achieved without causing excessive back pressure across the filter when implemented in emission treatment systems.

대표청구항 ▼

1. A method of reducing NOx and particulate matter in a diesel engine exhaust, comprising: injecting ammonia or an ammonia precursor into the diesel engine exhaust; andpassing the exhaust through a SCR filter comprising a fiber matrix wall flow filter and a chabazite molecular sieve SCR catalyst on

1. A method of reducing NOx and particulate matter in a diesel engine exhaust, comprising: injecting ammonia or an ammonia precursor into the diesel engine exhaust; andpassing the exhaust through a SCR filter comprising a fiber matrix wall flow filter and a chabazite molecular sieve SCR catalyst on the fiber matrix wall flow filter, the fiber matrix wall flow filter comprising a plurality of non-woven inorganic fibers. 2. The method of claim 1 further comprising passing the exhaust through an oxidation catalyst before injecting ammonia or ammonia precursor into the exhaust. 3. The method of claim 1, wherein the fiber matrix wall flow filter comprises at least one of alumina fibers, silica fibers, mullite fibers, silicon carbide fibers, aluminosilicate fibers, aluminum borosilicate fibers, or combinations thereof. 4. The method of claim 1, wherein the fiber matrix wall flow filter has a coefficient of thermal expansion from 200 to 800° C. of about 1×10−6/degree Celsius or more and about 6×10−6/degree Celsius or less. 5. The method of claim 1, wherein the fiber matrix wall flow filter has a porosity of about 50% or more and about 70% or less. 6. The method of claim 1, wherein the fiber matrix wall flow filter has a honeycomb structure. 7. The method of claim 1, wherein the chabazite molecular sieve SCR catalyst comprises metal exchanged chabazite molecular sieve. 8. The method of claim 7, wherein the chabazite molecular sieve SCR catalyst comprises Cu-exchanged chabazite molecular sieve, Fe-exchanged chabazite molecular sieve or a combination thereof. 9. The method of claim 7, wherein the chabazite molecular sieve SCR catalyst has a surface that is hydrophobic. 10. The method of claim 1, wherein the ammonia precursor is urea.