Use of shaped bodies having catalytic properties as reactor internals
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-031/00
B01J-021/00
B28B-001/00
B28B-003/00
B28B-005/00
B29B-017/00
B29C-063/00
B29C-065/00
B29C-069/00
B29C-071/00
C04B-033/32
C04B-033/36
C04B-035/64
출원번호
US-0681998
(2008-09-26)
등록번호
US-8119554
(2012-02-21)
우선권정보
EP-07118050 (2007-10-08)
국제출원번호
PCT/EP2008/062956
(2008-09-26)
§371/§102 date
20100407
(20100407)
국제공개번호
WO2009/047141
(2009-04-16)
발명자
/ 주소
Kashani-Shirazi, Nawid
Wloka, Veronika
Gerlinger, Wolfgang
Schmidt, Andrea
Heinen, Kerstin
Kollenberg, Wolfgang
출원인 / 주소
BASF SE
대리인 / 주소
Connolly Bove Lodge & Hutz LLP
인용정보
피인용 횟수 :
3인용 특허 :
2
초록▼
Shaped bodies having catalytic properties which can be obtained by a process comprising the steps: a) production of a shaped body by means of a powder-based rapid prototyping process,b) if appropriate, a heat treatment of the shaped body,c) if appropriate, application of at least one catalytically a
Shaped bodies having catalytic properties which can be obtained by a process comprising the steps: a) production of a shaped body by means of a powder-based rapid prototyping process,b) if appropriate, a heat treatment of the shaped body,c) if appropriate, application of at least one catalytically active component to the shaped body,d) if appropriate, a further heat treatment,where steps b), c) and/or d) can be carried out a number of times, are used as reactor internals in heterogeneously catalyzed chemical reactions.
대표청구항▼
1. A process for the preparation of shaped bodies having catalytic properties as reactor internals in heterogeneously catalyzed chemical reactions comprising the steps: a) production of a shaped body by means of a powder-based rapid prototyping process, of the following steps which are repeated unti
1. A process for the preparation of shaped bodies having catalytic properties as reactor internals in heterogeneously catalyzed chemical reactions comprising the steps: a) production of a shaped body by means of a powder-based rapid prototyping process, of the following steps which are repeated until the desired shaped body has been built up completely from the individual layers: Applying a pulverulent starting material or starting material mixture having an average particle size in the range from about 0.5 μm to about 450 μm in a thin layer to a substrate and subsequently admixing at selected places on this layer with a binder and any auxiliaries required or irradiating or treating in another way so that the powder is bonded at these places, as a result of which the powder is bound both within the layer and also to the adjoining layers, repeating this procedure as often as necessary for the desired shape of the workpiece to have been reproduced completely in the powder bed formed, removing the powder which has not been bound by the binder to leave the bound powder in the desired shaped body,b) a heat treatment of the shaped body in the format sintering and/or calcination, wherein firstly binder removal can be carried out,c) application of at least one catalytically active component to the shaped body, andd) if appropriate, a further heat treatment,where steps b), c) and/or d) can be carried out a number of times. 2. The process according to claim 1, wherein a binder or binder mixture selected so that it itself or its residues do not affect or do not adversely affect the chemical reaction in the later use as catalyst (support) is used in step a). 3. The process according to claim 2, wherein a sol or a colloidal solution of silicon dioxide or aluminosilicates, silica, silicic esters, siloxanes or silicones or a water-based liquid binder with addition of vinyl polymers or other wetting agents is used as binder in step a). 4. The process according to claim 2, wherein the shaped bodies are made up of silicon dioxide, aluminum oxide, titanium dioxide, zirconium dioxide, magnesium oxide, calcium oxide, mixed metal oxides, hydrotalcites, spinels, Perovskites, metal phosphates, silicates, zeolites, steatite, cordierite, carbides, nitrides or mixtures or blends thereof. 5. The process according to claim 2, wherein a pulverulent starting material having an average particle size in the range from 1 μm to 450 μm is used in step a). 6. The process according to claim 2, wherein the heat treatment in step b) is carried out as a calcination at temperatures in the range from 350 to 2100° C. 7. The process according to claim 1, wherein a sol or a colloidal solution of silicon dioxide or aluminosilicates, silica, silicic esters, siloxanes or silicones or a water-based liquid binder with addition of vinyl polymers or other wetting agents is used as binder in step a). 8. The process according to claim 7, wherein the shaped bodies are made up of silicon dioxide, aluminum oxide, titanium dioxide, zirconium dioxide, magnesium oxide, calcium oxide, mixed metal oxides, hydrotalcites, spinels, Perovskites, metal phosphates, silicates, zeolites, steatite, cordierite, carbides, nitrides or mixtures or blends thereof. 9. The process according to claim 7, wherein a pulverulent starting material having an average particle size in the range from 1 μm to 450 μm is used in step a). 10. The process according to claim 1, wherein the shaped bodies are made up of silicon dioxide, aluminum oxide, titanium dioxide, zirconium dioxide, magnesium oxide, calcium oxide, mixed metal oxides, hydrotalcites, spinels, Perovskites, metal phosphates, silicates, zeolites, steatite, cordierite, carbides, nitrides or mixtures or blends thereof. 11. The process according to claim 10, wherein a pulverulent starting material having an average particle size in the range from 1 μm to 450 μm is used in step a). 12. The process according to claim 1, wherein a pulverulent starting material having an average particle size in the range from 1 μm to 450 μm is used in step a). 13. The process according to claim 1, wherein the heat treatment in step b) is carried out as a calcination at temperatures in the range from 350 to 2100° C. 14. The process according to claim 1, wherein the powder used in step a) has been subjected to a pretreatment comprising at least one of the steps milling, sieving, calcination, granulation, compacting, mixing, and agglomeration. 15. The process according to claim 1, wherein the shaped bodies have channels through which a reaction medium flows and which are inclined to the main flow direction at an angle in the range from 0° to 70°. 16. The process according to claim 1, wherein the shaped bodies are configured as multichannel packings which have channels in which the chemical reaction preferentially takes place and additionally comprise channels in which convective heat transport preferentially takes place, with the channels for heat transport preferably being inclined at a greater angle and preferably having a hydraulic diameter which is 2-10 times the diameter of the channels for catalysis. 17. The process according to claim 16, wherein the shaped bodies are configured as multichannel packings whose individual layers are perforated to achieve better mass transfer. 18. The process according to claim 16, wherein the channels for heat transport are inclined at a greater angle than the channels for catalysis. 19. The process according to claim 16, wherein the channels for heat transport have a hydraulic diameter which is 2-10 times the diameter of the channels for catalysis. 20. The process according to claim 16, wherein the shaped bodies have channels through which a reaction medium flows and which are inclined to the main flow direction at an angle in the range from 30° to 60°.
연구과제 타임라인
LOADING...
LOADING...
LOADING...
LOADING...
LOADING...
이 특허에 인용된 특허 (2)
Cleveland Joseph J. (Wysox PA), Method for producing ceramic cellular structure having high cell density.
deAngelis Alfredo O. (241 Freeman St. #1 Brookline MA 02146), Method of three-dimensional rapid prototyping through controlled layerwise deposition/extraction and apparatus therefor.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.