초록 ▼

To provide a glass containing little B2O3, whereby when its powder is fired, its thermal expansion curve does not have an inflection point, a non-lead glass is provided containing, as represented by mol % based on the following oxides, from 35 to 41.5% of SiO2, from 8 to 25% of MgO, more than 27 to

To provide a glass containing little B2O3, whereby when its powder is fired, its thermal expansion curve does not have an inflection point, a non-lead glass is provided containing, as represented by mol % based on the following oxides, from 35 to 41.5% of SiO2, from 8 to 25% of MgO, more than 27 to 35% of CaO, from 0 to 2% of SrO, from 0 to 4% of BaO, from 5 to 15% of ZnO and from 4.5 to 10% of Al2O3, wherein the total content of these components is at least 97%, and when SrO and BaO are contained, the total content of SrO and BaO is at most 2%; as well as a non-lead glass containing, as represented by mol % based on the following oxides, from 39.5 to 41.5% of SiO2, from 10 to less than 13% of MgO, from 18 to 22% of CaO, more than 12 to 15% of SrO, from 0 to 1% of BaO, from 6 to 11% of ZnO and from 4.5 to 7% of Al2O3, wherein the total content of these components is at least 97%.

대표청구항 ▼

1. Non-lead glass comprising, as represented by mol % based on the following oxides, from 38 to 41.5% of SiO2, from 13 to 17% of MgO, 28 to 33% of CaO, from 0 to 2% of SrO, from 0 to 2.2% of BaO, from 5 to 12% of ZnO and from 4.5 to 7% of Al2O3, wherein the total content of these components is at le

1. Non-lead glass comprising, as represented by mol % based on the following oxides, from 38 to 41.5% of SiO2, from 13 to 17% of MgO, 28 to 33% of CaO, from 0 to 2% of SrO, from 0 to 2.2% of BaO, from 5 to 12% of ZnO and from 4.5 to 7% of Al2O3, wherein the total content of these components is at least 97%, and when SrO and BaO are contained, the total content of SrO and BaO is at most 2%; wherein the molar ratio of CaO to MgO is from 1.8 to 2.2. 2. The non-lead glass according to claim 1, wherein BaO is from 0.8 to 1.2%, and from 0.8 to 1.2% of La2O3 is contained. 3. The non-lead glass according to claim 1, wherein SiO2 is at most 41.2%. 4. The non-lead glass according to claim 1, wherein an alkali metal oxide is not contained, or an alkali metal oxide is contained in the total amount of at most 1%. 5. The non-lead glass according to claim 1, which has a softening point of higher than 800° C. 6. The non-lead glass according to claim 1, wherein when its powder is fired at 950° C., a fired product obtained has an average linear expansion coefficient of from 90×10−7 to 110×10−7/° C. at from 50 to 1,000° C. 7. The non-lead glass according to claim 1, wherein when its powder is fired at from 900 to 1,100° C., CaO—MgO—SiO2 crystal precipitates in a fired product obtained. 8. Sealing glass made of the non-lead glass as defined in claim 1, which has a sealing temperature of at least 900° C. 9. A glass paste, which contains a powder of the non-lead glass as defined in claim 1. 10. A green sheet, which contains a powder of the non-lead glass as defined in claim 1. 11. A process for producing a solid oxide fuel cell, which comprises a step of sealing members made of a ceramics or metal each other by means of a powder of the non-lead glass as defined in claim 1. 12. A solid oxide fuel cell having at least one sealed part at which members made of a ceramics or metal are sealed each other, wherein at least one sealed part is sealed with a fired product formed by firing the non-lead glass as defined in claim 1.