IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
|
출원번호 |
US-0587350
(2009-10-06)
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등록번호 |
US-8188318
(2012-05-29)
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발명자
/ 주소 |
- Petraitis, David M.
- King, Stephen W.
- Srnak, Thomas Z.
|
출원인 / 주소 |
- Union Carbide Chemicals & Plastics Technology LLC
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대리인 / 주소 |
|
인용정보 |
피인용 횟수 :
5 인용 특허 :
71 |
초록
▼
The present invention provides methods of manufacturing ethyleneamines that makes use of an ethyleneamine-generating process that is coupled to a transamination process. The combination of an ethyleneamine-generating process with a transamination process improves the mix flexibility that can be obta
The present invention provides methods of manufacturing ethyleneamines that makes use of an ethyleneamine-generating process that is coupled to a transamination process. The combination of an ethyleneamine-generating process with a transamination process improves the mix flexibility that can be obtained from the single process allowing the production of ethyleneamine compositions having an improved and more desirable product mix.
대표청구항
▼
1. A method of manufacturing ethyleneamines, the method comprising the steps of: (a) manufacturing an ethyleneamines composition comprising a mixture of ethyleneamines using an ethyleneamine-generating process; and(b) transaminating at least a portion of the ethyleneamines composition in the presenc
1. A method of manufacturing ethyleneamines, the method comprising the steps of: (a) manufacturing an ethyleneamines composition comprising a mixture of ethyleneamines using an ethyleneamine-generating process; and(b) transaminating at least a portion of the ethyleneamines composition in the presence of a hydrogenation/dehydrogenation catalyst to form a transaminated ethyleneamines composition;wherein the transaminated ethyleneamines composition comprises at least one ethyleneamine that is present in an amount that is greater than an amount that the at least one ethyleneamine is present in the ethyleneamines composition that is transaminated in step (b). 2. The method of claim 1, wherein the method further comprises the step of: removing at least a portion of at least one ethyleneamine from the ethyleneamines composition. 3. The method of claim 1, wherein the ethyleneamine-generating process comprises an ethylenedichloride (EDC) process. 4. The method of claim 1, wherein the ethyleneamine-generating process comprises a reductive amination (RA) process. 5. The method of claim 1, wherein the ethyleneamine-generating process comprises a condensation process. 6. A method of manufacturing ethyleneamines, the method comprising the steps of: (a) manufacturing an ethyleneamines composition comprising one or more ethyleneamines using an ethyleneamine-generating process selected from an ethylenedichloride (EDC) process, a reductive amination (RA) process, and a condensation process; and(b) transaminating at least a portion of the ethyleneamines composition in the presence of a transamination catalyst to form a transaminated ethyleneamines composition;wherein the transaminated ethyleneamines composition comprises at least one ethyleneamine that is present in an amount that is greater than an amount that the at least one ethyleneamine is present in the ethyleneamines composition that is transaminated in step (b). 7. The method of claim 1, wherein the ethyleneamines composition comprises any combination of two or more ethyleneamines selected from HPA, PEHA, AEEA, AEP, PIP, TEPA, TETA, DETA, and EDA. 8. The method of claim 1, wherein the transamination step increases the amount of at least one of TETA; DETA; EDA; or AEP that is present in the transaminated ethyleneamines composition as compared to the ethyleneamines composition that is transaminated in step (b). 9. The method of claim 1, wherein the transamination is conducted using a fixed bed reactor. 10. The method of claim 1, wherein the transamination is conducted over a transamination catalyst. 11. The method of claim 10, wherein the transamination catalyst comprising Ni, Cu, Co, Ru, Re, Rh, Pt, Pd, or a mixture thereof. 12. The method of claim 10, wherein the transamination catalyst comprises transitional alumina containing silica. 13. The method of claim 10, wherein the transamination catalyst comprises Re and Ni supported on an extruded Al2O3—SiO2 support. 14. The method of claim 10, wherein the transamination catalyst comprises: (a) a support portion comprising an acidic mixed metal oxide comprising a transitional alumina and a second metal oxide; and(b) a catalyst portion comprising nickel and rhenium, wherein:the second metal oxide has a weight percentage that is less than the weight percentage of alumina,the catalyst portion is 25 weight percent or less of the catalyst composition,the catalyst portion comprises nickel in an amount in the range of 2 to 20 weight percent, based upon total catalyst composition weight, andthere is no boron in the catalyst portion. 15. The method of claim 10, wherein the transamination catalyst comprises: (a) a support portion comprising an acidic mixed metal oxide comprising a transitional alumina and a second metal oxide, wherein the second metal oxide has a weight percentage that is less than the weight percentage of alumina; and(b) a catalyst portion comprising one or more metals selected from the group consisting of cobalt, nickel, and copper,wherein there is no, or less than 0.01 wt. % rhenium in the catalyst composition, and the catalyst portion is 25 wt. % or less of the catalyst composition. 16. The method of claim 15, wherein the catalyst portion comprises two or three metals selected from the group consisting of cobalt, nickel, and copper. 17. The method of claim 1, wherein the transamination is conducted in the presence of hydrogen. 18. The method of claim 1, wherein the transamination is conducted in the presence of ammonia. 19. The method of claim 1, wherein the transamination process is partially-integrated into the ethyleneamine-generating process. 20. The method of claim 1, wherein the transamination process is fully-integrated into the ethyleneamine-generating process.
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