초록 ▼

The invention relates to a shell catalyst containing ruthenium as an active metal, alone or together with at least one other metal of the auxiliary group IB, VIIB or VIII of the periodical system of the elements (CAS version), and applied to a carrier containing silicon dioxide as a carrier material

The invention relates to a shell catalyst containing ruthenium as an active metal, alone or together with at least one other metal of the auxiliary group IB, VIIB or VIII of the periodical system of the elements (CAS version), and applied to a carrier containing silicon dioxide as a carrier material. The invention also relates to a method for producing said shell catalyst, and to a method for hydrogenating an organic compound containing hydrogenable groups, preferably for hydrogenating a carbocyclic aromatic group to form the corresponding carbocyclic aliphatic groups or for hydrogenating aldehydes to form the corresponding alcohols, using the inventive shell catalyst. The invention further relates to the use of the inventive shell catalyst for hydrogenating an organic compound containing hydrogenable groups, preferably for hydrogenating a carbocyclic aromatic group to form the corresponding carbocyclic aliphatic groups or for hydrogenating aldehydes to form the corresponding alcohols.

대표청구항 ▼

1. A coated catalyst comprising, as an active metal, ruthenium alone or together with at least one further metal of transition groups IB, VIIB or VIII of the Periodic Table of the Elements (CAS version), applied to a support material consisting of silicon dioxide at least to an extent of 90% by weig

1. A coated catalyst comprising, as an active metal, ruthenium alone or together with at least one further metal of transition groups IB, VIIB or VIII of the Periodic Table of the Elements (CAS version), applied to a support material consisting of silicon dioxide at least to an extent of 90% by weight and the remaining up to 10% by weight of the support material being selected from the group consisting of MgO, CaO, TiO2, ZrO2, Fe2O3, and alkali metal oxide, or a mixture thereof, wherein the amount of the active metal is <1% by weight based on the total weight of the catalyst, and at least 60% by weight of the active metal is present in the coating of the catalyst up to a penetration depth of 200 μm, determined by SEM-EPMA (EDXS), wherein the catalyst is prepared by impregnating the support material once or more than once with a solution of ruthenium(III) acetate alone or together with a solution of at least one further salt of metals of transition groups IB, VIIB or VIII of the Periodic Table of the Elements (CAS version), drying and reduction, the solution of the at least one further salt of metals of transition groups IB, VIIB or VIII of the Periodic Table of the Elements being applicable in one or more impregnation steps together with the solution of ruthenium(III) acetate or in one or more impregnation steps separately from the solution of ruthenium(III) acetate. 2. The coated catalyst according to claim 1, wherein the amount of the active metal is from 0.1 to 0.5% by weight. 3. The coated catalyst according to claim 1, wherein at least 80% by weight of the active metal is present in the coating of the catalyst up to a penetration depth of 200 μm. 4. The coated catalyst according to claim 1, wherein the amount of active metal, based on the weight ratio of active metal to Si, on the surface of the coated catalyst is from 2 to 25%, determined by SEM-EPMA (EDXS). 5. The coated catalyst according to claim 1, wherein the ruthenium is present partly or fully in crystalline form. 6. The coated catalyst according to claim 1, wherein the coated catalyst additionally comprises alkaline earth metal ions (M2+). 7. The coated catalyst according to claim 1, wherein the support material has a BET surface area (DIN 66131) in the range from 30 to 700 m2/g. 8. The coated catalyst according to claim 1, which comprises less than 0.05% by weight of halide (determined by ion chromatography), based on the total weight of the catalyst. 9. A process for preparing a coated catalyst according to claim 1, comprising: a) impregnating the support material consisting of silicon dioxide at least to an extent of 90% by weight and the remaining up to 10% by weight of the support material being selected from the group consisting of MgO, CaO, TiO2, ZrO2, Fe2O3, and alkali metal oxide, or a mixture thereof once or more than once with a solution of ruthenium(III) acetate alone or together with a solution of at least one further salt of metals of transition groups IB, VIIB or VIII of the Periodic Table of the Elements (CAS version);b) subsequent drying; andc) subsequent reduction;the solution of the at least one further salt of metals of transition groups IB, VIIB or VIII of the Periodic Table of the Elements being applicable in one or more impregnation steps together with the solution of ruthenium(III) acetate or in one or more impregnation steps separately from the solution of ruthenium(III) acetate. 10. A process for hydrogenating an organic compound which comprises hydrogenatable groups, which comprises using a coated catalyst according to claim 1. 11. The process according to claim 10, wherein a carbocyclic aromatic group is part of an aromatic hydrocarbon which has the following general formula: (A)-(B)n wherein A, B, and n are each defined as follows:A is independently aryl or heteroaryl;n is from 0 to 5, the remaining carbon atoms or heteroatoms of A not bearing any substituents B bear hydrogen atoms or, if appropriate, no substituents; andB is independently selected from the group consisting of alkyl, alkenyl, alkynyl, substituted alkyl, substituted alkenyl, substituted alkynyl, heteroalkyl, substituted heteroalkyl, heteroalkenyl, substituted heteroalkenyl, heteroalkynyl, substituted heteroalkynyl, cycloalkyl, cycloalkenyl, substituted cycloalkyl, substituted cycloalkenyl, COOR wherein R is H, alkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl, aryl or substituted aryl, halogen, hydroxyl, alkoxy, aryloxy, carbonyl, amino, amido, thio and phosphino. 12. The process according to claim 11, wherein A is phenyl, n is from 0 to 3 and B is C1-6-alkyl, COOR wherein R is H or linear or branched C1-12-alkyl, amino, hydroxyl or alkoxy. 13. The process according to claim 11, wherein the aromatic hydrocarbon is selected from the group consisting of benzene and alkyl-substituted benzenes, ethylbenzene, xylene, mesitylene and mixtures thereof. 14. The process according to claim 11, wherein the aromatic hydrocarbon is selected from the group consisting of phenol, alkyl-substituted phenols, bis(p-hydroxyphenyl)methane and bis(p-hydroxyphenyl)dimethylmethane. 15. The process according to claim 11, wherein the aromatic hydrocarbon is selected from the group consisting of aniline, alkyl-substituted aniline, N,N-dialkylaniline, diaminobenzene, bis(p-aminophenyl)methane and bis(p-aminotolyl)methane. 16. The process according to claim 11, wherein the aromatic hydrocarbon is selected from the group consisting of aromatic carboxylic acids and aromatic carboxylic esters. 17. The process according to claim 10, wherein the aldehyde is a mono- or disaccharide which is hydrogenated to a corresponding sugar alcohol. 18. The process according to claim 10, wherein the hydrogenation is effected in a fixed bed reactor. 19. The process according to claim 18, wherein benzene is hydrogenated at a temperature of from 75 to 170° C., and a pressure of from 10 to 45 bar, wherein the sulfur content of the benzene is <0.2 ppm by weight. 20. The process of according to claim 10, wherein the organic compound which comprises hydrogenated groups is selected from a carbocyclic aromatic group which is hydrogenated to the corresponding carbocyclic aliphatic group and from aldehydes which are hydrogenated to corresponding alcohols.