IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0483294
(2009-06-12)
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등록번호 |
US-8211498
(2012-07-03)
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발명자
/ 주소 |
- Ku, Anthony Yu-Chung
- Taylor, Seth Thomas
- Manoharan, Mohan
- Loureiro, Sergio Paulo Martins
- Ruud, James Anthony
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출원인 / 주소 |
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대리인 / 주소 |
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인용정보 |
피인용 횟수 :
10 인용 특허 :
2 |
초록
▼
In some embodiments, the present invention is directed to methods of making structures with complex functional architectures, where such structures generally comprise at least two mesoporous regions comprising different chemical activity, and where such methods afford spatial control over the placem
In some embodiments, the present invention is directed to methods of making structures with complex functional architectures, where such structures generally comprise at least two mesoporous regions comprising different chemical activity, and where such methods afford spatial control over the placement of such regions of differing chemical activity. In some embodiments, the present invention is also directed to the structures formed by such methods, where such structures are themselves novel.
대표청구항
▼
1. A method comprising the steps of: a) providing a framework in which a mesoporous ceramic can be generated;b) depositing, in a first region of the framework, a first precursor mixture;c) treating the first precursor mixture so as to form a region of mesoporous ceramic substructure comprising a fir
1. A method comprising the steps of: a) providing a framework in which a mesoporous ceramic can be generated;b) depositing, in a first region of the framework, a first precursor mixture;c) treating the first precursor mixture so as to form a region of mesoporous ceramic substructure comprising a first chemical activity;d) depositing, in a second region of the framework adjacent to the region of mesoporous ceramic substructure comprising a first chemical activity, a second precursor mixture; ande) treating the second precursor mixture so as to form a region of mesoporous ceramic substructure comprising a second chemical activity, wherein the regions of mesoporous ceramic substructure of first and second chemical activity provide for a mesoporous membrane structure comprising regions of mesoporous ceramic, wherein such regions are differentiable by at least one property selected from the group consisting of chemical activity, pore morphology, bulk chemical composition, and compositions thereof; wherein both of the first and second precursor mixtures comprise a quantity of a self-assembling surfactant species, a quantity of ceramic precursor, and wherein at least one of the first and second precursor mixtures comprises a species for imparting organic-based chemical activity to the region in which it is present. 2. The method of claim 1, wherein the method provides for a mesoporous membrane structure comprising regions of mesoporous ceramic of different chemical activity. 3. The method of claim 2, further comprising a step of depositing additional precursor mixtures into additional regions of the framework, wherein such additional precursor mixtures are treated so as to form additional regions of mesoporous ceramic substructure comprising additional chemical activities, and wherein this additional precursor mixture deposition and treatment provides for a structure comprising at least three chemically-distinct mesoporous ceramic regions. 4. The method of claim 2, wherein the method provides positional control over the deposition of the first and second precursor mixtures and over placement of the regions of mesoporous ceramic substructure so formed. 5. The method of claim 2, further comprising a step of removing at least part of the framework. 6. The method of claim 5, wherein the framework is completely removed to yield mesoporous ceramic nanorods. 7. The method of claim 6, wherein the chemical activity varies within individual nanorods. 8. The method of claim 6, wherein the chemical activity varies between individual nanorods. 9. The method of claim 2, wherein at least one of the first and second chemical activities is at least partially-derived from organic-based molecules covalently-integrated with the region of mesoporous ceramic substructure with which it is associated. 10. The method of claim 9, wherein the organic-based molecules comprise functional moieties selected from the group consisting of alkyl, mercapto, carboxyl, vinyl, amine, benzyl, and combinations thereof. 11. The method of claim 10, further comprising a step of chemically modifying the functional moieties so as to alter the chemical activity of the mesoporous region in which they are present. 12. The method of claim 11, wherein step of chemically modifying involves treating at least some of the functional moieties in the mesoporous regions in which they are present with a species selected from the group consisting of organic species, organometallic species, metallic species, and combinations thereof. 13. The method of claim 2, wherein the regions of mesoporous ceramic substructure comprise a bulk composition selected from the group consisting of SiO2, TiO2, Al2O3, ZrO2, Y2O3:ZrO2, Y2O3, and combinations thereof.
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