IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
|
출원번호 |
US-0649108
(2009-12-29)
|
등록번호 |
US-8216963
(2012-07-10)
|
발명자
/ 주소 |
- Kibby, Charles L.
- Haas, Alfred
|
출원인 / 주소 |
|
대리인 / 주소 |
|
인용정보 |
피인용 횟수 :
5 인용 특허 :
42 |
초록
▼
A method for forming a cobalt-containing Fischer-Tropsch catalyst involves precipitating a cobalt oxy-hydroxycarbonate species by turbulent mixing, during which a basic solution collides with an acidic solution comprising cobalt. The method further involves depositing the cobalt oxy-hydroxycarbonate
A method for forming a cobalt-containing Fischer-Tropsch catalyst involves precipitating a cobalt oxy-hydroxycarbonate species by turbulent mixing, during which a basic solution collides with an acidic solution comprising cobalt. The method further involves depositing the cobalt oxy-hydroxycarbonate species onto a support material to provide a catalyst comprising cobalt and the support material. The support material comprises one or more of alumina, silica, magnesia, titania, zirconia, ceria-zirconia, and magnesium aluminate.
대표청구항
▼
1. A method for forming a cobalt-containing Fischer-Tropsch catalyst, comprising: precipitating a cobalt oxy-hydroxycarbonate species by turbulent mixing, wherein a basic solution is collided with an acidic solution comprising cobalt; anddepositing the cobalt oxy-hydroxycarbonate species onto a supp
1. A method for forming a cobalt-containing Fischer-Tropsch catalyst, comprising: precipitating a cobalt oxy-hydroxycarbonate species by turbulent mixing, wherein a basic solution is collided with an acidic solution comprising cobalt; anddepositing the cobalt oxy-hydroxycarbonate species onto a support material to provide a catalyst comprising cobalt and the support material, wherein the support material comprises one or more of alumina, silica, magnesia, titania, zirconia, ceria-zirconia, and magnesium aluminate. 2. The method of claim 1, wherein depositing the cobalt oxy-hydroxycarbonate species onto the support material comprises injecting the cobalt oxy-hydroxycarbonate species into an aqueous slurry of the support material. 3. The method of claim 1, wherein depositing the cobalt oxy-hydroxycarbonate species onto the support material comprises mixing the support material with either the acidic solution or the basic solution such that the cobalt oxy-hydroxycarbonate species is precipitated onto the support material. 4. The method of claim 1, further comprising multiple precipitation/deposition iterations with intervening decompositions. 5. The method of claim 1, further comprising spray drying the cobalt-containing Fischer-Tropsch catalyst to provide a fluidized bed catalyst or a slurry catalyst. 6. The method of claim 1, wherein the acidic solution and the basic solution are heated. 7. The method of claim 6, wherein the acidic solution and the basic solution are heated to a temperature of about 80° C. 8. The method of claim 1, wherein the acidic solution comprises cobalt (II) nitrate. 9. The method of claim 1, wherein the acidic solution further comprises one or more metals selected from the group consisting of Re, Ru, Pt, Fe, Ni, Th, Zr, Hf, U, Mg, La, Au, Ag, Cu, Pd, Rh, Ir, Mn, and Cr. 10. The method of claim 9, wherein the acidic solution comprises Co(NO3)2*6H2O+Ru(NO)(NO3)3. 11. The method of claim 10, wherein the acidic solution has a weight ratio of Co:Ru between about 1:1 and about 400:1. 12. The method of claim 11, wherein the acidic solution further comprises La(NO3)3*6H2O and has a weight ratio of Co/Ru/La=about 40/1/1. 13. The method of claim 1, wherein the basic solution comprises K2CO3 or (NH4)2CO3 and has a pH of about 7 to about 9. 14. The method of claim 1, further comprising decomposing the oxy-hydroxycarbonate species at about 200° C. in an oxidizing environment, inert gas, or a reducing environment. 15. The method of claim 14, further comprising calcining the catalyst comprising cobalt and the support material at a temperature of about 250° C. to about 350° C. 16. The method of claim 1, further comprising reducing the catalyst comprising cobalt and the support material at a temperature of about 350° C. to about 400° C. 17. The method of claim 16, further comprising re-oxidizing the catalyst comprising cobalt and the support material at ≦ about 300° C. 18. The method of claim 17, further comprising reducing the catalyst comprising cobalt and the support material for a second time. 19. The method of claim 18, further comprising passivating the catalyst comprising cobalt and the support material between reducing and re-oxidizing and/or after reducing for a second time. 20. A method of performing a Fischer-Tropsch synthesis reaction, comprising: forming a cobalt-containing Fischer-Tropsch catalyst according to the method of claim 1; andcontacting the cobalt-containing Fischer-Tropsch catalyst with synthesis gas.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.