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특허 상세정보

Water repellent metal-organic frameworks, process for making and uses regarding same

특허상세정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판) C07F-015/00   
미국특허분류(USC) 556/132; 556/001; 556/115; 556/136; 556/142; 534/015
출원번호 US-0420588 (2009-04-08)
등록번호 US-8269029 (2012-09-18)
발명자 / 주소
  • Masel, Richard I
  • Ni, Zheng
  • Chen, Qingmei
출원인 / 주소
  • The Board of Trustees of the University of Illinois
대리인 / 주소
    Kilpatrick Townsend & Stockton LLP
인용정보 피인용 횟수 : 4  인용 특허 : 167
초록

Microwave assisted synthesis may be used to produce water-repellent metallic organic frameworks (MOFs) molecules. The water-repellent MOFs contain non-polar functional groups, such as a trifluoromethoxy group, which has a strong water repellent effect. The water-repellent MOF, when exposed to water vapor for one week does not result in a significant X-ray power pattern change. The water-repellent MOFs may be suitable as an adsorbent in many industrial applications, such as gas chromatography.

대표
청구항

1. A metal organic framework (MOF), comprising: a plurality of metals and/or metal oxides and a plurality of ligands arranged to form a crystalline structure having a surface area of at least about 100 m2/gm, wherein said plurality of ligands have a structure of formula I; wherein R1 is DY3 or A-DY3 or A-B-DY3, wherein R2-R4 is DY3 or A-DY3 or A-B-DY3 or hydrogen; wherein A is O or S and B is DY2 or O or S, each D is independently C or Si, each Y is independently hydrogen, fluorine, chlorine, or bromine, with the provisos that (i) at least one of A or B...

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