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Processes for conversion of lignin to products such as phenolic compounds and biofuels prepared from such phenolic compounds are disclosed and described. A process for conversion of a lignin material to bio-fuels can include subjecting the lignin material to a base catalyzed depolymerization reactio

Processes for conversion of lignin to products such as phenolic compounds and biofuels prepared from such phenolic compounds are disclosed and described. A process for conversion of a lignin material to bio-fuels can include subjecting the lignin material to a base catalyzed depolymerization reaction to produce a partially depolymerized lignin. The partially depolymerized lignin can then be subjected to a stabilization/partial hydrodeoxygenation reaction to form a partially hydrodeoxygenated product. Following partial hydrodeoxygenation, the partially hydrodeoxygenated product can be reacted in a hydroprocessing step to form a bio-fuel. Each of these reaction steps can be performed in single or multiple steps, depending on the design of the process. The production of an intermediate partially hydrodeoxygenation product and subsequent reaction thereof can significantly reduce or eliminate reactor plugging and catalyst coking. A variety of useful bio-fuels such as fuels, fuel additives, and the like, including gasoline and jet or rocket fuels are describe which can be readily produced from renewable lignin materials in an improved conversion process.

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1. A process for conversion of a lignin material to substantially phenolic compounds comprising: a) Subjecting the lignin material to a base catalyzed depolymerization reaction to produce a partially depolymerized lignin;b) Subjecting the partially depolymerized lignin to a stabilization/partial hyd

1. A process for conversion of a lignin material to substantially phenolic compounds comprising: a) Subjecting the lignin material to a base catalyzed depolymerization reaction to produce a partially depolymerized lignin;b) Subjecting the partially depolymerized lignin to a stabilization/partial hydrodeoxygenation reaction to form a partially hydrodeoxygenated product, said process being carried out in the presence of a catalyst containing one or more metals selected from the group consisting of Group VI metals of the Periodic Table, Group VIII metals of the Periodic Table, vanadium and mixtures thereof; wherein said partially hydrodeoxygenated product is substantially comprised of aromatic compounds having a single oxygen moiety substituent, andc) Treating the product of step b) in a mild hydrocracking process to produce substantially monomeric phenols. 2. The process of claim 1 wherein the step b) is carried out at a temperature of about 200 to about 300° C. 3. The process of claim 1 wherein the catalyst is selected from the group consisting of sulfided Mo, Co, Pt, and of VN, Mo2N, TiN, WC, Mo2C, VC, and mixtures thereof. 4. The process of claim 3 wherein the catalyst is positioned on a support selected from the group consisting of carbon and silicon dioxide. 5. The process of claim 1 wherein the catalyst is selected from the group consisting of sulfided Pt, Co, Mo and mixtures thereof. 6. The process of claim 1 wherein the catalyst is positioned on a support selected from the group consisting of carbon and silicon dioxide. 7. The process of claim 1, wherein the stabilization/partial hydrodeoxygenation step is carried out at a temperature of about 200 to about 300° C. in the presence of a catalyst that is selected from the group consisting of sulfided Pt, Co, Mo and mixtures thereof, said catalyst being positioned on a non-acidic activated carbon support. 8. The process of claim 1 wherein the mild hydrocracking process is carried out at a reaction temperature from about 200° C. to about 400° C. and a hydrogen pressure from about 1000 to about 1800 psig. 9. The process of claim 8 wherein the process is carried out in the presence of an acidic catalyst. 10. The process of claim 9 wherein the catalyst is selected from the group consisting of Pt/WO42−/ZrO2, heteropolyacids, salts of heteropolyacids, and FeCl3.H2O. 11. A process for producing aromatic etherified products comprising etherifying the substantially monomeric phenol compounds prepared by the process of claim 1. 12. The process of claim 11 wherein the aromatic etherified product is the substantially monomeric phenol compounds prepared by the process of claim 8. 13. The process of claim 11 wherein the aromatic etherified product is the substantially monomeric phenol compounds prepared by the process of claim 10. 14. The process of claim 11 wherein the etherified product is prepared by reacting the product of claim 1 with an alcohol selected from the group consisting of methanol and ethanol. 15. The process of claim 14 wherein the etherification is carried out at a temperature from about 200° C. to about 400° C. 16. The process of claim 14 wherein the etherification is carried out in the presence of a catalyst selected from the group consisting of heteropolyacids, salts of heteropolyacids, potassium benzoate, Cs—P/SiO2, sulfated manganese oxide/aluminum oxide, sulfated molybdenum oxide/aluminum oxide, sulfated tungsten oxide/aluminum oxide, sulfated chromium oxide/aluminum oxide, and sulfated cerium oxide/aluminum oxide.