초록 ▼

The present invention relates to a method and apparatus for intensifying the energy content of an organic material by converting the material into hydrocarbons and the resulting product thereof. A method for converting an organic material into hydrocarbon fuels is disclosed. The method comprising th

The present invention relates to a method and apparatus for intensifying the energy content of an organic material by converting the material into hydrocarbons and the resulting product thereof. A method for converting an organic material into hydrocarbon fuels is disclosed. The method comprising the steps of pressurizing said organic material being in a fluid to a pressure above 225 bar, heating said organic material in said fluid to a temperature above 200 C in the presence of a homogeneous catalyst comprising a compound of at least one element of group IA of the periodic table of elements. The disclosed method further comprises the steps of contacting said organic material in said fluid with a heterogeneous catalyst comprising a compound of at least one element of group IVB of the periodic table and/or alpha-alumina assuring that said fluid has initially a pH value of above 7.

대표청구항 ▼

1. A method for converting an organic material feed into a hydrocarbon fuel product, comprising the steps of: pressurizing said organic material being in a slurry to a pressure above 225 bar,heating said organic material in said slurry to a temperature above 200° C. in the presence of a homogeneous

1. A method for converting an organic material feed into a hydrocarbon fuel product, comprising the steps of: pressurizing said organic material being in a slurry to a pressure above 225 bar,heating said organic material in said slurry to a temperature above 200° C. in the presence of a homogeneous catalyst comprising a compound of at least one element of group IA of the periodic table of elements, wherein the method further comprises the steps of: contacting said organic material in said slurry with a heterogeneous catalyst in a reactor, the heterogeneous catalyst comprising a compound of at least one element of group IVB of the periodic table and/or alpha-alumina assuring that said slurry has initially a pH value of above 7, and maintaining the pH value of said slurry containing said organic material in the range 7-14 and,re-circulating at least a part of the slurry exiting the reactor by mixing it into the slurry comprising organic material prior to this entering the reactor, and wherein the concentration of said organic material is at least 5% by weight, the conversion of said organic material is at least 90%, and said hydrocarbon fuel product comprises an oil with at least 50% of the feed carbon content,pre-treating the slurry at a pressure of 4-15 bar at the temperature of 100-170° C. for a period of 0.5-2 hours, and wherein the step of pre-treating comprises the step of adding additives to the slurry comprising said organic material, and wherein the step of pre-treating comprises the step of adjusting the pH of said slurry comprising said organic material to above 7. 2. The method according to claim 1, wherein at least 50% of the energy content in the feed is recovered in said hydrocarbon oil product. 3. The method according to claim 1, further comprising a second step of heating the slurry comprising the organic material before contacting the slurry with the heterogeneous catalyst. 4. The method according to claim 3, further comprising a step of separating fuel gas from the slurry, wherein the fuel gas is used for heating the slurry in the second heating step. 5. The method according to claim 1, further comprising separating particles from the slurry comprising the organic material. 6. The method according to claim 1, further comprising a first step of cooling the slurry, performed by heat exchanging with the step of heating and/or a step of pre-heating the slurry in the pre-treating step. 7. The method according to claim 1, wherein the step of contacting the organic material in the slurry with a heterogeneous catalyst is performed while the temperature is kept substantially constant, and wherein the temperature in the step of contacting is in the range 250-374 degrees Celsius, and wherein the pressure is in the range 225-350 bars. 8. The method according to claim 1, wherein the step of contacting is done in less than 10 minutes. 9. The method according to claim 1, wherein the compound of at least one element of group IVB of the periodic table comprises zirconium and/or titanium on an oxide and/or hydroxide form or a combination of the two. 10. The method according to claim 1, wherein the heterogeneous catalyst further comprises at least one element selected from the group consisting of Fe, Ni, Co, Cu, Cr, W, Mn, Mo, V, Sn, Zn, Si in an amount up to 20% by weight and wherein these elements are on an oxide and/or hydroxide form. 11. The method according to claim 10, wherein said amount is up to 10% by weight, an amount up to 5% by weight, or an amount up to 2.5% by weight. 12. The method according to claim 1, comprising the step of re-circulating a slurry containing hydrogen, and wherein the hydrogen content of said slurry corresponds to at least 0.001% by weight of the amount of said organic material to be treated. 13. The method according to claim 1, wherein the homogeneous catalyst comprises potassium and/or sodium and wherein the homogeneous catalyst comprises one or more water soluble salts selected from the group consisting of KOH, K2CO3, KHCO3, NaOH, Na2CO3 or NaHCO3 or a combination thereof, and wherein the concentration of the homogeneous catalyst is at least 0.5% by weight. 14. The method according to claim 1, wherein said slurry comprises water in a concentration of at least 30% by weight. 15. The method according to claim 1, wherein at least one carbonate and/or at least one hydrogen carbonate and/or at least one alcohol and/or at least one carboxylic acid and/or at least one aldehyde and/or at least one ketone is at least partly produced by the conversion of said organic material, and wherein said at least one carbonate and/or at least one hydrogen carbonate and/or at least one alcohol and/or at least one carboxylic acid and/or at least one aldehyde and/or at least one ketone is re-circulated after the step of contacting. 16. The method according to claim 15, wherein at least part of a stream of said re-circulation is mixed in a ratio with a feed stream of said slurry comprising said homogeneous catalyst and organic material to be converted before entering the catalytic reactor. 17. The method according to claim 16, wherein the ratio of the re-circulating stream to the feed stream of said slurry is in the range 1-20 by volume. 18. The method according to claim 17, wherein the ratio of the re-circulating stream to the feed stream of said fluid is in the range 1-10, 1.5-7.5, 2-6, or 2.5-5 by volume. 19. The method according to claim 1, wherein said organic material is selected from the group consisting of sludge, sewage sludge, liquid manure, corn silage, clarifier sludge, black liquor, residues from fermentation, residues from juice production, residues from edible oil production, residues from fruit and vegetable processing, residues from food and drink production, leachate or seepage water or a combination thereof, and wherein said sludge is sludge from a biological treatment process. 20. The method according to claim 1, wherein said organic material is sludge from a waste water treatment process. 21. The method according to claim 1, wherein said organic material comprise a mixture of sludge, lidnocellulosic materials or waste. 22. The method according to claim 1, wherein the recirculation comprises mixing at least a part of the slurry exiting the reactor into the slurry comprising organic material after or during said pressurizing and heating of the slurry. 23. The method according to claim 22, wherein said heating is at least partly performed in a first heating unit, and wherein the at least a part of the slurry exiting the reactor is mixed into the slurry comprising organic material at a point situated after said first heating unit in the feeding direction. 24. The method according to claim 1, wherein the recirculation comprises mixing at least a part of the slurry exiting the reactor into the slurry comprising organic material prior to the completion of said pressurizing and heating of the slurry. 25. The method according to claim 24, wherein the at least a part of the slurry exiting the reactor is a fluid stream separated from the fluid exiting the reactor in a product recovery system (11), and wherein the fluid stream is mixed into the slurry comprising organic material during a pre-treatment of the organic material.