IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
|
출원번호 |
US-0587358
(2009-10-06)
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등록번호 |
US-8383861
(2013-02-26)
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발명자
/ 주소 |
- Do, David
- Domke, Christopher H.
- Lopez-Toledo, Jacinto
- Petraitis, David M.
- Srnak, Thomas Z.
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출원인 / 주소 |
- Dow Global Technologies LLC
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인용정보 |
피인용 횟수 :
3 인용 특허 :
73 |
초록
▼
The present invention relates to processes for the manufacture of one or more ethanolamines and one or more ethyleneamines starting from the reaction of ethylene oxide with ammonia to produce one or more ethanolamines and the conversion of the ethanolamine(s) to ethyleneamine(s). The present inventi
The present invention relates to processes for the manufacture of one or more ethanolamines and one or more ethyleneamines starting from the reaction of ethylene oxide with ammonia to produce one or more ethanolamines and the conversion of the ethanolamine(s) to ethyleneamine(s). The present invention also relates to separating alkylethyleneamines from ethyleneamines.
대표청구항
▼
1. A process for the manufacture of one or more ethanolamines and one or more ethyleneamines comprising the steps of: a) combining ethylene oxide with ammonia;b) a first reacting step comprising reacting ethylene oxide with ammonia in a manner to produce one or more ethanolamines, wherein said first
1. A process for the manufacture of one or more ethanolamines and one or more ethyleneamines comprising the steps of: a) combining ethylene oxide with ammonia;b) a first reacting step comprising reacting ethylene oxide with ammonia in a manner to produce one or more ethanolamines, wherein said first reacting step forms a first effluent comprising: i) unreacted ammonia; andii) the one or more ethanolamines;c) a second reacting step comprising reacting at least a portion of the first effluent in the presence of a reductive amination catalyst to produce one or more ethyleneamines, wherein said second reacting step forms a second effluent comprising: i) unreacted ammonia;ii) one or more alkylamines, wherein the one or more alkylamines are chosen from methylamine, ethylamine, and combinations thereof;iii) one or more unreacted ethanolamines; andiv) the one or more ethyleneamines;d) separating the unreacted ammonia and one or more alkylamines from the second effluent;e) separating the unreacted ammonia from the one or more alkylamines; andf) after separating the unreacted ammonia from the one or more alkylamines, recycling the unreacted ammonia so as to be combined with the ethylene oxide in the step of combining ethylene oxide with ammonia. 2. The process of claim 1, wherein the second reacting step comprises reacting all of the first effluent in the presence of a reductive amination catalyst to produce one or more ethyleneamines. 3. The process of claim 1, further comprising the step of, after the step of separating the unreacted ammonia and one or more alkylamines from the second effluent, removing water from the second effluent. 4. The process of claim 1, wherein the one or more ethanolamines are selected from the group consisting of: monoethanolamine, diethanolamine, triethanolamine, and combinat ions thereof, and wherein the one or more ethyleneamines are selected from the group consisting of: ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, piperazine, aminoethylpiperazine, aminoethylethanolamine, heavy polyamine, and combinations thereof. 5. The process of claim 1, wherein the ammonia in the step of reacting ethylene oxide with ammonia is anhydrous ammonia. 6. The process of claim 1, wherein the ammonia in the step of reacting ethylene oxide with ammonia is in solution with water, wherein the water is present in an amount of five percent by weight of ammonia and water or less. 7. The process of claim 1, wherein after the step of separating the unreacted ammonia from the one or more alkylamines, the amount of alkylamines present in the stream of unreacted ammonia is less than 100 parts per million by weight. 8. The process of claim 1, wherein after the step of separating the unreacted ammonia from the one or more alkylamines, the amount of alkylamines present in the stream of unreacted ammonia is less than 50 parts per million by weight. 9. A process for the manufacture of one or more ethanolamines and one or more ethyleneamines comprising the steps of: a) combining ethylene oxide with ammonia;b) a first reacting step comprising reacting ethylene oxide with ammonia in a manner to produce one or more ethanolamines, wherein said first reacting step forms a first effluent comprising: i) unreacted ammonia; andii) the one or more ethanolamines;c) separating at least a portion of the unreacted ammonia from the first effluent;d) after separating the at least a portion of the unreacted ammonia from the first effluent, recycling the unreacted ammonia so as to be combined with the ethylene oxide in the step of combining ethylene oxide with ammonia;e) a second reacting step comprising reacting one or more ethanolamines made in the first reacting step and ammonia in the presence of a reductive amination catalyst to produce one or more ethyleneamines, wherein said second reacting step forms a second effluent comprising: i) unreacted ammonia;ii) one or more alkylamines, wherein the one or more alkylamines are chosen from methylamine, ethylamine, and combinations thereof;iii) one or more unreacted ethanolamines; andiv) the one or more ethyleneamines;f) separating at least a portion of the unreacted ammonia and at least a portion of the one or more alkylamines from the second effluent; andg) after separating the unreacted ammonia and at least a portion of the one or more alkylamines from the second effluent, recycling the unreacted ammonia and the at least a portion of the one or more alkylamines so as to be combined with the one or more ethanolamines and ammonia in the second reacting step. 10. The process of claim 9, wherein the one or more ethanolamines comprise at least monoethanolamine. 11. The process of claim 9, wherein the one or more ethanolamines consist essentially of mono ethanolamine. 12. The process of claim 9, further comprising the steps of: a) after separating the at least a portion of the unreacted ammonia from the first effluent and after separating the unreacted ammonia and at least a portion of the one or more alkylamines from the second effluent, combining the first and second effluents to form a third effluent;b) separating unreacted ammonia from the third effluent; andc) after separating unreacted ammonia from the third effluent, recycling the unreacted ammonia in a manner so as to be combined with the ammonia in the second reacting step. 13. The process of claim 12, further comprising the step of, after the unreacted ammonia is separated from the third effluent, removing water from the third effluent. 14. The process of claim 13, further comprising the steps of, after the water is removed from the third effluent: a) separating the one or more ethanolamines and one or more ethyleneamines from the third effluent into individual components; andb) recycling at least a portion of the monoethanolamine so as to combine the monoethanolamine with ammonia in the step of reacting the monoethanolamine with at least a portion of the unreacted ammonia in the presence of a reductive amination catalyst to produce one or more ethyleneamines. 15. A process for the manufacture of one or more ethanolamines and one or more ethyleneamines comprising the steps of: a) combining ethylene oxide with ammonia;b) a first reacting step comprising reacting ethylene oxide with ammonia in a manner to produce one or more ethanolamines, wherein said first reacting step forms a first effluent comprising: i) unreacted ammonia; andii) the one or more ethanolamines;c) separating at least a portion of the unreacted ammonia from the first effluent so as to form a second effluent;d) after separating the at least a portion of the unreacted ammonia from the first effluent, recycling the unreacted ammonia so as to be combined with the ethylene oxide in the step of combining ethylene oxide with ammonia;e) a second reacting step comprising reacting at least a portion of the second effluent in the presence of a reductive amination catalyst to produce one or more ethyleneamines, wherein said second reacting step forms a third effluent comprising: i) unreacted ammonia;ii) one or more alkylamines, wherein the one or more alkylamines are chosen from methylamine, ethylamine, and combinations thereof;iii) one or more unreacted ethanolamines; andiv) the one or more ethyleneaminesf) separating the unreacted ammonia and at least a portion of the one or more alkylamines from the third effluent;g) after separating the unreacted ammonia and at least a portion of the one or more alkylamines from the third effluent, recycling the unreacted ammonia and the at least a portion of the one or more alkylamines so as to be combined with the second effluent. 16. The process of claim 15, wherein the second effluent in the second reacting step comprises one or more ethanolamines comprising at least monoethanolamine. 17. The process of claim 15, wherein the second effluent in the second reacting step comprises an ethanolamine consisting essentially of monoethanolamine. 18. The process of claim 15, wherein the step of separating at least a portion of the unreacted ammonia from the first effluent comprises separating the first effluent into at least three compositions comprising: a) a first composition comprising the at least a portion of the unreacted ammonia, wherein said unreacted ammonia is recycled so as to be combined with the ethylene oxide in the step of combining ethylene oxide with ammonia;b) a second composition comprising at least a portion of the unreacted ammonia and monoethanolamine, wherein said monoethanolamine and ammonia are reacted in the presence of a reductive amination catalyst to produce one or more ethyleneamines; andc) a third composition comprising monoethanolamine, diethanolamine, and triethanolamine. 19. The process of claim 18, wherein the step of separating the first effluent into at least three compositions comprises introducing the first effluent into an inter-reactor separator in a manner so as to form the at least three compositions.
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