A polyester composition containing: a) aluminum atoms; andb) alkaline earth atoms or alkali metal atoms or alkali compound residues such as lithium atoms; andc) particles comprising titanium, zirconium, vanadium, niobium, hafnium, tantalum, chromium, tungsten, molybdenum, iron, or nickel atoms or co
A polyester composition containing: a) aluminum atoms; andb) alkaline earth atoms or alkali metal atoms or alkali compound residues such as lithium atoms; andc) particles comprising titanium, zirconium, vanadium, niobium, hafnium, tantalum, chromium, tungsten, molybdenum, iron, or nickel atoms or combinations thereof, where the particles improve the reheat rate of the polyester composition. The polyester polymer compositions may also contain phosphorus catalyst deactivators/stabilizers. The polyester compositions and the articles made from the compositions such as bottle preforms and stretch blow molded bottles have improved reheat rate while maintaining low haze, high L*, a b* below 3, and have low levels of acetaldehyde. In the process for making the polyester polymer, the polymer melt is polycondensed in the presence of a) and b), with the particles c) added in a melt phase process or added to the polymer in an injection molding machine or extruder. The polyester polymer composition can be made to high IV from the melt phase while avoiding solid state polymerization.
대표청구항▼
1. A polyester composition comprising a polyester polymer and: a) aluminum atoms;b) lithium atoms;c) phosphorus atoms, wherein the amount of the phosphorus atoms ranges from 30 ppm to 400 ppm, based on the weight of the polyester polymer; andd) particles comprising titanium nitride, said particles i
1. A polyester composition comprising a polyester polymer and: a) aluminum atoms;b) lithium atoms;c) phosphorus atoms, wherein the amount of the phosphorus atoms ranges from 30 ppm to 400 ppm, based on the weight of the polyester polymer; andd) particles comprising titanium nitride, said particles improving the reheat rate of the polyester composition, wherein the polyester composition has an L* value of 70 or more as measured on a twenty ounce bottle preform having a nominal sidewall cross-sectional thickness of 0.154 inches. 2. The polyester composition of claim 1, wherein the particles further comprise at least one metal selected from the group consisting of a titanium atom, a zirconium atom, a vanadium atom, a niobium atom, a hafnium atom, a tantalum atom, a chromium atom, a tungsten atom, a molybdenum atom, an iron atom, and a nickel atom. 3. The polyester composition of claim 2, wherein the particles have a median particle size ranging from 1 nm to about 500 nm. 4. The polyester composition of claim 3, wherein the particles are present in an amount ranging from 1 ppm to 50 ppm, with respect to the total weight of the polyester composition. 5. The polyester composition of claim 1, wherein the polyester composition is in the form of a beverage bottle preform. 6. The polyester composition of claim 5, wherein the beverage bottle preform has a reheat improvement temperature (RIT) of at least 5° C., a preform L* value of 70 or more, and a b* value ranging from −8 to +5. 7. The polyester composition of claim 1, wherein the particles comprise the titanium nitride having an empirical formula ranging from TiN0.42 to about TiN1.16. 8. The polyester composition of claim 1, wherein the particles comprise the titanium nitride in an amount of at least 90 wt. %, with respect to the total weight of the particles. 9. The polyester composition of claim 1, wherein the particles have a particle size distribution with a span (S) ranging from 0.01 to 2. 10. The polyester composition of claim 1, wherein the polyester polymer is obtained by reacting an acid component comprising at least 85 mole % of terephthalic acid, naphthalenic acid, or at least one C1-C4 dialkyl ester thereof,with a diol component comprising at least 90 mole % ethylene glycol,based on a mole percentage for all acid components totaling 100 mole %, and the mole percentage for all diol components totaling 100 mole %. 11. The polyester composition of claim 10, wherein the acid component further comprises isophthalic acid, cyclohexanedicarboxylic acid, naphthalene-2,6-dicarboxylic acid, or a combination thereof, in an amount of greater than zero to less than 15 mole %. 12. The polyester composition of claim 10, wherein the diol component further comprises diethylene glycol, 1,4-cyclohexanedimethanol, or a combination thereof, in an amount of greater than zero to less than 10 mole %. 13. The polyester composition of claim 1, wherein the particles do not cause an increase in the It.V. of the polyester polymer during its manufacture of more than 0.10 dL/g. 14. The polyester composition of claim 1, wherein the particles are coated with a layer of metal oxide. 15. The polyester composition of claim 1, wherein the titanium nitride comprises relative amounts of titanium, carbon, and nitrogen corresponding to the formula TiaCxNy,whereina ranges from 1-2,x ranges from 0.0 to 0.8, andy ranges from 0.1 to 1.0. 16. The polyester composition of claim 1, wherein the particles have a median particle size ranging from 0.001 μm to 5 μm. 17. The polyester composition of claim 1, wherein the particles have a mean particle size ranging from 5 nanometers to 60 nanometers. 18. The polyester composition of claim 17, wherein the amount of particles comprising titanium nitride ranges from 1 ppm to 20 ppm based on the titanium atoms relative to the weight of the polyester polymer. 19. The polyester composition of claim 1, wherein the polyester composition is in the form of a bottle preform having a final reheat temperature of at least 110° C. 20. The polyester composition of claim 1, wherein the amount of aluminum atoms ranges from 10 ppm to 100 ppm based on the weight of the polyester polymer. 21. The polyester composition of claim 20, wherein the aluminum atoms are derived from an aluminum organic compound. 22. The polyester composition of claim 21, wherein the aluminum organic compound has a formula Al[OR]a[OR′]b[OR″]c[R′″]d,whereinR, R′, R″ are independently an alkyl group, aryl group, acyl group, or hydrogen,R′″ is an anionic group,a, b, c, d are independently 0 or positive integers, anda+b+c+d is no greater than 4. 23. The polyester composition of claim 21, wherein the aluminum organic compound is at least one selected from the group consisting of a carboxylic acid salt of aluminum, an aluminum alcoholate, an aluminum hydroxide, an aluminum halide, and an aluminum hydroxyhalide. 24. The polyester composition of claim 1, wherein the lithium atoms are derived from at least one lithium salt or complex comprising a counterion of a hydroxide, an amine, an amine derivative, a carbonate, or a halide. 25. The polyester composition of claim 1, wherein the amount of the lithium atoms in the polyester polymer ranges from 4 ppm to 250 ppm, based on the weight of the polyester polymer. 26. The polyester composition of claim 25, wherein the amount of the lithium atoms ranges from 25 ppm to 100 ppm, based on the weight of the polyester polymer. 27. The polyester composition of claim 1, wherein the molar ratio of the lithium atoms:aluminum atoms ranges from 1:1 to 5:1. 28. The polyester composition of claim 1, wherein the quantity of phosphorus atoms ranges from 75 ppm to 300 ppm. 29. The polyester composition of claim 1, wherein the molar ratio of the phosphorus atoms to the total of the aluminum atoms, and the lithium atoms, measured as the number of metal atoms, ranges from 0.5:1 to 3:1. 30. The polyester composition of claim 1, wherein the It.V. of the polyester polymer obtained from a melt phase polymerization reaction is at least 0.72 dL/g. 31. The polyester composition of claim 1, wherein the polyester polymer is partially crystallized to a degree of at least 30 percent. 32. The polyester composition of claim 1, wherein the polyester composition has an acetaldehyde generation rate of less than 15 ppm. 33. The polyester composition of claim 1, wherein the lithium atoms are derived from a lithium compound and the lithium atoms are present in an amount ranging from 10 ppm to 50 ppm, wherein the aluminum atoms are present in an amount ranging from 10 ppm to 50 ppm and the aluminum atoms are derived from an aluminum compound, andwherein the particles have a median particle size ranging from 5 nm to 60 nm and the particles are present in an amount ranging from of 5 ppm to 50 ppm based on the titanium atoms,each as based on the weight of the polyester polymer. 34. The polyester composition of claim 33, wherein the phosphorus atoms are present in an amount ranging from 100 ppm to 250 ppm and the polyester composition has an acetaldehyde generation rate of less than 15 ppm. 35. A bottle preform made from the polyester composition of claim 34, having a b* of less than 3.0. 36. A polyester composition, comprising: a polyester polymer obtained by adding particles comprising titanium nitride to a melt phase process for manufacturing the polyester polymer or at any time thereafter,wherein the polyester polymer is obtained by polycondensing a polyester polymer melt in the presence of aluminum atoms, lithium atoms, and phosphorus atoms,wherein the amount of the phosphorus atoms ranges from 30 ppm to 400 ppm, based on the weight of the polyester polymer,wherein the polyester composition has an L* value of 70 or more as measured on a twenty ounce bottle preform having a nominal sidewall cross-sectional thickness of 0.154 inches. 37. The polyester composition of claim 36, wherein the particles have a median size ranging from 1 nm to 500 nm. 38. The polyester composition of claim 36, wherein the amount of particles present in the polyester composition ranges from 5 ppm to 50 ppm based on the titanium atoms, wherein the particles present in the polyester composition have a median particle size ranging from 0.001 μm to 5 μm, andwherein the aluminum atoms are present in an amount ranging from 4 ppm to 100 ppm. 39. The polyester composition of claim 36, wherein the It.V. of the polyester polymer obtained from the polycondensing is at least 0.72 dL/g. 40. The polyester composition of claim 36, wherein the aluminum atoms are added to the melt phase process before the It.V. of the polyester polymer has reached 0.3 dL/g. 41. The polyester composition of claim 36, wherein the particles are added to the polyester polymer melt in the melt phase process after the It.V. of the polyester polymer melt has reached 0.45 dL/g. 42. The polyester composition of claim 36, wherein the particles are added to the melt phase process at a point proximate to an outlet of a final polycondensation reactor and any point thereafter up to a die for solidifying the polyester melt, or at any point after solidification of the polyester polymer made in the melt phase process. 43. The polyester composition of claim 36, wherein the aluminum atoms are added to the melt phase process as a stream separate from a stream containing the lithium atoms. 44. The polyester composition of claim 36, wherein the aluminum atoms are added to the melt phase process as a liquid solution or dispersion, wherein the aluminum atoms are obtained from at least one aluminum compound selected from the group consisting of a carboxylic acid salt of aluminum, an aluminum alcoholate, an aluminum hydroxide, an aluminum halide, and an aluminum hydroxyhalide. 45. The polyester composition of claim 36, wherein the lithium atoms are added as a liquid stream to the melt phase process, wherein the lithium atoms are obtained from at least one lithium salt or complex comprising a counterion of a hydroxide, an amine, an amine derivative, a carbonate, or a halide. 46. The polyester composition of claim 1, wherein the polyester polymer is obtained in a direct esterification process. 47. The polyester composition of claim 36, wherein the polyester polymer is made in the absence of added titanium-containing catalysts. 48. The polyester composition of claim 36, wherein the polyester polymer is made in the absence of added antimony containing catalysts. 49. The polyester composition of claim 36, wherein the lithium atoms are added to a diol feed to an esterification reactor. 50. The polyester composition of claim 36, wherein the lithium atoms are added before 50% conversion of an esterification reaction mixture. 51. The polyester composition of claim 36, wherein the lithium atoms are added between an esterification and a polycondensation zone. 52. The polyester composition of claim 36, wherein the aluminum atoms are added to the polyester polymer melt before the It.V. of the polyester polymer melt reaches 0.3 dL/g. 53. The polyester composition of claim 36, wherein the polyester polymer is made in the absence of titanium containing catalysts, cobalt containing catalysts, and antimony containing catalysts, used to increase the It.V. of the polyester polymer in the melt phase by more than 0.1 dL/g. 54. The polyester composition of claim 53, wherein the polyester polymer is made without the addition of any metal containing catalyst to the melt phase process other than the aluminum atoms and the lithium atoms. 55. The polyester composition of claim 36, wherein the phosphorus atoms are obtained from at least one acidic phosphorus compound or at least one acidic phosphorus ester derivative. 56. The polyester composition of claim 36, wherein the phosphorus atoms are derived from one or more phosphorus containing compounds selected from the group consisting of phosphoric acid, phosphorus acid, polyphosphoric acid, a carboxyphosphonic acid, a phosphonic acid derivative, an acidic salt of any of these, an acidic ester of any of these, and a derivative of any of these. 57. The polyester composition of claim 56, wherein the phosphorus containing compounds are one or more selected from the group consisting of an oligomeric phosphate tri-ester, (tris)ethylene glycol phosphate, a tri-ester of phosphoric acid with ethylene glycol, diethylene glycol, and mixtures of each. 58. The polyester composition of claim 36, wherein the amount of phosphorus atoms is at least 50 ppm. 59. The polyester composition of claim 58, wherein the amount of phosphorus atoms ranges from 75 ppm up to 300 ppm. 60. The polyester composition of claim 36, wherein the molar ratio of the phosphorus atoms to the total of the aluminum atoms and the lithium atoms ranges from 0.3:1 to 5:1. 61. The polyester composition of claim 60, wherein the molar ratio of the phosphorus atoms to the total of the aluminum atoms and the lithium atoms ranges from 0.5:1 to 3:1. 62. The polyester composition of claim 36, wherein the phosphorus atoms are added to the polyester melt when one or more of the following conditions are satisfied or thereafter and before solidification of the polyester melt: a) the polyester polymer melt reaches an It.V. of at least 0.50 dL/g; orb) vacuum applied to the polyester polymer melt, if any, is released; orc) if the polyester polymer melt is present in a melt phase polymerization process, adding the phosphorus atoms within a final reactor for making the polyester polymer or between the final reactor and before a cutter for cutting the polyester polymer melt; ord) if the polyester polymer melt is present in a melt phase polymerization process, following at least 85% of the time for polycondensing the polyester polymer melt; ore) the It.V. of the polyester polymer melt is within +/−0.15 dL/g of the It.V. obtained upon solidification; orf) at a point within 20 minutes or less of solidifying the polyester polymer melt. 63. The polyester composition of claim 62, wherein the phosphorus atoms are added to the polyester polymer melt after the polyester polymer melt obtains an It.V. of at least 0.72 dL/g. 64. The polyester composition of claim 62, wherein the phosphorus atoms are added to the polyester polymer melt immediately before or after bringing the pressure within a final polycondensation reactor to a level of 300 mmHg or greater. 65. The polyester composition of claim 62, wherein the phosphorus atoms are added at a location near or at the end of the final reactor or between the final reactor and before a cutter for cutting the polyester polymer melt. 66. The polyester composition of claim 62, wherein the phosphorus atoms are added to the polyester polymer melt following at least 90% of the polycondensation time. 67. The polyester composition of claim 62, wherein the phosphorus atoms are added to the polyester polymer melt when the It.V. of the polyester polymer melt is within 0.05 dL/g of the It.V. obtained upon solidification. 68. The polyester composition of claim 62, wherein the phosphorus atoms are added to the polyester polymer melt at a point within 5 minutes or less of solidifying the polyester polymer melt. 69. The polyester composition of claim 36, wherein the polyester polymer is made in a continuous manufacturing process where the throughput of the melt phase process is at least 50 tons/day. 70. The polyester composition of claim 36, wherein a reaction time of the polyester polymer melt from an It.V. of 0.40 dL/g through and up to a final It.V. obtained in the melt phase process is 80 minutes or less. 71. The polyester composition of claim 36, wherein the polyester polymer has an It.V. of at least 0.72 dL/g obtained in the melt phase process. 72. The polyester composition of claim 36, wherein the polyester composition has an L* value of at least 73. 73. The polyester composition of claim 36, wherein organic acetaldehyde scavengers are not added to the melt phase process for making the polyester polymer. 74. A bulk of pellets, comprising the polyester composition of claim 36 in a shipping container. 75. A post consumer recycle polyester polymer, comprising the polyester composition of claim 36. 76. A bottle preform comprising the polyester composition of claim 36, having a b* ranging from −8.6 to 3.0 or less. 77. The bottle preform of claim 76, having an RIT of 5° C. or more. 78. The polyester composition of claim 36, wherein the lithium atoms are present in an amount ranging from 10 ppm to 50 ppm, wherein the aluminum atoms are present in an amount ranging from 10 ppm to 50 ppm, andwherein the particles comprising titanium nitride have a median particle size ranging from 5 nm to 60 nm and are present in amount ranging from 5 ppm to 50 ppm based on the titanium atoms,each based on the weight of the polyester polymer. 79. The polyester composition of claim 78, wherein the amount of phosphorus atoms ranges from 75 ppm to 170 ppm, based on the weight of the polyester polymer. 80. The polyester composition of claim 79, wherein the phosphorus atoms are added at the completion of the polycondensing or thereafter. 81. The polyester composition of claim 36, wherein the particles further comprise atoms of tungsten or molybdenum. 82. The polyester composition of claim 1, wherein the particles further comprise a transition metal compound comprising at least one boron atom,a transition metal compound comprising at least one carbon atom, ora transition metal compound comprising nitrogen. 83. The polyester composition of claim 2, wherein the particles further comprise a transition metal compound comprising at least one boron atom,a transition metal compound comprising at least one carbon atom, ora transition metal compound comprising nitrogen. 84. The polyester composition of claim 1, wherein the polyester composition has an L* value of at least 73. 85. The polyester composition of claim 1, comprising no added antimony containing catalysts. 86. The polyester composition of claim 36, comprising no added antimony containing catalysts. 87. The polyester composition of claim 1, comprising no added titanium containing catalysts, no added cobalt containing catalysts, and no added antimony containing catalysts. 88. The polyester composition of claim 36, comprising no added titanium containing catalysts, no added cobalt containing catalysts, and no added antimony containing catalysts. 89. The polyester composition of claim 1, comprising no added metal containing catalyst other than the aluminum atoms and the lithium atoms. 90. The polyester composition of claim 36, comprising no added metal containing catalyst other than the aluminum atoms and the lithium atoms. 91. The polyester composition of claim 1, wherein the amount of the lithium atoms ranges from 40 ppm to 100 ppm, based on the weight of the polyester polymer. 92. The polyester composition of claim 36, wherein the amount of the lithium atoms ranges from 40 ppm to 100 ppm, based on the weight of the polyester polymer. 93. The polyester composition of claim 1, wherein L* is at least 75. 94. The polyester composition of claim 36, wherein L* is at least 75. 95. The polyester composition of claim 1, wherein L* is at least 78. 96. The polyester composition of claim 36, wherein L* is at least 78. 97. The polyester composition of claim 1, wherein L* is at least 79.18. 98. The polyester composition of claim 36, wherein L* is at least 79.18. 99. The polyester composition of claim 1, wherein L* is at least 80. 100. The polyester composition of claim 36, wherein L* is at least 80. 101. The polyester composition of claim 1, wherein L* is at least 85. 102. The polyester composition of claim 36, wherein L* is at least 85. 103. The polyester composition of claim 1, wherein the particles are present in an amount ranging from 10 ppm to 100 ppm. 104. The polyester composition of claim 36, wherein the particles are present in an amount ranging from 10 ppm to 100 ppm. 105. The polyester composition of claim 1, wherein the particles are present in an amount ranging from 15 ppm to 100 ppm. 106. The polyester composition of claim 36, wherein the particles are present in an amount ranging from 15 ppm to 100 ppm. 107. The polyester composition of claim 1, wherein the particles are present in an amount ranging from 20 ppm to 100 ppm. 108. The polyester composition of claim 36, wherein the particles are present in an amount ranging from 20 ppm to 100 ppm. 109. The polyester composition of claim 1, wherein the particles are present in an amount ranging from 25 ppm to 100 ppm. 110. The polyester composition of claim 36, wherein the particles are present in an amount ranging from 25 ppm to 100 ppm. 111. The polyester composition of claim 72, wherein the particles are present in an amount ranging from 10 ppm to 100 ppm. 112. The polyester composition of claim 84, wherein the particles are present in an amount ranging from 10 ppm to 100 ppm. 113. The polyester composition of claim 72, wherein the particles are present in an amount ranging from 15 ppm to 100 ppm. 114. The polyester composition of claim 84, wherein the particles are present in an amount ranging from 15 ppm to 100 ppm. 115. The polyester composition of claim 72, wherein the particles are present in an amount ranging from 20 ppm to 100 ppm. 116. The polyester composition of claim 84, wherein the particles are present in an amount ranging from 20 ppm to 100 ppm. 117. The polyester composition of claim 72, wherein the particles are present in an amount ranging from 25 ppm to 100 ppm. 118. The polyester composition of claim 84, wherein the particles are present in an amount ranging from 25 ppm to 100 ppm.
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