The ceramic product provided by the present invention is provided with at least two ceramic members bonded to each other, and the bond parts between these ceramic members bonded to each other are formed from glass having leucite crystals precipitated within the glass matrix.
대표청구항▼
1. A ceramic product, comprising an oxygen separation membrane made of an oxide ceramic with a perovskite structure which is an oxygen ion conductor,at least one ceramic connecting member bonded to the oxygen separation membrane, anda bond part between the oxygen separation membrane and the connecti
1. A ceramic product, comprising an oxygen separation membrane made of an oxide ceramic with a perovskite structure which is an oxygen ion conductor,at least one ceramic connecting member bonded to the oxygen separation membrane, anda bond part between the oxygen separation membrane and the connecting member, whereinboth the oxygen separation membrane and the connecting member are formed of perovskite structured oxide ceramic having a perovskite structure of a composition represented by the general formula: Ln1-xAexMO3 (wherein Ln is at least one selected from lanthanoids, Ae is at least one selected from the group consisting of Sr, Ca and Ba, M is at least one selected from the group consisting of Mg, Mn, Ga, Ti, Co, Ni, Al, Fe, Cu, In, Sn, Zr, V, Cr, Zn, Ge, Sc and Y, and 0≦x≦1), the bond part is formed from a crystalline-amorphous composite material, wherein the crystalline-amorphous composite material is composed of a glass matrix and leucite crystals precipitated in a dispersed state in the glass matrix, andthe bond part is formed of the following oxide components in the following mass ratios as oxides:SiO2 about 50 to 75 mass %;Al2O3 10 to 20 mass %;Na2O 5 to 20 mass %;K2O 5 to 20 mass %;MgO 3 mass % or less; andCaO 3 mass % or less, and wherein a thermal expansion coefficient of the bond part is 10 to 14×10−6 K−1. 2. The ceramic product according to claim 1, further comprising a porous substrate, wherein the oxygen separation membrane is formed on the substrate. 3. The ceramic product according to claim 1, wherein the perovskite-structured oxide ceramic is represented by the general formula: Ln1-xAexMO3 (wherein Ln is at least one selected from lanthanoids, Ae is at least one selected from the group consisting of Sr, Ca and Ba, M is at least one selected from the group consisting of Mg, Mn, Ga, Ti, Co, Ni, Al, Fe, Cu, In, Sn, Zr, V, Cr, Zn, Ge, Sc and Y, and 0
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이 특허에 인용된 특허 (9)
Zhou Hua-bing,JPX ; Taira Hiroaki,JPX, Complex oxide ceramic sintered body and solid-electrolyte fuel cell comprising the same.
Pierre Macaudiere FR; Thierry Seguelong FR, LaMO3 type composition, M being aluminium, gallium or indium, in powder or sintered form, method of preparation and use as conductor of oxygen.
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