The application provides a moderate fraction of a carbohydrate derived component having at least one C4+ compound (and kerosene fuel composition comprising same), the moderate fraction exhibiting a mean percentage of 99% or more biobased material, as determined by C14 testing, the moderate fraction
The application provides a moderate fraction of a carbohydrate derived component having at least one C4+ compound (and kerosene fuel composition comprising same), the moderate fraction exhibiting a mean percentage of 99% or more biobased material, as determined by C14 testing, the moderate fraction comprising: one or more substituted carbohydrate derived cycloalkanes comprising one or more substituent selected from the group consisting of branched C3-4 alkyls, straight chain C1-4 alkyls, branched C3-4 alkylenes, and straight chain C1-4 alkylenes; one or more carbohydrate derived aromatics, at least some of the carbohydrate derived aromatics comprising one or more substituent selected from the group consisting of branched C3-4 alkyls, straight chain C1-4 alkyls, branched C3-4 alkylenes, and, straight chain C2-4 alkylenes; and one or more carbohydrate derived compound selected from the group consisting of fused aryls, indane, indene, isomers thereof, and combinations thereof, at least some of the carbohydrate derived compound comprising one or more substituent selected from the group consisting of straight chain C1-4 alkyls and combinations thereof.
대표청구항▼
1. A moderate fraction of a carbohydrate derived component having at least one C4+ compound wherein: (a) the moderate fraction exhibits: a mean percentage of 99% or more biobased material, as determined by C14 testing;an initial boiling point in the range of from 120 to 215° C.;a final boiling point
1. A moderate fraction of a carbohydrate derived component having at least one C4+ compound wherein: (a) the moderate fraction exhibits: a mean percentage of 99% or more biobased material, as determined by C14 testing;an initial boiling point in the range of from 120 to 215° C.;a final boiling point of up to 320° C.;a density at 15° C. in the range of from 700 to 890 kg/m3; and,a sulfur content of at most 0.1% wt.; and,(b) the moderate fraction comprises: one or more substituted carbohydrate derived cycloalkanes comprising one or more substituent selected from the group consisting of branched C3-4 alkyls, straight chain C1-4 alkyls, branched C3-4 alkylenes, and straight chain C1-4 alkylenes;one or more carbohydrate derived aromatics, at least some of the carbohydrate derived aromatics comprising one or more substituent selected from the group consisting of branched C3-4 alkyls, straight chain C1-4 alkyls, branched C3-4 alkylenes, and, straight chain C2-4 alkylenes; andone or more carbohydrate derived compound selected from the group consisting of fused aryls, indane, indene, isomers thereof, and combinations thereof, at least some of the carbohydrate derived compound comprising one or more substituent selected from the group consisting of straight chain C1-4 alkyls and combinations thereof. 2. The moderate fraction of claim 1 further comprising one or more carbohydrate derived C4+ alkenes, at least some of the carbohydrate derived C4+ alkenes comprising one or more substituent selected from the group consisting of branched C3-4 alkyls, straight chain C1-4 alkyls, branched C3-4 alkylenes, and straight chain C2-4 alkylenes. 3. The moderate fraction of claim 1 made by a process comprising: (a) providing water and carbohydrate derived water-soluble oxygenated hydrocarbon comprising C1+O1+ hydrocarbon in an aqueous liquid phase and/or a vapor phase;(b) providing H2;(c) catalytically reacting in the liquid and/or vapor phase the carbohydrate derived water-soluble oxygenated hydrocarbon with the H2 in the presence of a deoxygenation catalyst at a deoxygenation temperature and deoxygenation pressure to produce carbohydrate derived oxygenate comprising C1+O1-3 hydrocarbon in a reaction stream; and(d) catalytically reacting in the liquid and/or vapor phase the carbohydrate derived oxygenate under condensation conditions comprising the presence of a condensation catalyst and a condensation temperature of 325° C. or higher, the condensation conditions being effective to produce the carbohydrate derived component having at least one C4+ compound; and,(e) separating the moderate fraction from the carbohydrate derived component. 4. The moderate fraction of claim 3 wherein the condensation conditions comprise a ZSM-5 zeolite type condensation catalyst. 5. The moderate fraction of claim 3 wherein the condensation catalyst is selected from the group consisting of an acid condensation catalyst and an acid-base condensation catalyst. 6. The moderate fraction of claim 4 wherein the condensation catalyst is selected from the group consisting of an acid condensation catalyst and an acid-base condensation catalyst. 7. The moderate fraction of claim 1 wherein the at least one C4+ compound comprises primarily compounds having from about 7 to about 14 carbon atoms. 8. The moderate fraction of claim 1 further comprising at least one different fuel component. 9. The moderate fraction of claim 2 further comprising at least one different fuel component. 10. A kerosene fuel composition comprising a moderate fraction of a carbohydrate derived component having at least one C4+ compound: the kerosene composition having a final boiling point of up to 320° C.;the moderate fraction:(a) exhibiting: a mean percentage of 99% or more biobased material, as determined by C14 testing;an initial boiling point in the range of from 120 to 215° C.;a final boiling point of up to 320° C.;a component density at 15° C. in the range of from 700 to 890 kg/m3; and,a component sulfur content of at most 0.1% wt.; and,(b) comprising: one or more substituted carbohydrate derived cycloalkane comprising one or more substituent selected from the group consisting of branched C3-4 alkyls, straight chain C1-4 alkyls, branched C3-4 alkylenes, and straight chain C1-4 alkylenes;one or more carbohydrate derived aromatics, at least some of the carbohydrate derived aromatics comprising one more substituent selected from the group consisting of branched C3-4 alkyls, straight chain C1-4 alkyls, branched C3-4 alkylenes, and, straight chain C2-4 alkylenes; andone or more carbohydrate derived compound selected from the group consisting of fused aryls, indane, indene, isomers thereof, and combinations thereof, at least some of the carbohydrate derived compound comprising one or more substituent selected from the group consisting of straight chain C1-4 alkyls and combinations thereof. 11. The kerosene fuel composition of claim 10 wherein the moderate fraction further comprises one or more carbohydrate derived C4+ alkenes, at least some of the carbohydrate derived C4+ alkenes comprising one or more substituent selected from the group consisting of branched C3-4 alkyls, straight chain C1-4 alkyls, branched C3-4 alkylenes, and straight chain C2-4 alkylenes. 12. The kerosene fuel composition of claim 10 wherein the at least one C4+ compound comprises primarily compounds having from about 7 to about 14 carbon atoms. 13. The kerosene fuel composition of claim 10 further comprising at least one different fuel component. 14. The kerosene fuel composition of claim 13 exhibiting a component freeze point of −40° C. or lower. 15. The kerosene fuel composition of claim 13 exhibiting a viscosity at −20° C. in the range of from 0.8 to 10 mm2/s (ASTM D445). 16. The kerosene fuel composition of claim 13 exhibiting a smoke point of at least 18 mm. 17. The kerosene fuel composition of claim 14 exhibiting a viscosity at −20° C. in the range of from 0.8 to 10 mm2/s (ASTM D445). 18. The kerosene fuel composition of claim 17 exhibiting a smoke point of at least 18 mm. 19. The kerosene fuel composition of claim 11 further comprising at least one different fuel component. 20. The kerosene fuel composition of claim 12 further comprising at least one different fuel component. 21. The kerosene fuel composition of claim 13 wherein the at least one different fuel component comprises synthetic paraffins having boiling points within the range of from 110 to 320° C. 22. The kerosene fuel composition of claim 21 wherein the at least one different fuel component is selected from the group consisting of a Fischer-Tropsch product and a synthetic paraffins derived from a synthesis product of a Fischer-Tropsch condensation process. 23. The kerosene fuel composition of claim 19 wherein the at least one different fuel component comprises synthetic paraffins having boiling points within the range of from 110 to 320° C. 24. The kerosene fuel composition of claim 23 wherein the at least one different fuel component is selected from the group consisting of a Fischer-Tropsch product and a synthetic paraffins derived from a synthesis product of a Fischer-Tropsch condensation process. 25. The kerosene fuel composition of claim 20 wherein the at least one different fuel component is a synthetic paraffin comprising components having boiling points within the range of from 110 to 320° C. 26. The kerosene fuel composition of claim 25 the at least one different fuel component is selected from the group consisting of a Fischer-Tropsch product or a synthetic paraffin derived from a synthesis product of a Fischer-Tropsch condensation process. 27. The kerosene fuel composition of claim 13 further comprising one or more additive selected from the group consisting of antioxidant, anti-static agents, and metal deactivators, and combinations thereof. 28. The kerosene fuel composition of claim 13 comprising one or more antioxidant. 29. The kerosene fuel composition of claim 28 comprising t-butyl phenol antioxidant. 30. The kerosene fuel composition of claim 13 comprising one or more anti-static agent. 31. The kerosene fuel composition of claim 13 comprising one or more metal deactivator. 32. The kerosene fuel composition of claim 13 wherein the moderate fraction is made by a process comprising: (a) providing water and carbohydrate derived water-soluble oxygenated hydrocarbon comprising C1+O1+ hydrocarbon in an aqueous liquid phase and/or a vapor phase;(b) providing H2;(c) catalytically reacting in the liquid and/or vapor phase the carbohydrate derived water-soluble oxygenated hydrocarbon with the H2 in the presence of a deoxygenation catalyst at a deoxygenation temperature and deoxygenation pressure to produce carbohydrate derived oxygenate comprising C1+O1-3 hydrocarbon in a reaction stream; and(d) catalytically reacting in the liquid and/or vapor phase the carbohydrate derived oxygenate under condensation conditions comprising the presence of a condensation catalyst and a condensation temperature of 325° C. or higher, the condensation conditions being effective to produce the carbohydrate derived component having at least one C4+ compound; and,(e) separating the moderate fraction from the carbohydrate derived component. 33. The kerosene fuel composition of claim 32 wherein the condensation conditions comprise a ZSM-5 zeolite type condensation catalyst. 34. The kerosene fuel composition of claim 32 wherein the condensation catalyst is selected from the group consisting of an acid condensation catalyst and an acid-base condensation catalyst. 35. The kerosene fuel composition of claim 33 wherein the condensation catalyst is selected from the group consisting of an acid condensation catalyst and an acid-base condensation catalyst.
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