초록 ▼

Disclosed is an acetylenic polyamide and a composition comprising said acetylenic polyamide, which acetylenic polyamide. Said acetylenic group is suitably obtained by subjecting at least one acetylenic compound to reaction with either at least one polyamide, or at least one amino functional monomer

Disclosed is an acetylenic polyamide and a composition comprising said acetylenic polyamide, which acetylenic polyamide. Said acetylenic group is suitably obtained by subjecting at least one acetylenic compound to reaction with either at least one polyamide, or at least one amino functional monomer and/or carboxylic acid, yielding a corresponding acetylenic amide monomer, oligoamide or polyamide. Amide monomers and/or oligoamides can subsequently be used in production of the acetylenic polyamide.

대표청구항 ▼

1. An acetylenic polyamide wherein said acetylenic polyamide by reaction is fitted with at least one acetylenic carbon-carbon triple bond derived from at least one acetylenic compound having said at least one acetylenic carbon-carbon triple bond; said acetylenic compound is a compound of Formula I-V

1. An acetylenic polyamide wherein said acetylenic polyamide by reaction is fitted with at least one acetylenic carbon-carbon triple bond derived from at least one acetylenic compound having said at least one acetylenic carbon-carbon triple bond; said acetylenic compound is a compound of Formula I-VIII wherein the position in the aromatic ring of acetylenic (carbon-carbon triple bond) is variable and wherein each substituent R individually is hydrogen or a hydroxy, halo or amino group or a linear or branched alkyl, alkenyl, alkynyl, aminoalkyl, aminoalkenyl, aminoalkynyl, haloalkyl, haloalkenyl, haloalkynyl, hydroxyalkyl, hydroxyalkenyl, hydroxyalkynyl, hydroxyacyl or aminoacyl group or an aryl, hydroxyaryl or aminoaryl group, each substituent R1 individually is hydrogen or a hydroxy or halo group or a linear or branched alkyl, alkenyl, hydroxyalkyl, hydroxyalkenyl, haloalkyl or haloalkenyl group, each R2 individually is a linear or branched alkyl, alkenyl, alkynyl or acyl group and each R3 individually is a linear or branched alkyl, alkenyl or alkynyl group or an aryl group; or ethynyl o-phthalic anhydride, methylethynyl o-phthalic anhydride, phenylethynyl o-phthalic anhydride, naphthyl ethynyl o-phthalic anhydride, ethynyl isophthalic acid, methylethynyl isophthalic acid, phenylethynyl isophthalic acid, naphthyl ethynyl isophthalic acid, ethynyl terephthalic acid, methylethynyl terephthalic acid, phenylethynyl terephthalic acid, naphthyl ethynyl terephthalic acid, ethynyl benzoic acid, methylethynyl benzoic acid, phenylethynyl benzoic acid, naphthyl ethynyl benzoic acid, ethynyl adipic acid, methylethynyl adipic acid, phenylethynyl adipic acid, naphthyl ethynyl adipic acid, ethynyl azelaic acid, methylethynyl azelaic acid, phenylethynyl azelaic acid, naphthyl ethynyl azelaic acid, ethynyl sebacic acid, methylethynyl sebacic acid, phenylethynyl sebacic acid, naphthyl ethynyl sebacic acid, ethynyl 2,5-furandicarboxylic acid, methylethynyl 2,5-furandicarboxylic acid, phenyl ethynyl 2,5-furandicarboxylic acid, naphthyl ethynyl 2,5-furandicarboxylic acid and/or a corresponding acid halide or alkyl ester, wherein said acetylenic polyamide comprises monomer units derived from at least one linear or branched aliphatic, cycloaliphatic or aromatic di, tri or polyfunctional amine, at least one aliphatic, cycloaliphatic or aromatic aminoacid and/or at least one lactam; wherein said acetylenic polyamide comprises monomer units derived from hexamethylene diamine, pentamethylene diamine, 2,2,4-trimethyl-hexamethylene diamine, 2,4,4-trimethyl-hexamethylene diamine, 1,4-diaminobutane, 11-aminoundecanoic acid, 12-aminodecanoic acid, aminocaproic acid caprolactam and/or laurolactam. 2. An acetylenic polyamide according to claim 1, wherein said acetylenic polyamide comprises monomer units derived from at least one linear or branched aliphatic or cycloaliphatic di, tri or polyfunctional carboxylic acid or anhydride or a corresponding acid halide or alkyl ester. 3. An acetylenic polyamide according to claim 2 wherein said linear or branched aliphatic, or cycloaliphatic di, tri or polyfunctional carboxylic acid or anhydride has 2-18 carbon atoms. 4. An acetylenic polyamide according to claim 1, wherein said acetylenic polyamide comprises monomer units derived from oxalic acid, malonic acid, adipic acid, sebacic acid and/or a corresponding acid halide or alkyl ester. 5. An acetylenic polyamide according to claim 1, wherein said acetylenic group is obtained by subjecting at least one said acetylenic compound to reaction with at least one polyamide. 6. An acetylenic polyamide according to claim 1, wherein said acetylenic group is obtained by subjecting at least one said acetylenic compound to reaction with at least one said amine, aminoacid and/or lactam yielding a corresponding acetylenic amide monomer or oligomer, which acetylenic amide monomer or oligomer subsequently is used in the production of a said acetylenic polyamide. 7. An acetylenic polyamide according to claim 1, wherein said acetylenic group is obtained by subjecting at least one said acetylenic compound to co-polymerisation with at least one said amine, aminoacid and/or lactam and optionally at least one said carboxylic acid or anhydride or a corresponding acid halide or alkyl ester, yielding a corresponding acetylenic oligoamide or polyamide. 8. An acetylenic polyamide according to claim 7 wherein a yielded acetylenic oligoamide is used in production of the acetylenic polyamide. 9. An acetylenic polyamide according to claim 1, wherein said acetylenic compound is present in said acetylenic polyamide in an amount corresponding to at least 0.1 mole % of the total molar amount of monomers, oligomers and/or polymers used in production of said acetylenic polyamide. 10. An acetylenic polyamide according to claim 1, wherein said acetylenic compound is present in said acetylenic polyamide in an amount corresponding to between 1 and 30 mole % of the total molar amount of monomers, oligomers and/or polymers used in production of said acetylenic polyamide. 11. A composition comprising at least one acetylenic polyamide according to claim 1, wherein said composition comprises between 0.1 and 99.9% by weight of said acetylenic polyamide. 12. A composition according to claim 11 wherein said composition comprises between 1% and 40% by weight of said acetylenic polyamide. 13. A composition according to claim 12 wherein said composition comprises between 1% and 25% by weight of said acetylenic polyamide. 14. A moulded three-dimensional article wherein said article is obtained by moulding at least one acetylenic polyamide according to claim 1.