IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0281040
(2011-10-25)
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등록번호 |
US-8496894
(2013-07-30)
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발명자
/ 주소 |
- Durham, Michael D.
- Sjostrom, Sharon
- Baldrey, Kenneth E.
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출원인 / 주소 |
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대리인 / 주소 |
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인용정보 |
피인용 횟수 :
13 인용 특허 :
222 |
초록
The present disclosure is directed to the use of elemental or speciated iodine and bromine to control total mercury emissions.
대표청구항
▼
1. A method, comprising: providing a mercury-containing gas stream comprising vapor-phase mercury, a vapor-phase iodine, and particulates;passing the mercury-containing gas stream through a selective catalytic reduction zone; andthereafter removing particulates from the mercury-containing gas stream
1. A method, comprising: providing a mercury-containing gas stream comprising vapor-phase mercury, a vapor-phase iodine, and particulates;passing the mercury-containing gas stream through a selective catalytic reduction zone; andthereafter removing particulates from the mercury-containing gas stream to form a treated stream, at least a portion of the vapor-phase mercury being removed from the mercury-containing gas stream with removal of the particulates, wherein at least one of the following is true:(i) the mercury-containing gas stream comprises about 3.5 ppmw or less vapor-phase iodine;(ii) in the mercury-containing gas stream, a molar ratio of vapor-phase iodine to vapor-phase mercury is no more than about 600;(iii) at an air preheater outlet, a concentration of vapor-phase iodine ranges from about 0.1 to about 10 ppmw;(iv) a concentration of the iodine is about 30 ppmw or less relative to a weight of a mercury-containing feed material producing the vapor-phase mercury. 2. The method of claim 1, wherein (i) is true. 3. The method of claim 2, wherein the mercury-containing gas stream comprises about 1.5 ppmw or less vapor-phase iodine. 4. The method of claim 1, wherein (ii) is true. 5. The method of claim 4, wherein the molar ratio is no more than about 250. 6. The method of claim 1, wherein (iii) is true. 7. The method of claim 6, wherein a temperature of the mercury-containing gas stream ranges from about 325 to about 450° C. and wherein the concentration of vapor-phase iodine at the air preheater outlet ranges from about 0.2 to about 2 ppmw. 8. The method of claim 1, wherein (iv) is true. 9. The method of claim 1, wherein the feed material natively comprises no more than about 3 ppmw total iodine and no more than about 10 ppmw total bromine, wherein the halogen-containing additive is contacted with the feed material, wherein the halogen-containing additive comprises no more than about 25% of halogens other than iodine and/or bromine, and wherein a total halogen concentration relative to a weight of the feed material is about 15 ppmw or less. 10. The method of claim 6, wherein the iodine is contacted with vapor-phase mercury upstream of the air preheater. 11. The method of claim 9, wherein the feed material is combustible, wherein the combustible feed material is combusted to produce the mercury-containing gas stream, wherein the vapor-phase iodine causes removal of at least about 75% of elemental and speciated mercury from the mercury-containing gas stream, and wherein the combustible feed material, when combusted, produces an unburned carbon particulate level of no more than about 20% by weight of the combustible feed material. 12. The method of claim 1, further comprising: while vapor phase iodine and mercury are in the mercury-containing gas stream, introducing, into the mercury-containing gas stream, a reactive surface agent to collect at least most of the iodine and mercury. 13. The method of claim 12, wherein the reactive surface agent is one or more of a zeolite, silica, alumina, silica alumina, gamma-alumina, activated alumina, acidified alumina, a metal oxide particle, aluminosilicate, ion exchange resin, clay, a transition metal sulfate, a ceramic, an alkaline material, trona, an alkali metal bicarbonate, an alkali metal bisulfate, an alkali metal bisulfite, sulfide, elemental sulfur, circulating fluidized bed ash, fluidized catalytic cracker fines, and fumed silicate, and wherein one or more of a mean, median, and P90 size of the reactive surface agent is no more than about 100 microns. 14. The method of claim 1, wherein a concentration of the vapor-phase mercury in the mercury-containing gas stream is at least about 0.001 ppmw, wherein a molar ratio, in the mercury-containing gas stream, of vapor phase iodine to total gas-phase mercury is no more than about 250, wherein a concentration of the vapor-phase iodine in the mercury-containing gas stream is about 1.5 ppmw or less, and wherein the selective catalytic reduction catalyst at least one of catalyzes the formation of diatomic iodine and oxidizes at least some of the vapor-phase mercury. 15. The method of claim 1, further comprising: passing the mercury-containing gas stream through at least one of a baghouse, a spray dryer absorber, and an electrostatic precipitator to form a treated gas stream; andthereafter passing the treated gas stream through a wet scrubber, the wet scrubber having a scrubber slurry sorbing no more than about 20% of the total mercury. 16. The method of claim 1, further comprising: passing the mercury-containing gas stream through at least one of a first particulate removal device to remove at least most of the mercury and form a first gas stream; andpassing the first gas stream through a preheater to form a second gas stream; andpassing the second gas stream through a second particulate removal device to remove at least most of any remaining mercury from the second gas stream and form a treated gas stream. 17. The method of claim 1, wherein the mercury-containing gas stream is derived from combustion of a combustible feed material and wherein the feed material is one of a high- and medium-sulfur coal and wherein a concentration of at least one of sulfur trioxide and nitrogen dioxide gas in the mercury-containing gas stream is at least about 5 ppmv. 18. The method of claim 1, wherein the mercury-containing gas stream is derived from combustion of a combustible feed material and wherein the feed material is a high alkali coal. 19. The method of claim 1, wherein the vapor phase iodine comprises both a hydrogen-iodine species and diatomic iodide and wherein a molecular ratio of diatomic iodide to the hydrogen-iodine species is at least about 10:1. 20. The method of claim 12, wherein the reactive surface agent is introduced by a dry scrubber and wherein the dry scrubber is located upstream of a particulate removal device. 21. A method, comprising: contacting a mercury-containing feed material with a halogen-containing additive to form a treated feed material, the halogen in the halogen-containing additive being one or more of iodine and bromine;generating from the treated feed material a mercury-containing gas stream comprising vapor-phase mercury, a vapor-phase halogen, and particulates;passing the mercury-containing gas stream through a selective catalytic reduction zone, a temperature of the mercury-containing gas stream in the selective catalytic reduction zone being at least about 250′Celsius; andthereafter removing particulates from the mercury-containing gas stream to form a treated stream, at least a portion of the vapor-phase mercury being removed from the mercury-containing gas stream with removal of the particulates. 22. The method of claim 21, wherein the selective catalytic reduction zone is positioned upstream of an air preheater. 23. The method of claim 21, wherein the temperature is at least about 300° Celsius. 24. The method of claim 21, wherein the temperature is at least about 325° Celsius. 25. The method of claim 21, wherein a halogen/mercury mass ratio is no more than about 100. 26. The method of claim 25, wherein the mass ratio is no more than about 75. 27. The method of claim 26, wherein the mass ratio is more than about 50. 28. The method of claim 27, wherein the mass ratio is no more than about 40. 29. The method of claim 21, wherein a maximum amount of halogen added to the feed material is no more than about 25 ppmw. 30. The method of claim 29, wherein the maximum amount of halogen is no more than about 20 ppmw. 31. The method of claim 30, wherein the maximum amount of halogen is no more than about 15 ppmw. 32. The method of claim 31, wherein the maximum amount of halogen is no more than about 10 ppmw, and wherein the halogen comprises iodine. 33. A method, comprising: combusting a halogen-containing additive and a carbonaceous feed material to form a mercury-containing gas stream comprising vapor-phase mercury, particulates, and a vapor-phase halogen;thereafter contacting the mercury-containing gas stream with a mercury active agent other than the halogen-containing additive, the mercury active agent being capable of oxidizing elemental mercury; andthereafter removing particulates from the mercury-containing gas stream to form a treated stream, at least a portion of the vapor-phase mercury being removed from the mercury-containing gas stream with removal of the particulates. 34. The method of claim 33, wherein at least one of the following is true: (i) the mercury-containing gas stream comprises about 3.5 ppmw or less vapor-phase halogen;(ii) in the mercury-containing gas stream, a molar ratio of vapor-phase halogen to vapor-phase mercury is no more than about 600;(iii) at an air preheater outlet, a concentration of vapor-phase halogen ranges from about 0.1 to about 10 ppmw;(iv) a concentration of the vapor-phase halogen concentration is about 30 ppmw or less relative to a weight of a mercury-containing feed material producing the vapor-phase mercury. 35. The method of claim 33, wherein the mercury active agent comprises a halogen and wherein the vapor phase halogen is different from the mercury active agent. 36. The method of claim 35, wherein the vapor phase halogen comprises one or more of iodine and bromine and the mercury-active agent comprises chlorine. 37. The method of claim 33, wherein the mercury active agent and vapor phase halogen are a common halogen but the common halogen compounded differently. 38. The method of claim 33, wherein the mercury active agent and the vapor phase halogen are in diatomic elemental form. 39. The method of claim 33, wherein the mercury active agent is one or more of a bromide salt, iodide salt, chloride salt, diatomic iodine, diatomic bromine, diatomic chlorine, bromine gas, iodine gas, chlorine gas, hydrogen bromide, hydrogen chloride, chlorite, chlorate, perchlorate, hypochlorite, and copper oxide. 40. The method of claim 33, wherein the mercury active agent is contacted with the mercury-containing gas stream between an economizer and air preheater outlet. 41. The method of claim 33, wherein the mercury active agent is a substantially free of halogens. 42. The method of claim 33, wherein the mercury active agent is an oxidant substantially free of iodine and bromine. 43. The method of claim 33, wherein the mercury active agent is substantially free of carbon. 44. A method, comprising: providing a mercury-containing gas stream comprising vapor-phase mercury, a vapor-phase iodine and/or bromine, and particulates;passing the mercury-containing gas stream through a selective catalytic reduction zone comprising a selective catalyst reduction agent; andthereafter removing particulates from the mercury-containing gas stream to form a treated stream, at least a portion of the vapor-phase mercury being removed from the mercury-containing gas stream with removal of the particulates, wherein at least one of the following is true:(i) the selective catalyst reduction agent has an effective SO2-to-SO3 oxidation rate of lower than about 2%;(ii) an air preheater outlet temperature is no more than about 150° Celsius;(iii) an ammonia slip at a stack is no more than about 5 ppmv;(iv) the mercury-containing gas stream is formed from combustion of a feed material having no more than about 1 wt. % total sulfur (dry basis of the coal);(v) the mercury-containing gas stream is formed from combustion of a feed material having an alkali content of at least about 20 wt. % (dry basis of ash); and(vi) the mercury-containing gas stream has, at a particulate control device, a SO3 concentration of no more than about 7.5 ppmv. 45. A method, comprising: providing a mercury-containing gas stream comprising vapor-phase mercury and a vapor-phase halogen;contacting the mercury-containing gas stream with a particulate mercury active agent upstream of an air preheater; andremoving the particulate mercury active agent from the mercury-containing gas stream, wherein at least a portion of the vapor-phase mercury collects on and is removed with the particulate mercury active agent. 46. The method of claim 45, wherein the mercury active agent is one or more of a porous carbonaceous material, activated alumina, ceramic, clay, silica, silica-alumina, silicates, zeolites, fine fraction fly ash, FCC fines, and fluidized bed combustor ash. 47. The method of claim 45, wherein the mercury active agent is a porous carbonaceous material that is selected from the group consisting essentially of activated carbon, charcoal, coke, fly ash, bottom ash, carbon black, activated pet coke and mixtures thereof. 48. The method of claim 45, wherein the mercury active agent comprises a halogen in addition to the vapor-phase halogen present in the mercury-containing gas stream before contact with the mercury active agent. 49. The method of claim 45, wherein the mercury active agent is contacted with the mercury-containing gas stream downstream of an economizer. 50. A method, comprising: generating, from a mercury-containing feed material and a halogen additive to the mercury-containing feed material, a mercury-containing gas stream comprising vapor-phase elemental mercury and a vapor-phase halogen;contacting the mercury-containing gas stream with a diatomic elemental halogen upstream of an air preheater, the non-halogen mercury active agent and vapor phase halogen converting elemental mercury into ionic mercury; andremoving the ionic mercury active agent from the mercury-containing gas stream. 51. The method of claim 50, wherein the vapor-phase halogen and halogen additive comprise one or more of iodine and bromine and wherein the halogen in the diatomic elemental halogen is different from the one or more of iodine and bromine. 52. The method of claim 51, wherein the diatomic elemental halogen comprises chlorine. 53. The method of claim 50, wherein the halogen additive is one or more of a bromide, a bromate, an iodide, an iodate, a chloride, a chlorate, a chlorite, a chlorate, a perchlorate, and a hypochlorite. 54. The method of claim 53, wherein the diatomic elemental halogen is one or more of iodine, bromine, and chlorine gas. 55. The method of claim 50, wherein a reactive surface agent is contacted with the mercury-containing gas stream. 56. The method of claim 50, wherein a concentration of the vapor-phase halogen in the mercury-containing gas stream is one or more of: (i) about 3.5 ppmw or less;(ii) a molar ratio of vapor-phase iodine to vapor-phase mercury is no more than about 600;(iii) at an air preheater outlet, a concentration of vapor-phase iodine ranges from about 0.1 to about 10 ppmw; and(iv) a concentration of the vapor-phase iodine concentration is about 30 ppmw or less relative to a weight of a mercury-containing feed material producing the vapor-phase mercury. 57. The method of claim 56, wherein the diatomic elemental halogen has a concentration ranging from about 0.1 to about 8 ppm of mercury-containing gas stream. 58. The method of claim 56, wherein the diatomic elemental halogen has a concentration ranging from about 0.25 to about 5 ppmw of mercury-containing gas stream. 59. The method of claim 56, wherein the diatomic elemental halogen has a concentration ranging from about 0.5 to about 2 ppmw of mercury-containing gas stream. 60. The method of claim 56, wherein a halogen additive/mercury mass ratio is no more than about 100. 61. The method of claim 60, wherein the mass ratio is no more than about 75. 62. The method of claim 61, wherein the mass ratio is more than about 50. 63. The method of claim 62, wherein the mass ratio is no more than about 40. 64. The method of claim 60, wherein a maximum amount of halogen additive added to the feed material is no more than about 25 ppmw. 65. The method of claim 64, wherein the maximum amount of halogen is no more than about 20 ppmw. 66. The method of claim 65, wherein the maximum amount of halogen is no more than about 15 ppmw. 67. The method of claim 66, wherein the maximum amount of halogen is no more than about 10 ppmw. 68. The method of claim 44, wherein (i) is true. 69. The method of claim 44, wherein (ii) is true. 70. The method of claim 44, wherein (iii) is true. 71. The method of claim 44, wherein (iv) is true. 72. The method of claim 44, wherein (v) is true. 73. The method of claim 44, wherein (vi) is true. 74. The method of claim 44, wherein the vapor-phase iodine and/or bromine comprises iodine.
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