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NTIS 바로가기다음과 같은 기능을 한번의 로그인으로 사용 할 수 있습니다.
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Kafe 바로가기국가/구분 | United States(US) Patent 등록 |
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국제특허분류(IPC7판) |
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출원번호 | US-0928681 (2010-12-16) |
등록번호 | US-8518546 (2013-08-27) |
발명자 / 주소 |
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출원인 / 주소 |
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대리인 / 주소 |
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인용정보 | 피인용 횟수 : 2 인용 특허 : 169 |
The present invention relates to compounds represented by the following Formula I, Ring-A of the Formula I can be, for example an aryl group, and L1 is a chiral or achiral lengthening group. The compound represented by Formula I can be a photochromic compound. The present invention also relates to
The present invention relates to compounds represented by the following Formula I, Ring-A of the Formula I can be, for example an aryl group, and L1 is a chiral or achiral lengthening group. The compound represented by Formula I can be a photochromic compound. The present invention also relates to photochromic compositions and photochromic articles that include one or more photochromic compounds, such as represented by Formula I.
1. A compound represented by the following Formula I, wherein, (A) Ring-A is selected from unsubstituted aryl, substituted aryl, unsubstituted fused ring aryl, substituted fused ring aryl, unsubstituted heteroaryl, and substituted heteroaryl; (B) (i) m is selected from 0 to a total number of positio
1. A compound represented by the following Formula I, wherein, (A) Ring-A is selected from unsubstituted aryl, substituted aryl, unsubstituted fused ring aryl, substituted fused ring aryl, unsubstituted heteroaryl, and substituted heteroaryl; (B) (i) m is selected from 0 to a total number of positions to which R1 can be bonded to Ring-A, and R1, for each m, is independently selected from, L2 as described hereinafter, and a chiral or achiral group selected from formyl, alkylcarbonyl, alkoxycarbonyl, aminocarbonyl, arylcarbonyl, aryloxycarbonyl, aminocarbonyloxy, alkoxycarbonylamino, aryloxycarbonylamino, boronic acid, boronic acid esters, cycloalkoxycarbonylamino, heterocycloalkyloxycarbonylamino, heteroaryloxycarbonylamino, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, halogen, optionally substituted cycloalkyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted heteroalkyl, optionally substituted heterocycloalkyl, and optionally substituted amino, and (ii) n is selected from 0 to 3, and R2, for each n, is independently a chiral or achiral group selected from, formyl, alkylcarbonyl, alkoxycarbonyl, aminocarbonyl, arylcarbonyl, aryloxycarbonyl, aminocarbonyloxy, alkoxycarbonylamino, aryloxycarbonylamino, boronic acid, boronic acid esters, cycloalkoxycarbonylamino, heterocycloalkyloxycarbonylamino, heteroaryloxycarbonylamino, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, halogen, optionally substituted cycloalkyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted heteroalkyl, optionally substituted heterocycloalkyl, and optionally substituted amino; (C) R3 and R4 are each independently selected from, hydrogen, hydroxyl, and a chiral or achiral group selected from optionally substituted heteroalkyl, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted cycloalkyl, optionally substituted heterocycloalkyl, halogen, optionally substituted amino, carboxy, alkylcarbonyl, alkoxycarbonyl, optionally substituted alkoxy, and aminocarbonyl, or one of R3 and R4 is a bond, one of R3 and R4 is oxygen, and R3 and R4 together form oxo, orR3 and R4 together with any intervening atoms form a group selected from optionally substituted cycloalkyl, and optionally substituted heterocycloalkyl; (D) B and B′ are each independently selected from hydrogen, L3 as described hereinafter, halogen, and a chiral or achiral group selected from metallocenyl, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted heteroalkyl, optionally substituted alkoxy, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted heterocycloalkyl, and optionally substituted cycloalkyl, or B and B′ taken together with any intervening atoms form a group selected from optionally substituted cycloalkyl and optionally substituted heterocycloalkyl; and (E) L1, L2 and L3 are each independently selected from a chiral or achiral lengthening group represented by the following Formula II, —(S1)c-(Q1-(S2)d)d′-(Q2-(S3)e)e′(Q3-(S4)f)f′-S5—P II wherein, (i) Q1, Q2, and Q3 are each independently for each occurrence a divalent group chosen from, an unsubstituted or a substituted aromatic group, an unsubstituted or a substituted alicyclic group, and an unsubstituted or a substituted heterocyclic group, wherein each substituent is independently chosen from, a group represented by P, liquid crystal mesogens, halogen, poly(C1-C18 alkoxy), C1-C18 alkoxycarbonyl, C1-C18 alkylcarbonyl, C1-C18 alkoxycarbonyloxy, aryloxycarbonyloxy, perfluoro(C1-C18)alkoxy, perfluoro(C1-C18)alkoxycarbonyl, perfluoro(C1-C18)alkylcarbonyl, perfluoro(C1-C18)alkylamino, di-(perfluoro(C1-C18)alkyl)amino, perfluoro(C1-C18)alkylthio, C1-C18 alkylthio, C1-C18 acetyl, C3-C10 cycloalkyl, C3-C10 cycloalkoxy, a straight-chain or branched C1-C18 alkyl group that is mono-substituted with cyano, halo, or C1-C18 alkoxy, or poly-substituted with halo, and a group comprising one of the following formulae: -M(T)(t-1) and -M(OT)(t-1), wherein M is chosen from aluminum, antimony, tantalum, titanium, zirconium and silicon, T is chosen from organofunctional radicals, organofunctional hydrocarbon radicals, aliphatic hydrocarbon radicals and aromatic hydrocarbon radicals, and t is the valence of M,(ii) c, d, e, and f are each independently an integer selected from 0 to 20, inclusive; and S1, S2, S3, S4, and S5 are each independently for each occurrence a spacer unit chosen from:(1) —(CH2)g—, —(CF2)h—, —Si(Z)2(CH2)g—, —(Si(CH3)2O)h—, wherein Z is independently chosen for each occurrence from hydrogen, C1-C18 alkyl, C3-C18 cycloalkyl and aryl; g is independently chosen for each occurrence from 1 to 20; h is a whole number from 1 to 16 inclusive;(2) —N(Z)—, —C(Z)═C(Z)—, —C(Z)═N—, —C(Z′)—C(Z′)- or a single bond, wherein Z is independently chosen for each occurrence from hydrogen, C1-C18 alkyl, C3-C10 cycloalkyl and aryl, and Z′ is independently chosen for each occurrence from C1-C18 alkyl, C3-C10 cycloalkyl and aryl; and(3) —O—, —C(O)—, —N═N—, —S—, —S(O)—, —S(O)(O)—, —(O)S(O)—, —(O)S(O)O—, —O(O)S(O)O—, or straight-chain or branched C1-C24 alkylene residue, said C1-C24 alkylene residue being unsubstituted, mono-substituted by cyano or halo, or poly-substituted by halo,provided that when two spacer units comprising heteroatoms are linked together the spacer units are linked so that heteroatoms are not directly linked to each other, andprovided that when S1 is linked to Formula I and S5 is linked to P, S1 and S5 are each linked so that two heteroatoms are not directly linked to each other;(iii) P is chosen from: hydroxy, amino, C2-C18 alkenyl, C2-C18 alkynyl, azido, silyl, siloxy, silylhydride, (tetrahydro-2H-pyran-2-yl)oxy, thio, isocyanato, thioisocyanato, acryloyloxy, methacryloyloxy, 2-(acryloyloxy)ethylcarbamyl, 2-(methacryloyloxy)ethylcarbamyl, aziridinyl, allyloxycarbonyloxy, epoxy, carboxylic acid, carboxylic ester, acryloylamino, methacryloylamino, aminocarbonyl, C1-C18 alkyl aminocarbonyl, aminocarbonyl(C1-C18)alkyl, C1-C18 alkyloxycarbonyloxy, halocarbonyl, hydrogen, aryl, hydroxy(C1-C18)alkyl, C1-C18 alkyl, C1-C18 alkoxy, amino(C1-C18)alkyl, alkylamino, di-(C1-C18)alkylamino, alkyl(C1-C18)alkoxy, alkoxy(C1-C18)alkoxy, nitro, poly(C1-C18)alkyl ether, (C1-C18)alkyl(C1-C18)alkoxy(C1-C18)alkyl, polyethyleneoxy, polypropyleneoxy, ethylenyl, acryloyl, acryloyloxy(C1-C18)alkyl, methacryloyl, methacryloyloxy(C1-C18)alkyl, 2-chloroacryloyl, 2-phenylacryloyl, acryloyloxyphenyl, 2-chloroacryloylamino, 2-phenylacryloylaminocarbonyl, oxetanyl, glycidyl, cyano, isocyanato(C1-C18)alkyl, itaconic acid ester, vinyl ether, vinyl ester, a styrene derivative, main-chain and side-chain liquid crystal polymers, siloxane derivatives, ethyleneimine derivatives, maleic acid derivatives, fumaric acid derivatives, unsubstituted cinnamic acid derivatives, cinnamic acid derivatives that are substituted with at least one of methyl, methoxy, cyano and halogen, or substituted or unsubstituted chiral or non-chiral monovalent or divalent groups chosen from steroid radicals, terpenoid radicals, alkaloid radicals and mixtures thereof, wherein the substituents are independently chosen from C1-C18 alkyl, C1-C18 alkoxy, amino, C3-C10 cycloalkyl, C1-C18 alkyl(C1-C18)alkoxy, fluoro(C1-C18)alkyl, cyano, cyano(C1-C18)alkyl, cyano(C1-C18)alkoxy or mixtures thereof, or P is a structure having from 2 to 4 reactive groups, or P is an unsubstituted or substituted ring opening metathesis polymerization precursor, or P is a substituted or unsubstituted photochromic compound; and(iv) d′, e′ and f′ are each independently chosen from 0, 1, 2, 3, and 4, provided that a sum of d′+e′+f′ is at least 2. 2. The compound of claim 1, wherein, (A) Ring-A is selected from unsubstituted aryl and substituted aryl; (B) (i) R1, for each m, is independently selected from, L2, formyl, alkylcarbonyl, alkoxycarbonyl, aminocarbonyl, arylcarbonyl, aryloxycarbonyl, optionally substituted alkyl, boronic acid ester, halogen, optionally substituted cycloalkyl, optionally substituted aryl, optionally substituted alkoxy, optionally substituted heteroalkyl, optionally substituted heterocycloalkyl and optionally substituted amino, and (ii) R2, for each n, is independently selected from, formyl, alkylcarbonyl, alkoxycarbonyl, aminocarbonyl, arylcarbonyl, aryloxycarbonyl, optionally substituted alkyl, boronic acid ester, halogen, optionally substituted cycloalkyl, optionally substituted aryl, optionally substituted alkoxy, optionally substituted heteroalkyl, optionally substituted heterocycloalkyl and optionally substituted amino; (C) R3 and R4 are each independently selected from, hydrogen, hydroxy, and chiral and achiral groups selected from optionally substituted heteroalkyl, optionally substituted alkyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted cycloalkyl, halogen, optionally substituted amino, carboxy, alkylcarbonyl, alkoxycarbonyl, optionally substituted alkoxy, and aminocarbonyl, or one of R3 and R4 is a bond, one of R3 and R4 is oxygen, and R3 and R4 together form oxo, orR3 and R4 together with any intervening atoms form a group selected from optionally substituted cycloalkyl, and optionally substituted heterocycloalkyl; (D) B and B′ are each independently selected from L3, hydrogen, halogen, chiral or achiral groups selected from optionally substituted alkyl, optionally substituted alkenyl, optionally substituted heteroalkyl, optionally substituted alkoxy, optionally substituted aryl, optionally substituted heteroaryl, and optionally substituted cycloalkyl, or B and B′ taken together with any intervening atoms form a group selected from optionally substituted cycloalkyl and optionally substituted heterocycloalkyl; and (E) L1, L2 and L3 are each independently selected from said chiral or achiral lengthening group represented by Formula II, wherein, (i) Q1, Q2, and Q3 are each independently for each occurrence a divalent group selected from optionally substituted aryl, optionally substituted heteroaryl, optionally substituted cycloalkyl, and optionally substituted heterocycloalkyl, wherein each substituent is independently selected from, P, liquid crystal mesogens, halogen, poly(C1-C12 alkoxy), alkoxycarbonyl, C1-C12 alkylcarbonyl, perfluoro(C1-C12)alkoxy, perfluoro(C1-C12)alkoxycarbonyl, perfluoro(C1-C12)alkylcarbonyl, C1-C18 acetyl, C3-C7 cycloalkyl, C3-C7 cycloalkoxy, straight-chain C1-C12 alkyl, and branched C1-C12 alkyl, wherein said straight-chain C1-C12 alkyl and branched C1-C12 alkyl are mono-substituted with a group selected from, halogen, and C1-C12 alkoxy, orwherein said straight-chain C1-C12 alkyl and branched C1-C12 alkyl are poly-substituted with at least two groups independently selected from halogen;(ii) c, d, e, and f are each independently an integer chosen from 1 to 10; and S1, S2, S3, S4, and S5 are each independently for each occurrence a spacer unit selected from: (1) substituted or unsubstituted alkylene, substituted or unsubstituted haloalkylene, —Si(CH2)g—, and —(Si[(CH3)2]O)h—, wherein g for each occurrence is independently chosen from an integer from 1 to 10; h for each occurrence is independently chosen from an integer from 1 to 8; and said substitutes for the alkylene and haloalkylene are independently selected from C1-C12 alkyl, C3-C7 cycloalkyl and phenyl;(2) —N(Z)—, —C(Z)═C(Z)—, and a single bond, wherein Z for each occurrence is independently selected from hydrogen, C1-C12 alkyl, C3-C7 cycloalkyl and phenyl; and(3) —O—, —C(═O)—, —N═N—, —S—, and —S(═O)—,provided that when two spacer units comprising heteroatoms are linked together the spacer units are linked so that heteroatoms of the first spacer unit are not directly linked to the heteroatoms of the second spacer unit, andprovided that when S1 is linked to Formula I and S5 is linked to P, S1 and S5 are each linked so that two heteroatoms are not directly linked to each other;(iii) P for each occurrence is selected from hydroxy, amino, C2-C12 alkenyl, C2-C12 alkenyl, silyl, siloxy, (tetrahydro-2H-pyran-2-yl)oxy, isocyanato, acryloyloxy, methacryloyloxy, epoxy, carboxylic acid, carboxylic ester, C1-C12 alkyloxycarbonyloxy, halocarbonyl, hydrogen, aryl, hydroxy(C1-C12)alkyl, C1-C12 alkyl, C1-C12 alkoxy, ethylene, acryloyl, acryloyloxy(C1-C12)alkyl, methacryloyl, methacryloyloxy(C1-C12)alkyl, oxetanyl, glycidyl, vinyl ether, siloxane derivartives, unsubstituted cinnamic acid derivatives, cinnamic acid derivatives that are substituted with at least one of methyl, methoxy, cyano and halogen, and substituted or unsubstituted chiral or non-chiral monovalent or divalent groups chosen from Steroid radicals, wherein each substituent is independently chosen from C1-C12 alkyl, C1-C12 alkoxy, amino, C3-C7 cycloalkyl, alkyl(C1-C12)alkoxy, or fluoro(C1-C12)alkyl, or P is a structure having from 2 to 4 reactive groups; and(iv) d′, e′ and f are each independently chosen from 0, 1, 2, 3, and 4,provided that a sum of d′+e′+f is at least 2. 3. The compound of claim 2, wherein, (B) (i) R1, for each m, is independently selected from, L2, alkylcarbonyl, alkoxycarbonyl, aminocarbonyl, optionally substituted alkyl, boronic acid ester, halogen, optionally substituted cycloalkyl, optionally substituted aryl, optionally substituted alkoxy, optionally substituted heterocycloalkyl and optionally substituted amino, and (ii) R2, for each n, is independently selected from, alkylcarbonyl, alkoxycarbonyl, aminocarbonyl, optionally substituted alkyl, boronic acid ester, halogen, optionally substituted cycloalkyl, optionally substituted aryl, optionally substituted alkoxy, optionally substituted heterocycloalkyl and optionally substituted amino; (C) R3 and R4 are each independently selected from, hydrogen, hydroxy, and chiral groups selected from optionally substituted heteroalkyl, optionally substituted alkyl, optionally substituted aryl, optionally substituted cycloalkyl, halogen, carboxy, alkylcarbonyl, alkoxycarbonyl, optionally substituted alkoxy, and aminocarbonyl, or one of R3 and R4 is a bond, one of R3 and R4 is oxygen, and R3 and R4 together form oxo, orR3 and R4 together with any intervening atoms form optionally substituted cycloalkyl; (D) B and B′ are each independently selected from L3, hydrogen, chiral groups selected from optionally substituted alkyl, optionally substituted alkenyl, optionally substituted aryl, optionally substituted heteroaryl, and optionally substituted cycloalkyl, or wherein B and B′ are taken together with any intervening atoms to form a group selected from optionally substituted cycloalkyl; and (E) L1, L2 and L3 are each independently selected from said chiral or achiral lengthening group represented by Formula II, wherein, (i) Q1, Q2, and Q3 are each independently for each occurrence a divalent group selected from optionally substituted aryl, optionally substituted heteroaryl, optionally substituted cycloalkyl, and optionally substituted heterocycloalkyl, wherein each substituent is independently selected from, P, C1-C6 alkoxycarbonyl, perfluoro(C1-C6)alkoxy, C3-C7 cycloalkyl, C3-C7 cycloalkoxy, straight-chain C1-C6 alkyl, and branched C1-C6 alkyl, wherein said straight-chain C1-C6 alkyl and branched C1-C6 alkyl are mono-substituted with a group selected from halogen and C1-C12alkoxy, orwherein said straight-chain C1-C6 alkyl and branched C1-C6 alkyl are poly-substituted with at least two groups independently selected from halogen;(ii) c, d, e, and f are each independently an integer chosen from 1 to 10; and S1, S2, S3, S4, and S5 are each independently for each occurrence a spacer unit selected from: (1) substituted or unsubstituted alkylene;(2) —N(Z)—, —C(Z)═C(Z)—, and a single bond, wherein Z for each occurrence is independently selected from hydrogen and C1-C6 alkyl; and(3) —O—, —C(═O)—, —C═C—, and —N═N—, —S—;provided that when two spacer units comprising heteroatoms are linked together the spacer units are linked so that heteroatoms of the first spacer unit are not directly linked to the heteroatoms of the second spacer unit, andprovided that when S1 is linked to Formula I and S5 is linked to P, S1 and S5 are each linked so that two heteroatoms are not directly linked to each other;(iii) P for each occurrence is independently selected from hydroxy, amino, C2-C6 alkenyl, C2-C6 alkenyl, siloxy, (tetrahydro-2H-pyran-2-yl)oxy, isocyanato, acryloyloxy, methacryloyloxy, epoxy, carboxylic acid, carboxylic ester, C1-C6 alkyloxycarbonyloxy, hydrogen, aryl, hydroxy(C1-C6)alkyl, C1-C6 alkyl, ethylene, acryloyl, acryloyloxy(C1-C12)alkyl, oxetanyl, glycidyl, vinyl ether, siloxane derivatives, and substituted or unsubstituted chiral or non-chiral monovalent or divalent groups chosen from steroid radicals, wherein each substituent is independently chosen from C1-C6 alkyl, C1-C6 alkoxy, amino, C3-C7 cycloalkyl. 4. The compound of claim 3, wherein, (B) (i) R1, for each m, is independently selected from, methyl, ethyl, bromo, chloro, fluoro, methoxy, ethoxy and CF3, and (ii) R2, for each n, is independently selected from, methyl, ethyl, bromo, chloro, fluoro, methoxy, ethoxy and CF3; (C) R3 and R4 are each independently selected from, methyl, ethyl, propyl and butyl; (D) B and B′ are each independently selected from phenyl substituted with one or more groups independently selected from aryl, heteroaryl, heterocycloalkyl, alkyl, alkenyl, alkynyl, alkoxy, halogen, amino, alkylcarbonyl, carboxy, and alkoxycarbonyl; and (E) L1 is selected from said chiral or achiral lengthening group represented by Formula II, wherein, (i) Q1 is unsubstituted aryl, Q2 for each occurrence are each independently chosen from optionally substituted aryl,Q3 is optionally substituted cycloalkyl;(ii) e for each occurrence is 1, f is 1,S3 for each occurrence is a single bond,S4 is a single bond, andS5 is —(CH2)9, wherein g is from 1 to 20;(iii) P is hydrogen; and(iv) e′ is 1 or 2, and f is 1. 5. The compound of claim 1, wherein said compound is represented by the following Formula Ia, wherein m is from 0 to 3, and each R1 is selected, independently for each m, from formyl, alkylcarbonyl, alkoxycarbonyl, aminocarbonyl, arylcarbonyl, aryloxycarbonyl, aminocarbonyloxy, alkoxycarbonylamino, aryloxycarbonylamino, boronic acid, boronic acid esters, cycloalkoxycarbonylamino, heterocycloalkyloxycarbonylamino, heteroaryloxycarbonylamino, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, halogen, optionally substituted cycloalkyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted heteroalkyl, optionally substituted heterocycloalkyl, and optionally substituted amino. 6. The compound of claim 1, wherein said compound is represented by the following Formula Ib, wherein, (B) (i) m is from 0 to 3, and R1 is selected, independently for each m, from formyl, alkylcarbonyl, alkoxycarbonyl, aminocarbonyl, arylcarbonyl, aryloxycarbonyl, aminocarbonyloxy, alkoxycarbonylamino, aryloxycarbonylamino, boronic acid, boronic acid esters, cycloalkoxycarbonylamino, heterocycloalkyloxycarbonylamino, heteroaryloxycarbonylamino, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, halogen, optionally substituted cycloalkyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted heteroalkyl, optionally substituted heterocycloalkyl, and optionally substituted amino; and (C) B and B′ are each independently selected from hydrogen, halogen, and chiral or achiral groups selected from metallocenyl, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted heteroalkyl, optionally substituted alkoxy, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted heterocycloalkyl, and optionally substituted cycloalkyl, or wherein B and B′ are taken together with any intervening atoms to form a group selected from optionally substituted cycloalkyl and optionally substituted heterocycloalkyl. 7. The compound of claim 6, wherein L1 is selected from the following formulas, 8. The compound of claim 7, wherein, (B) (i) R1, for each m, is independently selected from, methyl, ethyl, bromo, chloro, fluoro, methoxy, ethoxy and CF3, and (ii) R2, for each n, is independently selected from, methyl, ethyl, bromo, chloro, fluoro, methoxy, ethoxy and CF3; (C) R3 and R4 are each independently selected from, methyl, ethyl, propyl and butyl; and (D) B and B′ are each independently selected from phenyl substituted with one or more groups independently selected from aryl, heteroaryl, heterocycloalkyl, alkyl, alkenyl, alkynyl, alkoxy, halogen, amino, alkylcarbonyl, carboxy, and alkoxycarbonyl. 9. The compound of claim 1, wherein said compound is a photochromic compound. 10. A photochromic composition comprising the compound of claim 9 and optionally at least one other photochromic compound, wherein said composition comprises: (a) a single photochromic compound;(b) a mixture of photochromic compounds;(c) a material comprising at least one photochromic compound;(d) a material to which at least one photochromic compound is chemically bonded;(e) material (c) or (d) further comprising a coating to substantially prevent contact of the at least one photochromic compound with external materials;(f) a photochromic polymer; or(g) mixtures thereof. 11. A photochromic composition comprising at least one compound of claim 9 incorporated into at least a portion of an organic material, said organic material being a polymeric material, an oligomeric material, a monomeric material or a mixture or combination thereof. 12. The photochromic composition of claim 11 wherein said polymeric material comprises liquid crystal materials, self-assembling materials, polycarbonate, polyamide, polyimide, poly(meth)acrylate, polycyclic alkene, polyurethane, poly(urea)urethane, polythiourethane, polythio(urea)urethane, polyol(allyl carbonate), cellulose acetate, cellulose diacetate, cellulose triacetate, cellulose acetate propionate, cellulose acetate butyrate, polyalkene, polyalkylene-vinyl acetate, poly(vinylacetate), poly(vinyl alcohol), poly(vinyl chloride), poly(vinylformal), poly(vinylacetal), poly(vinylidene chloride), poly(ethylene terephthalate), polyester, polysulfone, polyolefin, copolymers thereof, and/or mixtures thereof. 13. The photochromic composition of claim 11 wherein the photochromic composition further comprises at least one additive chosen from dyes, alignment promoters, antioxidants, kinetic enhancing additives, photoinitiators, thermal initiators, polymerization inhibitors, solvents, light stabilizers, heat stabilizers, mold release agents, rheology control agents, leveling agents, free radical scavengers, gelators and adhesion promoters. 14. The photochromic composition of claim 11 comprising a coating composition chosen from liquid crystal materials, self-assembling materials and film forming materials. 15. A photochromic article comprising a substrate and a photochromic compound according to claim 9 connected to at least a portion of a substrate. 16. The photochromic article of claim 15 comprising an optical element, said optical element being at least one of an ophthalmic element, a display element, a window, a mirror, packaging material and an active or passive liquid crystal cell element. 17. The photochromic article of claim 16, wherein the ophthalmic element comprises corrective lenses, non-corrective lenses, contact lenses, intra-ocular lenses, magnifying lenses, protective lenses, or visors. 18. The photochromic article of claim 15 wherein the substrate comprises a polymeric material and the photochromic material is incorporated into at least a portion of the polymeric material. 19. The photochromic article of claim 18 wherein the photochromic material is blended with at least a portion of the polymeric material, bonded to at least a portion of the polymeric material, and/or imbibed into at least a portion of the polymeric material. 20. The photochromic article of claim 15 wherein the photochromic article comprises a coating or film connected to at least a portion of the substrate, said coating or film comprising the photochromic material. 21. The photochromic article of claim 20 wherein said substrate is formed from organic materials, inorganic materials, or combinations thereof. 22. The photochromic article of claim 15 further comprising at least one additional at least partial coating chosen from photochromic coatings, anti-reflective coatings, linearly polarizing coatings, transitional coatings, primer coatings, adhesive coatings, reflective coatings, antifogging coatings, oxygen barrier coatings, ultraviolet light absorbing coatings, and protective coatings. 23. A photochromic article comprising a substrate;at least a partial coating of one alignment material;at least one additional at least partial coating of a liquid crystal material; andat least one compound of claim 9. 24. The photochromic article of claim 23 further comprising at least one additive chosen from dichroic dyes, non-dichroic dyes, alignment promoters, antioxidants, kinetic enhancing additives, photoinitiators, thermal initiators, polymerization inhibitors, solvents, light stabilizers, heat stabilizers, mold release agents, rheology control agents, leveling agents, free radical scavengers, gelators and adhesion promoters. 25. The photochromic article of claim 23, wherein the substrate is selected from glass, quartz, and polymeric organic materials. 26. The photochromic article of claim 23, wherein the at least one alignment material comprises a polymer network orientable by exposure to at least one of: a magnetic field, an electric field, linearly polarized infrared radiation, linearly polarized ultraviolet radiation, linearly polarized visible radiation and a shear force. 27. The photochromic article of claim 23, wherein said liquid crystal material is a liquid crystal polymer. 28. The photochromic article of claim 23, further comprising at least one primer coating, transitional coating, protective coating or a combination thereof. 29. The photochromic article of claim 28, wherein the transitional coating comprises an acrylate polymer. 30. The photochromic article of claim 28, wherein the protective coating comprises at least one siloxane derivative. 31. The photochromic article of claim 28, wherein the at least one primer coating comprises a polyurethane.
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