Process for the production of paper, board and cardboard having high dry strength by addition of a water-soluble cationic polymer and of an anionic polymer to a paper stock, draining of the paper stock and drying of the paper products, wherein an aqueous dispersion of at least one anionic latex and
Process for the production of paper, board and cardboard having high dry strength by addition of a water-soluble cationic polymer and of an anionic polymer to a paper stock, draining of the paper stock and drying of the paper products, wherein an aqueous dispersion of at least one anionic latex and at least one degraded starch is used as the anionic polymer.
대표청구항▼
1. A process for the production of paper, board and cardboard comprising adding a water-soluble cationic polymer and an anionic polymer to a paper stock, draining of the paper stock and drying of the paper products, whereinthe anionic polymer comprises an aqueous dispersion of at least one anionic l
1. A process for the production of paper, board and cardboard comprising adding a water-soluble cationic polymer and an anionic polymer to a paper stock, draining of the paper stock and drying of the paper products, whereinthe anionic polymer comprises an aqueous dispersion of at least one anionic latex and at least one degraded starch, andthe degraded starch has an average molecular weight Mw, of from 2,500 to 35,000 g/mol. 2. The process according to claim 1, wherein the molar mass Mw of the cationic polymer is in the range from 5000 to 5 million g/mol. 3. The process according to claim 2, wherein the anionic latex consists of (1) styrene and/or acrylonitrile or methacrylonitrile,(2) acrylates and/or methacrylates of C1- to C10-alcohols and optionally(3) acrylic acid, methacrylic acid, maleic acid and/or itaconic acid and(4) (meth)acrylates of optionally monoalkoxylated phosphoric acids of formula (VIII), H—[X]n—P(O)(OH)2 (VIII)where X is a straight-chain or branched C2-C6-alkylene oxide unitand n is an integer from 0 to 20. 4. The process according to claim 3, wherein the anionic latex consists of 2-25% by weight of styrene, 2-25% by weight of acrylonitrile, 50 -95% by weight of C1-C4-alkyl acrylates, 0-5% by weight of acrylic acid and 0.1- 5% by weight of (meth)acrylates of monoalkoxylated phosphoric acids of the formula (VIII), where X is a propylene oxide unit and n is an integer from 5 to 15. 5. The process according to claim 1, wherein the charge densities of the cationic polymer are in the range from 0.5 to 23 meq/g of polymer, and wherein the pH of the stock solution having at least the water-soluble cationic polymer is from 4.5 to 8. 6. The process according to claim 5, wherein the pH of the stock solution having at least the water-soluble cationic polymer is from 6 to 7.5. 7. The process according to claim 1, wherein the water-soluble cationic polymer is a polymer having vinylamine units. 8. The process according to claim 1, wherein the anionic latex consists of a) styrene and/or acrylonitrile or methacrylonitrile,b) acrylates and/or methacrylates of C1-to C10-alcohols and optionallyc) acrylic acid, methacrylic acid, maleic acid and/or itaconic acid. 9. The process according to claim 8, wherein the anionic latex consists of 2-20% by weight of styrene, 2-20% by weight of acrylonitrile, 60-95% by weight of C1-C4-alkyl acrylates and 0-5% by weight of acrylic acid. 10. The process according to claim 1, wherein the anionic latex comprises at least one monomer comprising phosphonic groups, phosphoric acid groups, or both incorporated in the form of polymerized units. 11. The process according to claim 10, wherein the monomer comprises a phosphoric acid group and is obtained by a process comprising esterifying a monoethylenically unsaturated C3-C8-carboxylic acid with optionally a monoalkoxylated phosphoric acid of the general formula (VIII) H—[X]n—P(O)(OH)2 (VIII)whereX is a straight-chain or branched C2-C6-alkylene oxide unit andn is an integer from 0 to 20. 12. The process according to claim 11, wherein in monoalkoxylated phosphoric acid of the formula (VIII), X is a straight-chain or branched C2-C3-alkylene oxide unit and n is an integer from 5 to 15 are used. 13. The process according to claim 11, wherein the monoethylenically unsaturated C3-C8-carboxylic acid is at least selected from the group consisting of acrylic acid, methacrylic acid, dimethylacrylic acid, ethacrylic acid, maleic acid, citraconic acid, methylenemalonic acid, crotonic acid, fumaric acid, mesaconic acid and itaconic acid. 14. The process according to claim 1, wherein the degraded starch is a maltodextrin. 15. The process according to claim 1, wherein the anionic latex comprises at least one monomer comprising phosphonic groups, phosphoric acid groups, or both incorporated in the form of polymerized units, andthe monomer comprises a phosphoric acid group and is obtained by a process comprising esterifying a monoethylenically unsaturated C3-C8-carboxylic acid with optionally a monoalkoxylated phosphoric acid of the general formula (VIII) H—[X]n—P(O)(OH)2 (VIII)whereX is a straight-chain or branched C2-C3-alkylene oxide unit andn is an integer from 5 to 15. 16. The process according to claim 15, wherein X represents an ethylene oxide unit. 17. The process according to claim 15, wherein X represents a propylene oxide unit. 18. The process according to claim 1, wherein said at least one anionic latex is in the form of particles in the aqueous dispersion, said particles having particle sizes of from 50 to 300 nm, measured with a Malvern Autosizer 2 C. 19. The process according to claim 1, wherein the degraded starch comprises starch having an amylopectin content of at least 80% by weight.
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이 특허에 인용된 특허 (12)
Linhart Friedrich,DEX ; Stange Andreas,DEX ; Schuhmacher Rudolf,DEX ; Hartmann Heinrich,DEX ; Denzinger Walter,DEX ; Niessner Manfred,DEX ; Nilz Claudia,DEX ; Reuther Wolfgang,DEX ; Meixner Hubert,DE, Cationic modification of starch and use of the cationically modified starch.
Anderson, Kevin Ray; Esser, Anton; Fosdick, Lawrence Edward; Hwang, Ki-Oh; Mahr, Norbert; McDonald, Jr., John Thomas; Sivasligil, Dogan Sahin; Stange, Andreas; Veelaert, Sarah; Wendker, Martin, Compositions suitable as additives in the paper industry, preparation; use; and, paper comprising such.
Stange Andreas (Mannheim DEX) Degen Hans-Juergen (Lorsch DEX) Auhorn Werner (Frankenthal DEX) Weberndoerfer Volkmar (Mannheim DEX) Kroener Michael (Mannheim DEX) Hartmann Heinrich (Limburgerhof DEX), Making paper, board and cardboard of high dry strength.
Lorencak, Primoz; Stange, Andreas; Diehl, Kurt; Mahr, Norbert, Modifying starch with cationic polymers and use of the modified starches as dry-strength agent.
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